Abstract
Graphene, as a two-dimensional crystal of sp2 conjugated carbon atoms, is viewed as a building block for carbonaceous materials of other dimensionalities including zero-dimensional fullerenes, one-dimensional carbon nanotubes, and three-dimensional (3D) graphite [1].
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, et al. Electric field effect in atomically thin carbon films. Science. 2004;306(5696):666–9.
Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia YY, et al. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon. 2007;45(7):1558–65.
Wei W, Yang SB, Zhou HX, Lieberwirth I, Feng XL, Müllen K. 3D graphene foams cross-linked with pre-encapsulated Fe3O4 nanospheres for enhanced lithium storage. Adv Mater. 2013;22:2909–14.
Gong YJ, Yang SB, Zhan L, Ma LL, Vajtai R, Ajayan PM. A bottom-up approach to build 3D architectures from nanosheets for superior lithium storage. Adv Funct Mater. 2014;24:125–30.
Dikin DA, Stankovich S, Zimney EJ, Piner RD, Dommett GHB, Evmenenko G, et al. Preparation and characterization of graphene oxide paper. Nature. 2007;448(7152):457–60.
Chen CM, Yang QH, Yang YG, Lv W, Wen YF, Hou PX, et al. Self-assembled free-standing graphite oxide membrane. Adv Mater. 2009;21(29):3007–11.
Kim F, Cote LJ, Huang JX. Graphene oxide: Surface activity and two-dimensional assembly. Adv Mater. 2010;22(17):1954–8.
Xu YX, Bai H, Lu GW, Li C, Shi GQ. Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets. J Am Chem Soc 2008; 130(18): 5856.
An SJ, Zhu YW, Lee SH, Stoller MD, Emilsson T, Park S, et al. Thin film fabrication and simultaneous anodic reduction of deposited graphene oxide platelets by electrophoretic deposition. J Phys Chem Lett. 2010;1(8):1259–63.
Yang XW, Zhu JW, Qiu L, Li D. Bioinspired effective prevention of restacking in multilayered graphene films: Towards the next generation of high-performance supercapacitors. Adv Mater. 2011;23(25):2833–8.
Liu F, Seo TS. A controllable self-assembly method for large-scale synthesis of graphene sponges and free-standing graphene films. Adv Funct Mater. 2010;20(12):1930–6.
Xu YX, Sheng KX, Li C, Shi GQ. Self-assembled graphene hydrogel via a one-step hydrothermal process. ACS Nano. 2010;4(7):4324–30.
Lee SH, Kim HW, Hwang JO, Lee WJ, Kwon J, Bielawski CW, et al. Three-dimensional self-assembly of graphene oxide platelets into mechanically flexible macroporous carbon films. Angew Chem Int Ed. 2010;49(52):10084–8.
Tang ZH, Shen SL, Zhuang J, Wang X. Noble-metal-promoted three-dimensional macroassembly of single-layered graphene oxide. Angew Chem Int Ed. 2010;49(27):4603–7.
Chen ZP, Ren WC, Gao LB, Liu BL, Pei SF, Cheng HM. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapor deposition. Nat Mater. 2011;10(6):424–8.
Liu QF, Ishibashi A, Fujigaya T, Mimura K, Gotou T, Uera K, et al. Formation of self-organized graphene honeycomb films on substrates. Carbon. 2011;49(11):3424–9.
Fan ZJ, Yan J, Zhi LJ, Zhang Q, Wei T, Feng J, et al. A three-dimensional carbon nanotube/graphene sandwich and its application as electrode in supercapacitors. Adv Mater. 2010;22(33):3723–8.
Lv RT, Cui TX, Jun MS, Zhang Q, Cao AY, Su DS, et al. Open-ended, N-doped carbon nanotube-graphene hybrid nanostructures as high-performance catalyst support. Adv Funct Mater. 2011;21(5):999–1006.
Chen CM, Yang YG, Wen YF, Yang QH, Wang MZ. Preparation of ordered graphene-based conductive membrane. New Carbon Mater. 2008;23(4):345–50.
Pham VH, Cuong TV, Hur SH, Shin EW, Kim JS, Chung JS, et al. Fast and simple fabrication of a large transparent chemically-converted graphene film by spray-coating. Carbon. 2010;48(7):1945–51.
Xu YF, Long GK, Huang L, Huang Y, Wan XJ, Ma YF, et al. Polymer photovoltaic devices with transparent graphene electrodes produced by spin-casting. Carbon. 2010;48(11):3308–11.
Li XL, Zhang GY, Bai XD, Sun XM, Wang XR, Wang E, et al. Highly conducting graphene sheets and Langmuir-Blodgett films. Nat Nanotechnol. 2008;3(9):538–42.
Schniepp HC, Li JL, McAllister MJ, Sai H, Herrera-Alonso M, Adamson DH, et al. Functionalized single graphene sheets derived from splitting graphite oxide. J Phys Chem B. 2006;110(17):8535–9.
Eda G, Fanchini G, Chhowalla M. Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material. Nat Nanotechnol. 2008;3(5):270–4.
Yang D, Velamakanni A, Bozoklu G, Park S, Stoller M, Piner RD, et al. Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy. Carbon. 2009;47(1):145–52.
Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, et al. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon. 2007;45(7):1558–65.
Xu YX, Sheng KX, Li C, Shi GQ. Highly conductive chemically converted graphene prepared from mildly oxidized graphene oxide. J Mater Chem. 2011;21(20):7376–80.
Shin HJ, Kim KK, Benayad A, Yoon SM, Park HK, Jung IS, et al. Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance. Adv Funct Mater. 2009;19(12):1987–92.
Pei SF, Zhao JP, Du JH, Ren WC, Cheng HM. Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids. Carbon. 2010;48(15):4466–74.
Fan ZJ, Wang K, Wei T, Yan J, Song LP, Shao B. An environmentally friendly and efficient route for the reduction of graphene oxide by aluminum powder. Carbon. 2010;48(5):1686–9.
Gao W, Alemany LB, Ci LJ, Ajayan PM. New insights into the structure and reduction of graphite oxide. Nat Chem. 2009;1(5):403–8.
Hummers WS, Offeman RE. Preparation of graphitic oxide. J Am Chem Soc. 1958;80(6):1339.
Liu YZ, Li YF, Yang YG, Wen YF, Wang MZ. The effect of thermal treatment at low temperatures on graphene oxide films. New Carbon Mater. 2011;26(1):41–5.
Moon IK, Lee J, Ruoff RS, Lee H. Reduced graphene oxide by chemical graphitization. Nat Comm. 2010;1:73.
Liu J, Jeong H, Liu J, Lee K, Park JY, Ahn YH, et al. Reduction of functionalized graphite oxides by trioctylphosphine in non-polar organic solvents. Carbon. 2010;48(8):2282–9.
Liu JQ, Lin ZQ, Liu TJ, Yin ZY, Zhou XZ, Chen SF, et al. Multilayer stacked low-temperature-reduced graphene oxide films: Preparation, characterization, and application in polymer memory devices. Small. 2010;6(14):1536–42.
Lai LF, Chen LW, Zhan D, Sun L, Liu JP, Lim SH, et al. One-step synthesis of NH2-graphene from in situ graphene-oxide reduction and its improved electrochemical properties. Carbon. 2011;49(10):3250–7.
Peng X-Y, Liu X-X, Diamond D, Lau KT. Synthesis of electrochemically-reduced graphene oxide film with controllable size and thickness and its use in supercapacitor. Carbon. 2011;49(11):3488–96.
Yan J, Wei T, Shao B, Ma FQ, Fan ZJ, Zhang ML, et al. Electrochemical properties of graphene nanosheet/carbon black composites as electrodes for supercapacitors. Carbon. 2010;48(6):1731–7.
Oberlin A. Carbonization and graphitization. Carbon. 1984;22(6):521–41.
Figueiredo JL, Pereira MFR, Freitas MMA, Orfao JJM. Modification of the surface chemistry of activated carbons. Carbon. 1999;37(9):1379–89.
Bagri A, Mattevi C, Acik M, Chabal YJ, Chhowalla M, Shenoy VB. Structural evolution during the reduction of chemically derived graphene oxide. Nat Chem. 2010;2(7):581–7.
Chen CM, Huang JQ, Zhang Q, Gong WZ, Yang QH, Wang MZ, et al. Annealing a graphene oxide film to produce a free standing high conductive graphene film. Carbon. 2012;50(2):659–67.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2016 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Chen, CM. (2016). Free-Standing Graphene Film with High Conductivity by Thermal Reduction of Self-assembled Graphene Oxide Film. In: Surface Chemistry and Macroscopic Assembly of Graphene for Application in Energy Storage. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-48676-4_4
Download citation
DOI: https://doi.org/10.1007/978-3-662-48676-4_4
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-48674-0
Online ISBN: 978-3-662-48676-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)