Auto-Coordination in Solid Phosphorylchloride

  • E. W. Wartenberg
Conference paper


IR and Raman investigations on solid POC13 at temperatures between -40 to -100° have shown a negative frequency shift of the PO-suetching frequency of 15 cm -1 on passing from the liquid to the solid state. in the IR spectrum one sharp peak was observed, whereas the Raman frequency of the liquid (1295 cm -1) is split into two frequencies 1300 (w) and 1280 (st). Gaseous POCl3 absorbs at 1324 cm -1. the frequency shift gas/solid amounts to ∆v -45 cm -1. Undercooled liquid POCl3 (-30°) shows no frequency shift.


Frequency Shift Carbonyl Compound Addition Compound Raman Frequency Raman Investigation 
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  1. 1.
    BELLAMY, L. J., “The infrared Spectra of Complex Molecules”, J. Wiley, S.380 (1958).Google Scholar
  2. 2.
    GOBEAU, J., and BERGER, W., Z. anorg. allg. Chem., 304, 148 (1960).Google Scholar
  3. 3.
    LINDQVIST, I., “Inorganic Adduct Molecules of Oxo Compounds ”, Springer, S. 87 (1963).CrossRefGoogle Scholar
  4. 4.
    WARTENBERG, E. W., Proc., 7 ICCC, 214 (1962).Google Scholar
  5. 5.
    WARTENBERG, E. W., and GOBEAU, J., Z. anorg. allg. Chem., im Druck.Google Scholar
  6. 6.
    GROENEVELD, W. J., and ZUUR, A. P., Rec. Trav. Chim. Pays Bas, 76, 1005 (1957).CrossRefGoogle Scholar
  7. 7.
    GUTMANN, V., XVIIth international Congress of Pure and Applied Chem., Verlag Chemie, Weinheim/Bergstr., p.106 (1959).Google Scholar
  8. 8.
    VAN WAZER, J. R.,“Phosphorus and its Compounds”; interscience, S.254(1958).Google Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • E. W. Wartenberg
    • 1
  1. 1.Laboratorium für anorganische ChemieTechnischen HochschuleStuttgartGermany

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