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Behaviour of Fluorochemical-Treated Fabric in Contact with Water

Ana Robert Estelrich
  • S. A. Pymag
Part of the International Centre for Mechanical Sciences book series (CISM, volume 463)

Abstract

The introduction of fluorinated coatings in the textile industry has improved significantly the hydro- and oleophobic properties of the treated fabrics. However, these properties are notably reduced when the fabric is washed and partially recovered with heat treatment in air such as ironing. These changes of repellency are related to the modification of the chemical organisation of the fiber surface. This paper describes the chemical structure of some of the fluoropolymers used in textile and their relationship with these surface properties. A new explanation of the nature of this diminishing performance in contact with water and its recovery by heating is given.

Keywords

Contact Angle Pendant Group Ethyl Acrylate Recede Contact Angle Smectic Phase 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. ACS Symposium Series 2001, 787 ( Fluorinated Surfaces, Coatings and Films ), 1Google Scholar
  2. Arunyadej S.,and Mitchell R., J. Text. Inst. 1998, 89 Part 1,696Google Scholar
  3. Brandon S., and Marmur A., J. Colloid Interface Sci. 1996, 183, 351CrossRefGoogle Scholar
  4. Bunn C. W., and Holmes D. R., Disc. Faraday Soc. 1958, 25, 95CrossRefGoogle Scholar
  5. Castelvetro V., Francini G., Ciardelli G., and Ceccato M., Textile Research Journal 2001, 71/5 399Google Scholar
  6. Crevoisier G., Fabre P., Corpart J. M., and Leibler L., Science 1999, 285, 1246CrossRefGoogle Scholar
  7. Crevoisier G., Fabre P., Leibler L., Tencé-Girault S., and Corpart J. M., Macromolecules 2002, 35 (10), 3880CrossRefADSGoogle Scholar
  8. Defay R., Surface Tension and Adsorption, Wiley, New York, 1966Google Scholar
  9. Dhathathereyan A., Baskar G., Ramasami T., and Juhué D., Langmuir 2002, 18(12), 4704 Dorset D.L., Macromolecules 1990, 23, 894CrossRefADSGoogle Scholar
  10. Duschek G., Melliand Textilberichte 2001, 7–8, 604Google Scholar
  11. Game Ph., Sage D., and Chapel J. P., Macromolecules 2002, 35, 917CrossRefADSGoogle Scholar
  12. Grottenmüller R., Fluorocarbons-An Innovative Aid to the Finishing of Textiles, Melliand Int. 1998, 4, 278Google Scholar
  13. Hara K., and Katano Y., Japanese J. App. Phys., part 2: Letters 2002, 41 (4B), L490CrossRefGoogle Scholar
  14. Holme, I., New Developments in the Chemical Finishing of Textiles, J. Textile Inst. 1993, 84, 520CrossRefGoogle Scholar
  15. Höpken J., Sheiko S., Czech J., and Möller M., Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 1992, 33 (1), 937Google Scholar
  16. Hsieh H. W. S., Post, B., and Morawetz, H., J. Polym. Sci., Polym. Phys. Ed. 1976, 14, 1241 Huh C., and Mason S. G., J. Colloid Interface Sci. 1977, 60, 11Google Scholar
  17. Johnson R. E. Jr., and Dettre R. H., Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 1987, 28 (2), 48Google Scholar
  18. Juhué D., Gayon A. C., Corpart J. M., Charret N., Cavaillé J. Y., and Perriat P., Fluorine in Coatings IV, paper 22, 2001Google Scholar
  19. Juhué D., Gayon A. C., Corpart J. M., Quet C., Delichère P., Charret N., David L., Cavaillé J. Y., and Perriat P., Textile Research Journal 2002, 72 (9), 832CrossRefGoogle Scholar
  20. Katano Y., Tomono H., and Nakajima T., Macromolecules 1994, 27, 2342Google Scholar
  21. Katsuragawa T., Chiba E., Okada K., Tani K., and Tomono H., Jpn. J. Appl. Phys. 1995, 34, 649CrossRefADSGoogle Scholar
  22. Kheshgi H. S., and Scriven L. E., Chem. Eng. Sci. 1991, 46, 519CrossRefGoogle Scholar
  23. Kober M., and Wesslen B., J. App. Polym. Sci. 1994, 54, 793CrossRefGoogle Scholar
  24. Lermann E., Dissertation Kapitel 6, Univerität Ulm 1997Google Scholar
  25. Lüning J., Yoon D.Y., and Stöhr J., J. Electron Spectroscopy and Related Phenomena 2001, 121, 265CrossRefGoogle Scholar
  26. Mélas M., Thèse de Doctorat, Université de Montpellier I I, 1995Google Scholar
  27. Mertig M., Thiele U., Bradt J., Klemm D., and Pompe W., Appl. Phys. 1998, A66, S565CrossRefADSGoogle Scholar
  28. Pittman A.G., “Fluoropolymers”, Wall, L.A. ed., Wiley-Interscience, New York, 1972, pp. 419–49Google Scholar
  29. Plate N. A., and Shibaev V. P., Comb-Shaped Polymers and Liquid Crystals’, Plenum Press, New York, 1987CrossRefGoogle Scholar
  30. Rao N. S., and Baker B.E., Textile Finishing and Fluorosurfactants in Organofluorine Chemistry: Principles and Commercial Applications, R E Banks et al., Eds. Plenum press, NY, 1994, pp. 321–338Google Scholar
  31. Sato Y., Wakida T., Tokino S., Niu S., Ueda M., Mizushima H., and Takekoshi S., Textile Research Journal 1994, 64 (6), 316CrossRefGoogle Scholar
  32. Sedev R. V., Petrov J. G., and Neumann A. W., J. Colloid Interface Sci. 1996, 180, 36CrossRefGoogle Scholar
  33. Sheiko S., Lermann E., and Möller M., Langmuir 1996, 12, 4015CrossRefGoogle Scholar
  34. Shibasaki Y., and Fukuda K., Therm. Anal., Proc. Int. Conf. 7th 1982, 2, 1517Google Scholar
  35. Tetsuo S., Modern Fluoropolymers, Chapter 6 (1997 John Wiley & Sons Ltd.)Google Scholar
  36. Thiele U., Mertig M., and Pompe W., Phy. Rev. Lett. 1998, 80 (13), 2869Google Scholar
  37. Thiele U., Neuffer K., Pomeau Y., and Velarde M. G., Colloids and Surfaces A 2002, 206, 135CrossRefGoogle Scholar
  38. Volkov V., Platé N., Takahara A., Kajiyama T., Amaya N., and Murata Y., Polymer 1992, 33, 1316CrossRefGoogle Scholar
  39. Wakida T., and Li H., J. Soc. Dyers Color. 1993, 109, 292CrossRefGoogle Scholar
  40. Wang J., Mao G., Ober C. K., and Kramer E. J., Macromolecules 1997, 30, 1906CrossRefADSGoogle Scholar
  41. Yuang C., Ouyang M., and Koberstein J. T., Macromolecules 1999, 32, 2329Google Scholar
  42. Zisman W.A., “Contact Angle, Wettability, and Adhesion”, Good, R F. (ed.), Adv. Chem. Ser. 43, 1964, 1, Am.Chem. Soc., Washington DCGoogle Scholar

Copyright information

© Springer-Verlag Wien 2004

Authors and Affiliations

  • S. A. Pymag
    • 1
  1. 1.Berguedà 21Pol. Ind. UrvasaBarcelonaSpain

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