Coordination Chemistry of Sulphur Trioxide with Oxygen Bases
Octahedral configuration for the sulphur atoms is not very frequent. Examples are sulphur hexafluoride, sulphur monochloro pentafluoride and disulphur decafluoride. JANDER (1) from potentiometric titrations of sulphur trioxide against anhydrous hydrocyanic acid has postulated the existence of tribasic adducts with the proposed structure (HO)3S(CN)3 having octahedral configuration.
KeywordsSulphur Hexa Fluoride Oxygen Base Hydrocyanic Acid Isobutyric Acid Buffer Region
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