Skip to main content

Abstract

The essence of gasification is the conversion of solid carbon to combustible carbon monoxide by thermochemical reactions of a fuel. Complete gasification comprises all the processes which convert the solid fuel into a gaseous and liquid product leaving only parts of the mineral constitutents of the fuel as a residue. Complete combustion takes place with excess air or at least 100% theoretical air; whereas, gasification takes place with excess carbon. The gasification of solid fuels containing carbon is accomplished in an air sealed, closed chamber under slight suction or pressure relative to ambient pressure. The fuel column is ignited at one point and exposed to the air blast. The gas is drawn off at another location in the fuel column as shown in Figure 6.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Reference Chapter III

  1. Baron, R. E., Chemical Equilibria in Carbon-Hydrogen-Oxygen Systems, MIT Press, Cambridge, Massachusetts, 1977.

    Google Scholar 

  2. Caram, H.S. and N.R. Amundson, Diffusion and Reaction in a Stagnant Boundary Layer about a Carbon Particle, Part 1, Ind. Eng. Chem. Fundam., v 16, n 2, 1977, pp 171–181.

    Article  Google Scholar 

  3. Dowson, J.E. and A.T. Larter, Producer Gas, Longmans Green and Co., London, 1907.

    Google Scholar 

  4. Ergun, S., Kinetics of the Reaction of Carbon Dioxide with Carbon, The Journal of Physical Chemistry, v 60, 1956, pp 480–485.

    Article  Google Scholar 

  5. Goldman, B. and N.C. Jones, The Modern Portable Gas Producer, Institute of Fuel, London, v 12, n 63, 1939, pp 103–40.

    Google Scholar 

  6. Goring, G.E., et al., Kinetics of Carbon Gasification by Steam, Industrial and Engineering Chemistry, v 44, n 5, 1952, pp 1051–1065.

    Article  Google Scholar 

  7. Goring, G.E., et al., Kinetics of Carbon Gasification by Steam, Industrial and Engineering Chemistry, v 45, n 11, 1953, pp 2586–2591.

    Article  Google Scholar 

  8. Goss, J.R., An Investigation of the Down-Draft Gasification Characteristics of Agricultural and Forestry Residues: Interim Report, California Energy Commission, P500–79-0017, Nov 1979.

    Google Scholar 

  9. Groeneveld, M.J., The Co-Current Moving Bed Gasifier, Thesis, Technische Hogeschool Twente, Netherlands, May 29, 1980.

    Google Scholar 

  10. Gumz, W., Gas Producers and Blast Furnaces, John Wiley and Sons, New York, 1950.

    Google Scholar 

  11. Holman, J.P., Thermodynamics, Third Edition, McGraw-Hill Book Co., New York, 1980.

    Google Scholar 

  12. Howard, J.B., et al., Kinetics of Carbon Monoxide Oxidation in Postflame Gases, 14th Symposium on Combustion, Penn. State Univ., August 1972, pp 975–986.

    Google Scholar 

  13. Johnson, J.L., Kinetics of Bituminous Coal Char Gasification with Gases Containing Steam and Hydrogen, Symposium on Coal Gasification, Division of Fuel Chemistry, Meeting of A.C.S., Dallas, Texas, April 1973.

    Google Scholar 

  14. Reed, T.B., A Survey of Biomass Gasification, Volume 2, Principles of Gasification, Publication # SERI/TR-33–239, Solar Energy Research Institute, Golden, Colorado, 1979.

    Google Scholar 

  15. Schläpfer, P. and J. Tobler, Theoretische und praktische Untersuchungen über den Betrieb von Motorfahrzeugen mit Holzgas, Schweizerische Gesellschaft für das Studium der Motobrennstoffe, Bern, Switzerland, 1937.

    Google Scholar 

  16. Skov, N.A. and M.L. Papworth, The Pegasus Unit, Pegasus Publisher Inc., Olympia, Washington, 1975.

    Google Scholar 

  17. Wen, C.Y. and J. Huebler, Kinetic Study of Coal Char Hydrogasification Rapid Initial Reaction, Industrial and Engineering Chemistry Process Design and Development, v 4, n 2, 1965, pp 142–147.

    Google Scholar 

  18. Wen, C.Y. and J. Huebler, Kinetic Study of Coal Char Hydrograsification Second-Phase Reaction, Industrial and Engineering Chemistry Process Design and Development, v 4, n 2, 1965, 147–154.

    Google Scholar 

  19. Zielke, C.W. and E. Gorin, Kinetics of Carbon Gasification, Industrial and Engineering Chemistry, v 47, n 4, 1955, pp 820–825.

    Article  Google Scholar 

  20. Zielke, C.W. and E. Gorin, Kinetics of Carbon Gasification, Industrial and Engineering Chemistry, v 9, n 3, 1957, pp 396–403.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1984 Springer Fachmedien Wiesbaden

About this chapter

Cite this chapter

Kaupp, A., Goss, J.R. (1984). Chemistry of Gasification. In: Small Scale Gas Producer-Engine Systems. Vieweg+Teubner Verlag, Wiesbaden. https://doi.org/10.1007/978-3-663-06868-6_3

Download citation

  • DOI: https://doi.org/10.1007/978-3-663-06868-6_3

  • Publisher Name: Vieweg+Teubner Verlag, Wiesbaden

  • Print ISBN: 978-3-528-02001-9

  • Online ISBN: 978-3-663-06868-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics