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The Lifetimes of Chloride Ion and Water Molecules in the First Coordination Sphere of Ferric Ion as Measured by Nuclear Magnetic Resonance

  • Elaine Blatt
  • Robert E. Connick
Conference paper

Abstract

The several ferric chloride complexes existing in solutions containing chloride ion exchange both their coordinated waters and coordinated chloride ions with waters and chloride ions in the bulk of the solution. Under favorable conditions it is possible to ascertain the rates of such exchange reactions by NMR measurements.

Keywords

Chloride Complex Usual Equilibrium Formation Rate Constant Lawrence Radiation Laboratory Equilibrium Quotient 
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References

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    Rabinowitch, E., and Stockmayer, W. F., J. Am. Chem. Soc., 64, 335 (1942).CrossRefGoogle Scholar
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    Genser, E., University of California Lawrence Radiation Laboratory Report UCRL -9846, January 1962.Google Scholar
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    Connick, R. E., and Coppel, C. P., J. Am. Chem. Soc., 81, 6389 (1959).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • Elaine Blatt
    • 1
  • Robert E. Connick
    • 1
  1. 1.Department of Chemistry and Inorganic Materials Research Division of the Lawrence Radiation LaboratoryUniversity of CaliforniaBerkeleyUSA

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