Advertisement

Effects of Different Mg/Ti Ratios on the Electrochemical Hydrogen Storage Properties of MgxTi1−x–Pd Films

  • Gongbiao XinEmail author
Chapter
  • 306 Downloads
Part of the Springer Theses book series (Springer Theses)

Abstract

Other than the gaseous hydrogen storage properties, metals, and alloys can also store hydrogen by electrochemical methods. At present, hydrogen storage alloys are used as the negative electrode materials in nickel-metal hydride (Ni–MH) batteries, which is a significant application. As the negative electrodes, the hydrogen storage alloys significantly affect the overall charge-discharge properties of Ni–MH.

Keywords

Discharge Capacity Hydrogen Storage Hydrogen Storage Alloy Hydrogen Storage Property Maximum Discharge Capacity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Li XF, Wang LZ, Dong HC et al (2012) Electrochemical hydrogen absorbing properties of graphite/AB5 alloy composite electrode. J Alloys Compd 510:114–118CrossRefGoogle Scholar
  2. 2.
    Boussami S, Khaldi C, Lamloumi J et al (2012) Electrochemical study of LaNi3.55Mn0.4Al0.3Fe0.75 as negative electrode in alkaline secondary batteries. Electrochim Acta 69:203–208CrossRefGoogle Scholar
  3. 3.
    Bliznakov S, Lefterova E, Dimitrov N et al (2008) A study of the Al content impact on the properties of MmNi4.4−xCo0.6Alx alloys as precursors for negative electrodes in Ni-MH batteries. J Power Sources 176:381–386CrossRefGoogle Scholar
  4. 4.
    Liao B, Lei YQ, Lu GL et al (2004) Effect of the La/Mg ratio on the structure and electrochemical properties of LaxMg3−xNi9 (x = 1.6–2.2) hydrogen storage electrode alloys for nickel-metal hydride batteries. J Power Sources 129:358–367CrossRefGoogle Scholar
  5. 5.
    Liu YF, Pan HG, Gao MX et al (2004) The effect of Mn substitution for Ni on the structural and electrochemical properties of La0.7Mg0.3Ni2.55−xCo0.45Mnx hydrogen storage electrode alloys. Int J Hydrogen Energy 29:297–305CrossRefGoogle Scholar
  6. 6.
    Dong ZW, Ma LQ, Shen XD et al (2011) Cooperative effect of Co and Al on the microstructure and electrochemical properties of AB3-type hydrogen storage electrode alloys for advanced MH/Ni secondary battery. Int J Hydrogen Energy 36:893–900CrossRefGoogle Scholar
  7. 7.
    Ovshinsky SR, Fetcenko MA, Ross J (1993) A nickel metal hydride battery for electric vehicles. Science 260:176–181CrossRefGoogle Scholar
  8. 8.
    Zhao XY, Li JJ, Yao Y et al (2012) Electrochemical hydrogen storage properties of a non-equilibrium Ti2Ni alloy. RSC Adv 2:2149–2153CrossRefGoogle Scholar
  9. 9.
    Zhao XY, Zhou JF, Shen XD et al (2012) Structure and electrochemical hydrogen storage properties of A2B-type Ti–Zr–Ni alloys. Int J Hydrogen Energy 37:5050–5055CrossRefGoogle Scholar
  10. 10.
    Xu JL, Niu D, Fan YJ et al (2012) Electrochemical hydrogen storage performance of Mg2−xAlxNi thin films. J Power Sources 198:383–388CrossRefGoogle Scholar
  11. 11.
    Anik M, özdemir G, Küçükdeveci N (2011) Electrochemical hydrogen storage characteristics of Mg–Pd–Ni ternary alloys. Int J Hydrogen Energy 36:6744–6750CrossRefGoogle Scholar
  12. 12.
    Xiao XZ, Chen LX, Hang ZM et al (2009) Microstructures and electrochemical hydrogen storage properties of novel Mg–Al–Ni amorphous composites. Electrochem Commun 11:515–518CrossRefGoogle Scholar
  13. 13.
    Jain PI, Lal C, Jain A (2010) Hydrogen storage in Mg: a most promising material. Int J Hydrogen Energy 35:5133–5144CrossRefGoogle Scholar
  14. 14.
    Fu Y, Kulenovic R, Mertz R (2008) The cycle stability of Mg-based nanostructured materials. J Alloys Compd 464:374–376CrossRefGoogle Scholar
  15. 15.
    Vermeulen P, Niessen RAH, Notten PHL (2006) Hydrogen storage in metastable MgyTi(1−y) thin films. Electrochem Commun 8:27–32CrossRefGoogle Scholar
  16. 16.
    Xin GB, Yang JZ, Fu H et al (2013) Pd capped MgxTi1−x films: promising anode materials for alkaline secondary batteries with superior discharge capacities and cyclic stabilities. Int J Hydrogen Energy 38:10625–10629CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  1. 1.College of Chemistry and Molecular EngineeringPeking UniversityBeijingChina

Personalised recommendations