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Recent Advances in Non-directed C(sp3)–H Bond Functionalization

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Sustainable C(sp3)-H Bond Functionalization

Part of the book series: SpringerBriefs in Molecular Science ((GREENCHEMIST))

Abstract

Selective functionalization of one specific C(sp3)–H bond in a complex molecule without the assistance of a directing group represents the state of the art in organic synthesis and will be a dynamic topic in future. In the past decade, many excellent methods have been developed to accomplish this goal with transition-metal catalysts and even under metal-free conditions. In this chapter, we summarize the recent achievements in this realm during the past 5 years, including oxidative functionalization of α-C(sp3)–H bonds adjacent to heteroatoms, allylic, benzylic, and unactivated aliphatic C(sp3)–H bonds. The total redox-neutral C(sp3)–H bond functionalization is also briefly introduced.

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Acknowledgments

The National Natural Science Foundation of China (No. 21372114, 21172106), and the Research Fund for the Doctoral Program of Higher Education of China (20120091110010) and the Brand Major Project of Jiangsu Province are kindly acknowledged.

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  1. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China

    Jin Xie & Chengjian Zhu

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Xie, J., Zhu, C. (2016). Recent Advances in Non-directed C(sp3)–H Bond Functionalization. In: Sustainable C(sp3)-H Bond Functionalization. SpringerBriefs in Molecular Science(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-49496-7_2

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