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The Formation of Metal Complexes in Solution

  • George H. Nancollas
Conference paper

Abstract

One of the more recent developments in the field of coord ina tion chem is try has been the determination of the heats of formation of metal complexes and ion-pairs in solution. It has been recognised that the measurement of the association constants at only one temperature is of very limited value since it is preferable to regard the free energy change as a consequence of changes in the heat and entropy of association. An effectively constant ∆G for a series of complex formation reactions can mask important changes in ∆H and ∆∆S.

Keywords

Association Constant Complex Formation Reaction Stop Flow Technique Divalent Transition Metal Glycinate Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    McAULEY, A., and NANCOLLAS, G. H., J. Chem. Soc. (London), 1961, 2215.Google Scholar
  2. 2.
    NAIR, V. S. K., and NANCOLLAS, G. H., J. Chem. Soc. (London), 1961, 4367.Google Scholar
  3. 3.
    McAULEY, A., and NANCOLLAS, G. H., J. Chem. Soc. (London), 1961, 4458.Google Scholar
  4. 4.
    BRANNAN, J. R., DUNSMORE, H. S., and NANCOLLAS, G. H., J.Chem. Soc. (London), 1964, 304.Google Scholar
  5. 5.
    McAULEY, A., and NANCOLLAS, G. H., J. Chem. Soc. (London), 1963, 989.Google Scholar
  6. 6.
    BOYD, S., and NANCOLLAS , G. H., Unpublished results.Google Scholar
  7. 7.
    CIAMPOLINI, M., PAOLETTI, P., and SACCONI, L., J. Chem. Soc. (London), 1960, 4553.Google Scholar
  8. 8.
    CIAMPOLINI, M., PAOLETTI, P., and SACCONI, L.,“Advances in the Chemistry of the Coordination Compounds”, Ed. Kirschner, MacMillan, 1961.Google Scholar
  9. 9.
    NANCOLLAS, G. H., and SUTIN, N., inorg. Chem., 3, 360 (1964).CrossRefGoogle Scholar
  10. 10.
    SWIFT, T. J., and CONNICK, R.E., J. Chem. Phys., 37, 307 (1962).CrossRefGoogle Scholar
  11. 11.
    DAVIES, A. G., and SMITH, W. Macf., Proc. Chem. Soc., 1961, 380.Google Scholar
  12. 12.
    NANCOLLAS, G. H., and TORRANCE, K., Unpublished results.Google Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • George H. Nancollas
    • 1
  1. 1.Chemistry DepartmentThe UniversityScotlandUK

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