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POP-Type MMX-Chain Compounds with Binary Countercations and Vapochromism

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Book cover Material Designs and New Physical Properties in MX- and MMX-Chain Compounds

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Abstract

Pyrophosphito-bridged diplatinum complex is one of the most studied dinuclear complexes in a paddle-wheel structure. The chemistry of pyrophosphito-bridged diplatinum complex began at the discovery of the Pt(II)–Pt(II) complex, K4[Pt2(pop)4]⋅2H2O (pop = P2H2O 2−5 ) by Roundhill et al. in 1977 [1]. Since [Pt2(pop)4]4− shows intense long-lived phosphorescence, photochemistry and excited-state chemistry of [Pt2(pop)4]4− has been attracted much attention (see following early reviews and references therein [2, 3]). Although no chemical bond exist between two Pt(II) atoms in the ground state, 5dσ* → 6pσ transition should induce the bonding character between them. This excited-state structure has been confirmed by several optical methods [4–9]. The excited state of [Pt2(pop)4]4− is powerful one-electron reductant, therefore, it can be used as a photochemical catalyst for converting ethanol to acetaldehyde and hydrogen [10] and for the transfer hydrogenation of alkenes and alkynes [11, 12]. The Pt(III)–Pt(III) complex, [Pt2(pop)4H2]4−, is the active species of the catalytic reaction [13].

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Authors and Affiliations

  1. Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai, 980-8578, Japan

    Hiroaki Iguchi, Shinya Takaishi & Masahiro Yamashita

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  1. Hiroaki Iguchi
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  2. Shinya Takaishi
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  3. Masahiro Yamashita
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Correspondence to Hiroaki Iguchi .

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  1. , Departement of Chemistry, Tohoku University, Aramaki-Aza-Aoba, Aoba-ku, Sendai, 980-8578, Japan

    Masahiro Yamashita

  2. Kashiwano 5-1-5, Kashiwa, 277-8561, Japan

    Hiroshi Okamoto

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Iguchi, H., Takaishi, S., Yamashita, M. (2013). POP-Type MMX-Chain Compounds with Binary Countercations and Vapochromism. In: Yamashita, M., Okamoto, H. (eds) Material Designs and New Physical Properties in MX- and MMX-Chain Compounds. Springer, Vienna. https://doi.org/10.1007/978-3-7091-1317-2_10

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