The Lifetimes of Chloride Ion and Water Molecules in the First Coordination Sphere of Ferric Ion as Measured by Nuclear Magnetic Resonance
The several ferric chloride complexes existing in solutions containing chloride ion exchange both their coordinated waters and coordinated chloride ions with waters and chloride ions in the bulk of the solution. Under favorable conditions it is possible to ascertain the rates of such exchange reactions by NMR measurements.
KeywordsChloride Complex Usual Equilibrium Formation Rate Constant Lawrence Radiation Laboratory Equilibrium Quotient
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