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The Affinity of Cupric(Pyridine) Complex Towards a Fifth Ligand

  • H. C. Volger
  • W. Brackman
Conference paper

Abstract

The further coordination of copper pyridine complexes with other ligands in methanol has been studied by investigation the absorption spectra and by studying equilibria of cupric nitrate and pyridine in methanol in the presence of solid Cu(Pyr)4(NO3)2. If addition of a ligand X to such a system leads to the formation of a new complex, it will do so at the expense of the solid phase. The formation constant of the new complex may then be estimated from the change in the total quantity of dissolved copper as a function of the amount of X added to the system.

Keywords

Electron Paramagnetic Resonance Sodium Methoxide Ligand Exchange Reaction Pyridine Ligand Pyridine Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    BJERRUM, J., Chem. Revs., 46, 394 (1950)Google Scholar
  2. 2.
    HARRIS, C. N., LOCKYER, T. N., and WATERMAN, H., Nature, 192, 424 (1961);CrossRefGoogle Scholar
  3. 2a.
    BARCLAY, G. A., and KENNARD, C. H. L., Nature, 192, 425 (1961).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • H. C. Volger
    • 1
    • 2
  • W. Brackman
    • 1
    • 2
  1. 1.Koninklijke/Shell-LaboratoriumAmsterdamNetherlands
  2. 2.Shell Research N. V.Netherlands

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