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Abstract

It has been shown, that the ESR spectra of transition metal complexes that exhibit a resolved ligand hyperfinestructure (hfs), give particularly useful information to perform semiempirical LCAO -MO calculations of such complexes (1, 2). The ESR data give a good measure of the degree of delocalisation of the unpaired electrons in the complex. MAKI and McGARVEY (3) have given a theory of the ESR spectra of copper(II) complexes, and they have shown, that the theory gives reasonable values for the bonding parameters of these complexes.

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© 1964 Springer-Verlag Wien

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v. Zelewsky, A., Schneider, W. (1964). ESR Spectra of Cupric Complexes with Substituted Pyridines. In: Gutmann, V. (eds) Proceedings of the 8th International Conference on Coordination Chemistry. Springer, Vienna. https://doi.org/10.1007/978-3-7091-3650-8_14

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  • DOI: https://doi.org/10.1007/978-3-7091-3650-8_14

  • Publisher Name: Springer, Vienna

  • Print ISBN: 978-3-7091-3652-2

  • Online ISBN: 978-3-7091-3650-8

  • eBook Packages: Springer Book Archive

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