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Trans-Configuration in Dimethyltin and Dimethyllead Bis(Acetylacetonates)

  • Rokuro Okawara
  • Yoshikane Kawasaki
  • Toshio Tanaka

Abstract

Recently, a series of diorganotin bis(8-hydroxyquinolinates) and diorganotin (2,2′ bipyridyl)dichlorides were characterized (1,2), and all of these compounds seemed to have chelating structure containing hexa-coordinated tin atom. It was not clear, however, whether they have cis- or trans-configuration concerning the methyl groups. Is is interesting to find out one of the isomers which is either cis- or trans-configuration among the similar compounds having hexa-coordinated tin atom.

Keywords

Aqueous Ammonia Sodium Methoxide Chloride Complex Lead Atom Hydrolyze Species 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Tanaka, T., Komura, M., Kawasaki, Y., and Okawara, R., J.Organometal.Chem., in press.Google Scholar
  2. 2.
    BLAKE, D., COATES, G.E., and TATE, J.M., J.Chem.Soc. (London), 1961, 756; Alleston, D.L., and Davies, A.G., J.Chem.Soc. (London), 1962, 2050.Google Scholar
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    NAKAMOTO, K., and MARTELL, A.E., J. Chem. Physa., 32, 588(1960);CrossRefGoogle Scholar
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    NAKAMOTO, K., MCCARTHY, P. J., and MARTELL, A.E., J. Am.Chem. Soc, 83, 1272 (1961);CrossRefGoogle Scholar
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    MIKAMI, M., NAKAGAWA, I., and SHIMANOUCHI, T., The 17th Annual Meeting of Japan Chem.Soc., 31X-21(1964).Google Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • Rokuro Okawara
    • 1
  • Yoshikane Kawasaki
    • 1
  • Toshio Tanaka
    • 1
  1. 1.Department of Applied ChemistryOsaka UniversityHigashinoda Miyakojima, OsakaJapan

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