Coordination Chemistry of Sulphur Trioxide with Oxygen Bases

  • Ram Chand Paul
  • M. S. Bains
Conference paper


Octahedral configuration for the sulphur atoms is not very frequent. Examples are sulphur hexafluoride, sulphur monochloro pentafluoride and disulphur decafluoride. JANDER (1) from potentiometric titrations of sulphur trioxide against anhydrous hydrocyanic acid has postulated the existence of tribasic adducts with the proposed structure (HO)3S(CN)3 having octahedral configuration.


Sulphur Hexa Fluoride Oxygen Base Hydrocyanic Acid Isobutyric Acid Buffer Region 
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  1. 1.
    JANDER, G., and SCHOLZ, G., Z. physik. Chem., 192, 163 (1943).Google Scholar
  2. 2.
    PAUL, R. C., and NARULA, S. P., J. Sci.Ind. Res., 20B, 184 (1961).Google Scholar
  3. 3.
    PAUL, R. C., NARULA, S. P., and MEYER PRABHA, J. Ind. Chem. Soc., 39, 297 (1962).Google Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • Ram Chand Paul
    • 1
  • M. S. Bains
    • 1
  1. 1.Department of ChemistryPanjab UniversityChandigarh-3India

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