Abstract
Recent advances in statistical mechanical molecular modelling of clay-fluid interactions will be discussed, with emphasis on empirical potential based Monte Carlo and molecular dynamics simulations. These methods will be illustrated by reference to the structure and dynamics of ions and solvent at hydrated clay surfaces. The aim of this research is to provide molecular scale insight into fluid dependent processes, for example; clay swelling, solute transport through clays, and clay compaction during burial. Models for the interparticle interactions will be reviewed, with particular reference to the various strategies used to represent clay-fluid systems. The general principles of Monte Carlo and molecular dynamics computer simulation will then be described. A number of specific issues arise when these techniques are applied to the properties of confined fluids: long-range interactions, system size limitations, boundary conditions, choice of thermodynamic ensemble, and statistical sampling. Throughout, we will compare and contrast recent computer simulations of clay-fluid systems with experimental data, and draw general lessons from these examples.
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References
Allen M.P and Tildesley D.J. (1987) Computer Simulation of Liquids. Clarendon Press, Oxford, UK.
Andersen H.C. (1980) Molecular dynamics simualtions at constant pressure and/or temperature. J Chem. Phys. 72, 2384–2393.
Bash P.A., Singh U.G., Langridge R. and Kollman P.A. (1987) Free energy calculation by computer simulation. Science 49, 564–568.
Bleam W.F (1993) Atomic Theories of Phyllosilicates: Quantum Chemistry, Statistical Mechanics, Electrostatic Theory, and Crystal Chemistry. Rev.Geophysics, 31, 51–73.
Boek E.S., Coveney P.V. and Skipper N.T. (1995a) Molecular Modelling of Clay Hydration: A Study of Hysteresis Loops in the Swelling Curves of Sodium Montmorillonites. Langmuir, 11, 4629–4631.
Boek E.S., Coveney P.V. and Skipper N.T. (1995b) Monte Carlo Molecular Modelling Studies of Hydrated Li-, Na-, and K-smectites: Understanding the Role of Potassium as a Clay Swelling Inhibitor. JAm.Chem.Soc., 117, 12608–12617.
Boek E.S. and Sprik M. (2003) Ab initio molecular dynamics study of the hydration of a sodium smectite clay. J. Phys. Chem. B 107, 3251–3256.
Bounds D.G. (1985) A molecular dynamics study of the structure of water around the ions Li+, Na+, K+, Cat+, Ni2+ and Cl“. Mol.Phys. 54, 1335–1355.
Bridgeman C.H., Buckingham A.D., Skipper N.T. and Payne M.C. (1996) Ab initio total energy study of uncharged clays and their interaction with water. Mol.Phys., 89, 879–888.
Brindley G.W and Brown G. (1980) Crystal Structures of Clay Minerals and their X-ray Identification. Mineralogical Society, London, UK.
Brodholt J. and Wood B. (1993) Simulations of the structure and thermodynamic properties of water at elevated pressures and temperatures. J.Geophys.Res: Solid Earth, 98, 513–536.
Car R. and Parrinello M. (1985) Unified Approach for Molecular Dynamics and Density Functional Theory. Phys.Rev.Lett., 55, 2471–2474.
Chandrasekhar J., Spellmeyer D.C. and Jorgensen W.L. (1984) Energy Component Analysis for Dilute Aqueous Solutions of Li+, Na+, F- and Cl-ions. J.Am.Chem.Soc., 106, 903–910.
Chang F-R.C., Skipper N.T. and Sposito G. (1995) Computer Simulation of Interlayer Molecular Structure in Sodium Montmorillonite Hydrates. Langmuir, 11, 2734–2741.
Chang F-R.C., Skipper N.T. and Sposito G. (1997) Monte Carlo and molecular dynamics simulations of interfacial structure in lithium montmorillonite hydrates. Langmuir, 13, 2074–2082.
Chavez-Paez M, de Pablo L and de Pablo J.J (200la) Monte Carlo simulations of Ca-montmorillonite hydrates. J.Chem.Phys.,114, 10948–10953.
Chavez-Paez M, van Workum K, de Pablo L and de Pablo J.J (200 lb) Monte Carlo simulations of Wyoming sodium montmorillonite hydrates. J.Chem.Phys.,114, 1405–1413.
De Carvalho RJFL and Skipper NT (2001) Atomistic computer simulation of the clay-fluid interface in colloidal laponite. J.Chem.Phys. 114, 3727–3733.
Delville A. (1991) Modelling the Clay-Water Interface. Langmuir, 7, 547–555.
Delville A. (1992) Structure of Liquids at a Solid Interface: An Application to the Swelling of Clay by Water. Langmuir, 8, 1796–1805.
Delville A. (1993a) Structure and Properties of Confined Liquids: A Molecular Model of the Clay-Water Inteface. J.Phys.Chem., 97, 9703–9712.
Delville A. and Sokolowski S. (1993b) Adsorption of Vapour at a Solid Interface: A Molecular Model of Clay Wetting. J.Phys.Chem., 97, 6261–6271.
Enderby J.E. and Neilson G.W. (1981) The structure of electrolyte solutions. Rep. Prog.Phys., 44, 593–643.
Finney J.L., Quinn J.E., and Baum J.O. (1986) The water dimer potential surface. Water Science Reviews, 1, 93.
Frenkel D. and Smit B. (1996) Understanding Molecular Simulation. Academic Press, San Diego, USA.
Glaeser R. et Méring J. (1968) Domaines d’hydration homogène des smectites. C. r. hebd. Séan. Acad. Sci. Paris 267, 463–466.
Guldbrand L., Jonsson B., Wennerstrom H. and Linse P (1983) Electrical double layer forces. A Monte Carlo study. J.Chem.Phys., 80, 2221–2228.
Guven N. (1992) Molecular Aspects of Clay-Water Interactions. Clay Water Interface and its Rheological Implication, editors N.Guven and R.M.Pollastro, Volume 4, CMS Workshop Lectures, The Clay Minerals Society, Boulder, Colorado, USA.
Hensen E.J.M and Smit B. (2002) Why Clays Swell. J. Phys. Chem. B, 106, 12664–12667.
Ichikawa Y., Kawamura K., Nakano M., Kitayama K. and Kawamura H. (1999). Unified molecular dynamics and homogenization analysis for bentonite behaviour: current results and future possibilities. Eng. Geology, 54, 21–31.
Ichikawa Y., Kawamura K., Nakano M., Kitayama K., Seiki T. and Theramast N. (2001). Seepage and consolidation of bentonite saturated with pure-and salt-water by the method of unified molecular dynamics and homogenization analysis. Eng. Geology, 60, 127–138.
Jorgensen W.L., Chandrasekhar J., Madura J., Impey R.W. and Klein M.L. (1983) Comparison of simple potential functions for modelling water. J.Chem.Phys., 79, 926–935.
Israelachvili J.N. and Wennerstrom H. (1996) The Role of Hydration and Water Structure in Biological and Colloidal Systems. Nature, 379, 219–225.
Jorgensen W.L. (1981) Transferable intermolecular potential functions for water, alcohols and ethers. Application to liquid water. J.Am.Chem.Soc., 103, 335–340.
Jorgensen W.L., Chandrasekhar J., Madura J., Impey R.W. and Klein M.L. (1983) Comparison of simple potential functions for modelling water. J.Chem.Phys., 79, 926–935.
Jorgensen W.L. (1984) Optimised Intermolecular Potential Functions for liquid hydrocarbons. J.Am.Chem.Soc., 106, 6638–6646.
Karaborni S., Smit B., Heidug W., Urai J. and van Oort E. (1996) The Swelling of Clays: Molecular of the Hydration of Montmorillonite. Science, 271, 1102–1104.
Kubicki J.D. and Bleam W.F. (1998). Molecular modeling of clays and mineral surfaces: a short course. CMS Workshop 12. Clay Minerals Society, Boulder, USA.
Kuyucak S., Andersen O.S. and Chung S-H. (2001) Models of permeation in ion channels. Rep. Prog. Phys. 64, 1427–1472.
Lee C., Vanderbilt D., Laasonen K., Car R. and Parrinello M. (1992) Ab initio Studies on High Pressure Phases of Ice. Phys.Rev.Lett., 69, 462–465.
Lie G.C., Clementi E. and Yoshimine O. (1976) Study of the structure of molecular complexes. XIII. Monte Carlo simulation of liquid water with a configuration interaction pair potential. J.Chem.Phys., 64, 2314–2323.
Lybrand T.P and Kollman P.A. (1985) Water-water and water-ion potential functions including terms for many body effects. J.Chem.Phys., 83, 2923–2933.
Mahoney M.W. and Jorgensen W.L. (2000) A five-site model for liquid water and the reporduction of the density anomaly by rigid, nonpolarizable potential functions. J. Chem. Phys. 112, 8910–8922.
Matsouka O., Clementi E. and Yoshimine M. (1976) CI study of the water dimer potential surface. J.Phys.Chem., 64, 1351–1361.
Mezei M. (1982) Excess free energy of different water models computed by Monte Carlo methods. Mol. Phys. 47, 1307–1315.
Neilson G.W. and Enderby J.E. (1989) Co-ordination of metal aquaions. Adv. Inorg. Chem., 34, 196–218.
Newman A C D (1987) Chemistry of Clays and Clay Minerals. Wiley, New York, USA.
Norrish K. (1954) The swelling of montmorillonite. Discuss Faraday Soc. 18, 120–132.
North F.K. (1990) Petroleum Geology. Unwin-Hyman, Boston, USA.
Nosé S. (1986) An extension of the canonical ensemble molecular dynamics method. Mol. Phys. 57, 187191.
Ohtaki H. and Radnai T. (1993). Structure and dynamics of hydrated ions. Chem. Rev., 93, 1157–1204.
Park S-H. and Sposito G. (2000) Monte Carlo simulation of total radial distribution functions for interlayer water in Li-, Na-, and K-montmorillonite hydrates. J. Phys. Chem. B 104, 4642–4648.
Payne M.C., Teter M.P., Allan D.C., Arias T.A. and Joannopoulos J.D. (1992) Iterative minimization techniques for ab initio total-energy calculations: molecular dynamics and conjugate gradients. Rev.Mod.Phys., 64, 1045–1097.
Porion P., Al Mukhtar M., Faugére A.M., Pellenq R.J.M., Meyer S. and Delville A. (2003) Water self diffusion within nematic dispersions of nanocomposites: a multiscale analysis of 1H pulsed gradient spin-echo NMR measurements. J. Phys. Chem. B 107, 4012–4023.
Refson K. Skipper N.T. and McConnell J.D.C. (1993), Molecular dynamics simulation of water mobility in smectites. In Geochemistry of Clay-Pore fluid interactions, editors D.A.C.Manning and P.L.Hall, Mineralogical Society, Chapman and Hall, London, UK.
Remler D.K. and Madden P.A. (1990) Molecular dynamics without effective pair potentials via the CarParrinello approach. Mol.Phys., 70, 921–966.
Shroll R.M. and Smith D.E. (1999) Molecular dynamics simulations in the grand canonical ensemble: application to clay mineral swelling. J.Chem.Phys., 111, 9025–9033.
Siqueira A. de, Skipper N.T., Coveney P.V and Boek E.S. (1997) Computer Simulation Evidence for Enthalpy driven Dehydration of Clays Under Sedimentary Basin Conditions. Mo1.Phys., 92, 1–6.
Skipper N.T., Refson K. and McConnell J.D.C. (1991) Computer simulation of interlayer water in 2:1 clays. J.Chem.Phys., 94, 7434–7445.
Skipper N.T., Chang F-R.C. and Sposito G. (1995a) Monte Carlo simulation of interlayer molecular structure in swelling clay minerals. 1. Methodology. Clays Clay Miner., 43, 285–293.
Skipper N.T., Chang F-R.C. and Sposito G. (1995b) Monte Carlo simulation of interlayer molecular struture in swelling clay minerals. 2. Monolayer Hydrates. Clays Clay Miner., 43, 294–303.
Smith D.E. (1998) Molecular computer simulation of the swelling properties and interlayer structure of cesium montmorillonite. Langmuir 14, 5959–5967.
Smith D.E. and Haymet A.D.J. (1992) Structure and dynamics of water and aqueous solutions: the role of flexibility. J.Chem.Phys., 96, 8450–8459.
Sposito G. and Prost R. (1982) Structure of water adsorbed on smectites. Chem.Rev., 82, 553–573.
Sposito G., Skipper N.T., Sutton R., Park S-H., Chang F-R, Soper A.K. and Greathouse J.A. (1999) Surface Geochemistry of the clay minerals. Proc. Natl. Acad. Sci. USA, 96, 3358–3364.
Titiloye J.O. and Skipper N.T. (2001) Molecular dynamics simulation of methane in sodium montmorillonite clay hydrates at elevated pressures and temperatures. Mol. Phys. 99, 899–906.
Tossell J.A. (1995) Mineral Surfaces: Theoretical Approaches. Edited by D.J.Vaughan and R.A.D.Pattrick. Chapman and Hall, London, UK.
Vlot M.J., Huinink J. and van der Eerden J.P. (1999) Free energy calculations on systems of rigid molecules: an application to the TIP4P model of H2O. J. Chem. Phys. 110, 55–61.
Watanabe K. and Klein M.L. (1989) Effective pair potentials and the properties of water. Chem.Phys., 131, 157–167
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Skipper, N. (2004). Molecular Modelling of Pore Fluids in Clays. In: Loret, B., Huyghe, J.M. (eds) Chemo-Mechanical Couplings in Porous Media Geomechanics and Biomechanics. International Centre for Mechanical Sciences, vol 462. Springer, Vienna. https://doi.org/10.1007/978-3-7091-2778-0_12
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DOI: https://doi.org/10.1007/978-3-7091-2778-0_12
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