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Application of Solid-Phase Microextraction in Soil and Sediment Sampling

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Solid Phase Microextraction

Abstract

Solid-phase microextraction (SPME) has been widely applied in environmental analysis and received increasing attention in the sampling of soil/sediment due to its recognized advantages over the traditional methods. In this chapter, recent development of SPME for soil/sediment sampling is summarized. The method development including the selection of sampling formats, fiber coatings, extraction-phase geometries, and calibration methods is discussed in detail. Finally, the application of SPME for sensing of the freely dissolved organic compounds in pore water; the determination of the partition coefficients of organic pollutants between the sediment and pore water; the characterization of the bioavailability of organic pollutants in the soil/sediment; and the use as a biomimetic tool are reviewed.

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Abbreviations

BCF:

Bioconcentration factor

BFRs:

Brominated flame retardants

BTEX:

Benzene, toluene, ethylbenzene, xylene

CAR/PDMS:

Carboxen/polydimethylsiloxane

CE:

Capillary electrophoresis

CW/DVB:

Carbowax/divinylbenzene

CW:

Carbon wax

DI:

Direct immersion

DVB:

Divinylbenzene

EC:

Equilibrium calibration

ECC:

External calibration curve

EVA:

Ethylene-vinyl acetate

GC:

Gas chromatography

HOCs:

Hydrophobic organic compounds

HS:

Headspace

IL:

Ionic liquid

IMS:

Ion mass spectrometry

IS:

Internal standard

LC:

Liquid chromatography

LOD:

Limit of detection

LOQ:

Limit of quantification

MDL:

Method detection limit

MS:

Mass spectrometry

MWA:

Microwave-assisted

OCPs:

Organochlorine pesticides

OS:

Ultrasound

PA:

Polyacrylate

PAHs:

Polyaromatic hydrocarbon

PBDEs:

Polybrominated diphenyl ethers

PCBs:

Polychlorinated biphenyls

PCRs:

Performance reference compounds

PDMS:

Polydimethylsiloxane

PHW:

Pressured hot water

PPy:

Dodecylsulfate-doped polypyrrole

SBSE:

Stir bar sorptive extraction

SPME:

Solid-phase microextraction

TNT:

Trinitrotoluene

USA:

Ultrasonic-assisted

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Acknowledgement

We acknowledge financial support from the projects of NNSFC (Grants 21407184, 21225731, 21377172, and 21477166) and the NSF of Guangdong Province (Grant S2013030013474).

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Authors and Affiliations

  1. School of Environment, Guangzhou Key Laboratory of Environmental Exposure and Health, and Guangdong Key Laboratory of Environmental Pollution and Health, Jinan University, Guangzhou, 510632, People’s Republic of China

    Ruifen Jiang

  2. MOE Key Laboratory of Aquatic Product Safety/KLGHEI of Environment and Energy Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, People’s Republic of China

    Gangfeng Ouyang

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  1. Ruifen Jiang
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  2. Gangfeng Ouyang
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Correspondence to Gangfeng Ouyang .

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Editors and Affiliations

  1. School of Chemistry, Sun Yat-sen University, Guangzhou, Guangdong, China

    Gangfeng Ouyang

  2. School of Environment, Jinan University, Guangzhou, Guangdong, China

    Ruifen Jiang

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Jiang, R., Ouyang, G. (2017). Application of Solid-Phase Microextraction in Soil and Sediment Sampling. In: Ouyang, G., Jiang, R. (eds) Solid Phase Microextraction. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-53598-1_6

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