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Metal Coordination - A Key to Oxidative Stability.

  • Horst G. Langer
Conference paper

Abstract

The oxidation of metal ions can be pH dependent because of kinetic effects as expressed in equation {1}
$$2{A^ + } + {H_2}O + 1/2{O_2} \rightleftharpoons 2{A^{2 + }} + 2O{H^ - }$$
(1)
or might be based on a difference in stabilities of various metal complexes as indicated below {2}
$$\begin{array}{*{20}{c}} {{{\left[ {M{{\left( {O{H_2}} \right)}_6}} \right]}^{2 + }}\;is\;more\;stable\;than{{\left[ {M{{\left( {O{H_2}} \right)}_6}} \right]}^{3 + }}} \\ {{{\left[ {M{{\left( {OH} \right)}_6}} \right]}^{3 - }}\;is\;more\;stable\;than\;{{\left[ {M{{\left( {OH} \right)}_6}} \right]}^{4 - }}} \end{array}$$
(34.1)
.

Keywords

Binuclear Complex Mononuclear Complex Half Wave Potential Stannous Oxide High Reduction Potential 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Langer, H. G., J. Inorg. Nucl. Chem. (in press).Google Scholar
  2. 2.
    MEITES, L., “Polarographic Techniques”, Interscience Publishers, Inc., New York, p. 286 –87 (1955).Google Scholar
  3. 3.
    LANGER, H. G., J. Inorg. Nucl. Chem., 26, 59 (1964).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • Horst G. Langer
    • 1
  1. 1.Eastern Research LaboratoryThe Dow Chemical CompanyFraminghamUSA

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