Skip to main content

Nanodiamond Films

  • Chapter
  • First Online:
Tetrahedrally Bonded Amorphous Carbon Films I

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 263))

  • 960 Accesses

Abstract

Many applications demand a high smoothness of the diamond films. Subsequent laborious polishing procedures can be avoided by two complementary concepts: One way consists in the oriented growth of (100) faces, resulting in parallelized polycrystals with less pronounced boundaries.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. O. Auciello, A.V. Sumant, Status review of the science and technology of ultrananocrystalline diamond (UNCD™) films and application to multifunctional devices. Diam. Relat. Mater. 19, 699–718 (2010)

    Google Scholar 

  2. J.E. Butler, A.V. Sumant, The CVD of nanodiamond materials. Chem. Vap. Depos. 14, 145–160 (2008)

    Google Scholar 

  3. D.M. Gruen, Nanocrystalline diamond films. Ann. Rev. Mater. Sci. 29, 211–259 (1999)

    Google Scholar 

  4. O.A. Shenderova, D.M. Gruen (eds.), Ultrananocrystalline Diamond (Andrew Publ, New York, 2006)

    Google Scholar 

  5. O.A. Shenderova, D.M. Gruen (eds.), Ultrananocrystalline Diamond. Synthesis, Properties, and Applications (Elsevier, Oxford, 2012)

    Google Scholar 

  6. O.A. Williams, Nanocrystalline diamond. Diam. Relat. Mater. 20, 621–640 (2011)

    Google Scholar 

  7. R. Erz, W. Dötter, K. Jung, H. Erhardt, Preparation of smooth and nanocrystalline diamond films. Diam. Relat. Mater. 2, 449–453 (1993)

    Google Scholar 

  8. A. Kromka, S. Potocky, J. Cermak, B. Rezek, J. Potmesil, J. Zemek, M. Vanecek, Early stage of diamond growth at low temperature. Diam. Relat. Mater. 17, 1252–1255 (2008)

    Google Scholar 

  9. J. Philip, P. Hess, T. Feygelson, J.E. Butler, S. Chattopadhyay, K.H. Chen, L.C. Chen, Elastic, mechanical, and thermal properties of nanocrystalline diamond films. J. Appl. Phys. 93, 2164–2171 (2003)

    Google Scholar 

  10. A.V. Sumant, P.U.P.A. Gilbert, D.S. Grierson, A.R. Konicek, M. Abrecht, J.E. Butler, T. Feygelson, Sh.S. Rotter, R.W. Carpick, Surface composition, bonding, and morphology in the nucleation and growth of ultra-thin, high quality nanocrystalline diamond films. Diam. Relat. Mater. 16, 718–724 (2007)

    Google Scholar 

  11. R.Sh. Edelstein, I. Gouzman, M. Folman, S. Rotter, A. Hoffman, Surface carbon saturation as a means of CVD diamond nucleation enhancement. Diam. Relat. Mater. 8, 139–145 (1999)

    Google Scholar 

  12. H. Eto, Y. Tamou, Y. Ohsawa, N. Kikuchi, TEM observations of diamond films prepared by microwave plasma CVD. Diam. Relat. Mater. 1, 373–379 (1992)

    Google Scholar 

  13. Y. Lifshitz, C.H. Lee, Y. Wu, W.J. Zhang, I. Bello, S.T. Lee, Role of nucleation in nanodiamond film growth. Appl. Phys. Lett. 88, 243114 (2006)

    Google Scholar 

  14. J. Wagner, C. Wild, P. Koidl, Resonance effects in Raman scattering from polycrystalline diamond films. Appl. Phys. Lett. 59, 779–781 (1991)

    Google Scholar 

  15. T. Sharda, T. Soga, T. Jimbo, M. Umeno, Highly stressed carbon film coatings on silicon: potential applications. Appl. Phys. Lett. 80, 2880–2882 (2002)

    Google Scholar 

  16. C.Z. Gu, X. Jiang, Deposition and characterization of nanocrystalline diamond films prepared by ion bombardment-assisted method. J. Appl. Phys. 88, 1788–1793 (2000)

    Google Scholar 

  17. Y.C. Chen, X.Y. Zhong, A.R. Konicek, D.S. Grierson, N.H. Tai, I.N. Lin, B. Kabius, J.M. Hiller, A.V. Sumant, R.W. Carpick, O. Auciello, Synthesis and characterization of smooth ultrananocrystalline diamond films via low pressure bias-enhanced nucleation and growth. Appl. Phys. Lett. 92, 133113 (2008)

    Google Scholar 

  18. T. Sharda, M. Umeno, T. Soga, T. Jimbo, Strong adhesion in nanocrystalline diamond films on silicon substrates. J. Appl. Phys. 89, 4874–4878 (2001)

    Google Scholar 

  19. K. Tsugawa, M. Ishihara, J. Kim, M. Hasegawa, Y. Koga, Large-area and low-temperature nanodiamond coating by microwave plasma chemical vapor deposition. New Diam. Front. Carbon Technol. 16, 337–346 (2006)

    Google Scholar 

  20. I. Gouzman, Sh. Michaelson, A. Hofman, Nanodiamond films deposited from energetic species: Material characterization and mechanism of formation, in Ultrananocrystalline Diamond, ed. by O.A. Shenderova, D.M. Gruen (Andrew Publ., New York, 2006), pp. 229–272

    Google Scholar 

  21. Sh Michaelson, A. Hoffman, Hydrogen in nano-diamond films. Diam. Relat. Mater. 14, 470–475 (2005)

    Google Scholar 

  22. Sh Michaelson, Y. Lifshitz, O. Ternyak, R. Akhvledian, A. Hoffman, Hydrogen incorporation in diamond films. Diam. Relat. Mater. 16, 845–850 (2007)

    Google Scholar 

  23. T. Sharda, T. Soga, T. Jimbo, M. Umeno, High compressive stress in nanocrystalline diamond films grown by microwave plasma chemical vapor deposition. Diam. Relat. Mater. 10, 352–357 (2001)

    Google Scholar 

  24. D.M. Gruen, A.R. Krauss, C.D. Zuiker, R. Csencisits, L.J. Terminello, J.A. Carlisle, I. Jimenez, D.G.J. Sutherland, D.K. Shuh, W. Tong, F.J. Himpsel, Characterization of nanocrystalline diamond films by core-level photoabsorption. Appl. Phys. Lett. 68, 1640–1642 (1996)

    Google Scholar 

  25. D.M. Gruen, S. Liu, A.R. Krauss, J. Luo, X. Pan, Fullerenes as precursors for diamond film growth without hydrogen or oxygen additions. Appl. Phys. Lett. 64, 1502–1504 (1994)

    Google Scholar 

  26. D.M. Gruen, S. Liu, A.R. Krauss, X. Pan, Buckyball microwave plasmas: fragmentation and diamond-film growth. J. Appl. Phys. 75, 1758–1763 (1994)

    Google Scholar 

  27. F. Benedic, G. Lombardi, K. Hassouni, F. Mohasseb, A. Gicquel, Plasma assisted synthesis: Plasma experimental diagnostics and modelling, in Ultrananocrystalline Diamond, ed. by O.A. Shenderova, D.M. Gruen (Andrew Publ., New York, 2006), pp. 185–228

    Google Scholar 

  28. D. Zhou, D.M. Gruen, L.C. Qin, T.G. McCauley, A.R. Krauss, Control of diamond film microstructure by Ar additions to CH4/H2 microwave plasmas. J. Appl. Phys. 84, 1981–1989 (1998)

    Google Scholar 

  29. C. Zuiker, A.R. Krause, D.M. Gruen, X. Pan, J.C. Li, R. Csencsits, A. Erdemir, C. Bindal, G. Fenske, Physical and tribological properties of diamond films grown in argon carbon plasmas. Thin Solid Films 270, 154–159 (1995)

    Google Scholar 

  30. S. Jiao, A.V. Sumant, M.A. Kirk, D.M. Gruen, A.R. Krauss, O. Auciello, Microstructure of ultrananocrystalline diamond films grown by microwave Ar–CH4 plasma chemical vapor deposition with or without added H2. J. Appl. Phys. 90, 118–122 (2001)

    Google Scholar 

  31. L.C. Qin, D. Zhou, A.R. Krauss, D.M. Gruen, TEM characterization of nanodiamond thin films. Nanostruct. Mater. 10, 649–660 (1998)

    Google Scholar 

  32. O.A. Williams, M. Nesladek, M. Daenen, S. Michaelson, A. Hoffman, E. Osawa, K. Haenen, R.B. Jackman, Growth, electronic properties and applications of nanodiamond. Diam. Relat. Mater. 17, 1080–1088 (2008)

    Google Scholar 

  33. D. Zhou, T.G. McCauley, L.C. Qin, A.R. Krauss, D.M. Gruen, Synthesis of nanocrystalline diamond thin films from an Ar–CH4 microwave plasma. J. Appl. Phys. 83, 540–543 (1998)

    Google Scholar 

  34. P. Keblinski, D. Wolf, S.R. Phillpot, H. Gleiter, Role of bonding and coordination in the atomic structure and energy of diamond and silicon grain boundaries. J. Mater. Res. 13, 2077–2100 (1998)

    Google Scholar 

  35. N.N. Naguib, J.W. Elam, J. Birrell, J. Wang, D.S. Grierson, B. Kabius, J.M. Hiller, A.V. Sumant, R.W. Carpick, O. Auciello, J.A. Carlisle, Enhanced nucleation, smoothness and conformality of ultrananocrystalline diamond (UNCD) ultrathin films via tungsten interlayers. Chem. Phys. Lett. 430, 345–350 (2006)

    Google Scholar 

  36. A.V. Sumant, D.S. Grierson, J.E. Gerbi, J.A. Carlisle, O. Auciello, R.W. Carpick, Surface chemistry and bonding configuration of ultrananocrystalline diamond surfaces and their effects on nanotribological properties. Phys. Rev. B 76, 235429 (2007)

    Google Scholar 

  37. D.M. Gruen, C.D. Zuiker, A.R. Krauss, X.Z. Pan, Carbon dimer, C2, as a growth species for diamond films from methane/hydrogen/argon microwave plasmas. J. Vac. Sci. Technol. A 13, 1628–1632 (1995)

    Google Scholar 

  38. J.R. Rabeau, P. John, J.I.B. Wilson, Y. Fan, The role of C2 in nanocrystalline diamond growth. J. Appl. Phys. 96, 6724–6732 (2004)

    Google Scholar 

  39. P. Zapol, M. Sternberg, L.A. Curtiss, Theoretical studies of UNCD synthesis and properties, in Ultrananocrystalline Diamond, ed. by O.A. Shenderova, D.M. Gruen (Andrew Publ., New York, 2006), pp. 273–302

    Google Scholar 

  40. A.N. Goyette, J.E. Lawler, L.W. Anderson, D.M. Gruen, T.G. McCauley, D. Zhou, A.R. Krauss, Spectroscopic determination of carbon dimer densities in Ar–H2–CH4 and Ar–H2–C60 plasmas. J. Phys. D 31, 1975–1986 (1998)

    Google Scholar 

  41. M. Eckert, E. Neyts, A. Bogaerts, Molecular dynamics simulations of the sticking and etch behavior of various growth species of (ultra) nanocrystalline diamond films. Chem. Vap. Deposition 14, 213–223 (2008)

    Google Scholar 

  42. P.W. May, M.N.R. Ashfold, YuA Mankelevich, Microcrystalline, nanocrystalline, and ultrananocrystalline diamond chemical vapor deposition: Experiment and modeling of the factors controlling growth rate, nucleation, and crystal size. J. Appl. Phys. 101, 053115 (2007)

    Google Scholar 

  43. P.W. May, J.N. Harvey, J.A. Smith, Y.A. Mankelevich, Reevaluation of the mechanism for ultrananocrystalline diamond deposition from Ar/CH4/H2 gas mixtures. J. Appl. Phys. 99, 104907 (2006)

    Google Scholar 

  44. P.W. May, YuA Mankelevich, Experiment and modeling of the deposition of ultrananocrystalline diamond films using hot filament chemical vapor deposition and Ar/CH4/H2 gas mixtures: a generalized mechanism for ultrananocrystalline diamond growth. J. Appl. Phys. 100, 024301 (2006)

    Google Scholar 

  45. C. Popov, W. Kulisch, S. Boycheva, K. Yamamoto, G. Ceccone, Y. Koga, Structural investigation of nanocrystalline diamond/amorphous carbon composite films. Diam. Relat. Mater. 13, 2071–2075 (2004)

    Google Scholar 

  46. C. Popov, W. Kulisch, P.N. Gibson, G. Ceccone, M. Jelinek, Growth and characterization of nanocrystalline diamond/amorphous carbon composite films prepared by MWCVD. Diam. Relat. Mater. 13, 1371–1376 (2004)

    Google Scholar 

  47. L. Sekaric, J.M. Parpia, H.G. Craighead, T. Feygelson, B.H. Houston, J.E. Butler, Nanomechanical resonant structures in nanocrystalline diamond. Appl. Phys. Lett. 81, 4455–4457 (2002)

    Google Scholar 

  48. F.J. Hernandez Guillén, K. Janischowsky, J. Kusterer, W. Ebert, E. Kohn, Mechanical characterization and stress engineering of nanocrystalline diamonds films for MEMS applications. Diam. Relat. Mater. 14, 411–415 (2005)

    Google Scholar 

  49. A. Kriele, O.A. Williams, M. Wolfer, D. Brink, W. Müller-Sebert, C.E. Nebel, Tuneable optical lenses from diamond thin films. Appl. Phys. Lett. 95, 031905 (2009)

    Google Scholar 

  50. H.D. Espinosa, B.C. Prorok, B. Peng, K.H. Kim, N. Moldovan, O. Auciello, J.A. Carlisle, D.M. Gruen, D.C. Mancini, Mechanical properties of ultrananocrystalline diamond thin films relevant to MEMS/NEMS devices. Exp. Mech. 43, 256–269 (2003)

    Google Scholar 

  51. J.T. Paci, T. Belytschko, G.C. Schatz, Mechanical properties of ultrananocrystalline diamond prepared in a nitrogen-rich plasma: a theoretical study. Phys. Rev. B 74, 184112 (2006)

    Google Scholar 

  52. O.A. Williams, A. Kriele, J. Hess, M. Wolfer, W. Müller-Sebert, C.E. Nebel, High Young’s modulus in ultra thin nanocrystalline diamond. Chem. Phys. Lett. 495, 84–89 (2010)

    Google Scholar 

  53. T. Sharda, T. Soga, T. Jimbo, M. Umeno, Growth of nanocrystalline diamond films by biased enhanced microwave plasma chemical vapor deposition. Diam. Relat. Mater. 10, 1592–1596 (2001)

    Google Scholar 

  54. T. Sharda, M. Umeno, T. Soga, T. Jimbo, Growth of nanocrystalline diamond films by biased enhanced microwave plasma chemical vapor deposition: a different regime of growth. Appl. Phys. Lett. 77, 4304–4306 (2000)

    Google Scholar 

  55. M.A. Angadi, T. Watanabe, A. Bodapati, X.C. Xiao, O. Auciello, J.A. Carlisle, J.A. Eastman, P. Keblinski, P.K. Schelling, S.R. Phillpot, Thermal transport and grain boundary conductance in ultrananocrystalline diamond thin films. J. Appl. Phys. 99, 11430 (2006)

    Google Scholar 

  56. O.A. Williams, M. Nesladek, Growth and properties of nanocrystalline diamond films. Physica Status Solidi (a) 203, 3375–3386 (2006)

    Google Scholar 

  57. K.H. Chen, D.M. Bhusari, J.R. Yang, S.T. Lin, T.Y. Wang, L.C. Chen, Highly transparent nano-crystalline diamond films via substrate pretreatment and methane fraction optimization. Thin Solid Films 332, 34–39 (1998)

    Google Scholar 

  58. B. Bi, W.S. Huang, J. Asmussen, B. Golding, Surface acoustic waves on nanocrystalline diamond. Diam. Relat. Mater. 11, 667–680 (2002)

    Google Scholar 

  59. O. Auciello, J. Birrell, J.A. Carlisle, J.E. Gerbi, X. Xiao, B. Peng, H.D. Espinosa, Materials science and fabrication processes for a new MEMS technology based on ultrananocrystalline diamond thin films. J. Phys. Condens. Matter 16, R539–R552 (2004)

    Google Scholar 

  60. O. Auciello, S. Pacheco, A.V. Sumant, Ch. Gudeman, S. Sampath, A. Datta, R.W. Carpick, V.P. Adiga, P. Zurcher, Zh Ma, H-Ch. Yuan, J.A. Carlisle, B. Kabius, J. Hiller, S. Srinivasan, Are diamonds a MEMS’ best friend? IEEE Microwave Mag. 8, 61–75 (2007)

    Google Scholar 

  61. V. Mortet, O. Williams, K. Haenen, Diamond-based acoustic devices, in S. Koizumi, C.E. Nebel, M. Nesladek (eds.), Physics and Applications of CVD Diamond (Wiley, Weinheim, 2008), pp. 177–197

    Google Scholar 

  62. S. Srinivasan, J. Hiller, B. Kabius, O. Auciello, Piezoelectric/ultrananocrystalline diamond heterostructures for high-performance multifunctional micro/nanoelectromechanical systems. Appl. Phys. Lett. 90, 134101 (2007)

    Google Scholar 

  63. A. Hatta, A. Hiraki, Low-temperature diamond deposition, in B. Dischler, Ch. Wild (eds.), Low-Pressure Synthetic Diamond (Springer, Berlin, 1998), pp. 103–118

    Google Scholar 

  64. Y. Muranaka, H. Yamashita, H. Miyadera, Worldwide status of low temperature growth of diamond. Diam. Relat. Mater. 3, 313–318 (1994)

    Google Scholar 

  65. S. Potocky, A. Kromka, J. Potmesil, Z. Remes, Z. Polackova, M. Vanecek, Growth of nanocrystalline diamond films deposited by microwave plasma CVD system at low substrate temperatures. Physica Status Solidi (a) 203, 3011–3015 (2006)

    Google Scholar 

  66. S. Potocky, A. Kromka, J. Potmesil, Z. Remes, V. Vorlicek, M. Vanecek, M. Michalka, Investigation of nanocrystalline diamond films grown on silicon and glass at substrate temperature below 400 °C. Diam. Relat. Mater. 16, 744–747 (2007)

    Google Scholar 

  67. C. Serra, E. Pascual, F. Maass, E. Bertran, J. Esteve, Effect of methane/hydrogen dilution on the properties of hydrogenated amorphous carbon films deposited by RF-plasma. Diam. Relat. Mater. 1, 538–542 (1992)

    Google Scholar 

  68. C.F. Chen, S.H. Chen, H.W. Ko, S.E. Hsu, Low temperature growth of diamond by microwave plasma chemical vapor deposition using CH4 + CO2 gas mixtures. Diam. Relat. Mater. 3, 443–447 (1994)

    Google Scholar 

  69. A. Inspektor, Y. Liou, T. McKenna, R. Messier, Plasma CVD diamond deposition in C–H–O systems. Surf. Coat. Technol. 39–40, 211–221 (1989)

    Google Scholar 

  70. Y. Liou, A. Inspektor, R. Weimer, D. Knight, R. Messier, The effect of oxygen in diamond deposition by microwave plasma enhanced chemical vapor deposition. J. Mater. Res. 5, 2305–2312 (1990)

    Google Scholar 

  71. J.R. Petherbridge, P.W. May, S.R.J. Pearc, K.N. Rosser, M.N.R. Ashfold, Low temperature diamond growth using CO2/CH4 plasmas: molecular beam mass spectrometry and computer simulation investigations. J. Appl. Phys. 89, 1484–1492 (2001)

    Google Scholar 

  72. Z. Remes, Y. Avigal, R. Kalish, C. Uzan-Saguy, A. Chack, M. Nesládek, Structural, optical and electrical properties of nanodiamond films deposited by HFCVD on borosilicate glass, fused silica and silicon at low temperature. Physica Status Solidi (a) 201, 2499–2502 (2004)

    Google Scholar 

  73. J. Stiegler, T. Lang, M. Nygard-Ferguson, Y. von Kaenel, E. Blank, Low temperature limits of diamond film growth by microwave plasma-assisted CVD. Diam. Relat. Mater. 5, 226–230 (1996)

    Google Scholar 

  74. D.L. Youchison, C.R. Eddy, B.D. Startwell, Role of oxygen in the electron cyclotron resonance plasma-assisted chemical vapor deposition of diamond films. J. Vac. Sci. Technol. A 11, 1875–1880 (1993)

    Google Scholar 

  75. J. Lee, R.W. Collins, R. Messier, Y.E. Straussner, Low temperature plasma process based on CO-rich CO/H2 mixtures for high rate diamond film deposition. Appl. Phys. Lett. 70, 1527–1529 (1997)

    Google Scholar 

  76. F. Piazza, G. Morell, Synthesis of diamond at sub 300 °C substrate temperature. Diam. Relat. Mater. 16, 1950–1957 (2007)

    Google Scholar 

  77. M. Asmann, J. Heberlein, E. Pfender, A review of diamond CVD utilizing halogenated precursors. Diam. Relat. Mater. 8, 1–16 (1999)

    Google Scholar 

  78. I. Schmidt, C. Benndorf, Low temperature CVD diamond deposition using halogenated precursors - deposition on low melting materials: Al, Zn and glass. Diam. Relat. Mater. 10, 347–351 (2001)

    Google Scholar 

  79. Q. Yang, S. Yang, Y.S. Li, X. Lu, A. Hirose, NEXAFS characterization of nanocrystalline diamond thin films synthesized with high methane concentrations. Diam. Relat. Mater. 16, 730–734 (2007)

    Google Scholar 

  80. M. Yuasa, O. Arakaki, J.S. Ma, A. Hiraki, H. Kawarada, Low temperature diamond film fabrication using magneto-active plasma CVD. Diam. Relat. Mater. 1, 168–174 (1992)

    Google Scholar 

  81. L. Dong, B. Ma, G. Dong, Diamond deposition at low temperature by using CH4/H2 gas mixture. Diam. Relat. Mater. 11, 1697–1702 (2002)

    Google Scholar 

  82. X. Xiao, J. Birrell, J.E. Gerbi, O. Auciello, J.A. Carlisle, Low temperature growth of ultrananocrystalline diamond. J. Appl. Phys. 96, 2232–2239 (2004)

    Google Scholar 

  83. G. Amaratunga, A. Putnis, K. Clay, W. Milne, Crystalline diamond growth in thin films deposited from a CH4/Ar rf plasma. Appl. Phys. Lett. 55, 634–635 (1989)

    Google Scholar 

  84. S.R.P. Silva, G.A.J. Amaratunga, E.K.H. Salje, K.M. Knowles, Evidence of hexagonal diamond in plasma-deposited carbon films. J. Mater. Sci. 29, 4962–4966 (1994)

    Google Scholar 

  85. J.M. Lopez, F.J. Gordillo-Vazquez, J.M. Albella, Nanocrystalline diamond thin films deposited by 45 kHz Ar-rich plasmas. Appl. Surf. Sci. 185, 321–325 (2002)

    Google Scholar 

  86. X.T. Zhou, X.M. Meng, F.Y. Meng, Q. Li, I. Bello, W.J. Zhang, C.S. Lee, S.T. Lee, Y. Lifshitz, Formation and structure of a-C/nanodiamond composite films by prolonged bias enhanced nucleation. Diam. Relat. Mater. 12, 1640–1646 (2003)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2018 Springer-Verlag GmbH Germany

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Schultrich, B. (2018). Nanodiamond Films. In: Tetrahedrally Bonded Amorphous Carbon Films I. Springer Series in Materials Science, vol 263. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-55927-7_3

Download citation

Publish with us

Policies and ethics