Abstract
This chapter addresses some special topics which are particularly relevant for current research involving cold atoms and molecules. Section 4.1 on deep potentials falling off faster than \(1/r^{ 2}\) at large distances contains a general theory for the description of near-threshold bound and continuum states, which is well suited for application to realistic binary systems such as diatomic molecules or molecular ions. Section 4.2 connects the well established theory of Feshbach resonances with the empirical description which has become widely used in the cold-atoms community, and it formulates a threshold-insensitive parametrization of the Feshbach resonances which is relevant for the analysis of current experiments. The last section contains a short treatise on two-dimensional scattering, which reveals significant differences to the 3D case, in particular in the low-energy, near-threshold regime.
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Notes
- 1.
Noninteger values of \(l\) are not merely of academic interest. They can describe the effects of inverse-square potentials of other origin than the centrifugal term. In two-dimensional scattering described in Sect. 4.3, the radial Schrödinger equation with integer angular momentum quantum number \(m\) resembles that of the 3D case when \(l=\vert m\vert-{1\over 2}\).
- 2.
Due to the \(m\)-independent term \({\pi\over 4}\) appearing in the arguments both of \(u_{m}^{(\mathrm{s})}(kr)\) and of \(u_{m}^{(\mathrm{c})}(kr)\) in (4.217), there is no a priori preference for the assignment of an asymptotic “sine-” or “cosine-like” behaviour. The present nomenclature is chosen to make the connection to the 3D case as transparent as possible.
- 3.
References
Adhikari, S.K.: Quantum scattering in two dimensions. Am. J. Phys. 54, 362 (1986)
Anderson, M.H., Ensher, J.R., Matthews, M.R., Wieman, C.E., Cornell, E.A.: Observation of Bose–Einstein condensation in a dilute atomic vapor. Science 269, 198 (1995)
Arnecke, F., Friedrich, H., Madroñero, J.: Effective-range expansion for quantum reflection amplitudes. Phys. Rev. A 74, 062702 (2006)
Arnecke, F., Friedrich, H., Madroñero, J.: Scattering of ultracold atoms by absorbing nanospheres. Phys. Rev. A 75, 042903 (2007)
Arnecke, F., Friedrich, H., Raab, P.: Near-threshold scattering, quantum reflection, and quantization in two dimensions. Phys. Rev. A 78, 052711 (2008)
Ball, P.: Lost correspondence. Nature (1999). doi:10.1038/news991202-2, http://www.nature.com/news/1999/991126/full/news991202-2.html
Barton, G.: Rutherford scattering in two dimensions. Am. J. Phys. 51, 420 (1982)
Boisseau, C., Audouard, E., Vigué, J.: Comment on “Breakdown of Bohr’s correspondence principle”. Phys. Rev. Lett. 86, 2694 (2001)
Barton, G.: Frequency shifts near an interface: inadequacy of two-level atomic models. J. Phys. B 7, 2134 (1974)
Böheim, J., Brenig, W., Stutzki, J.: On the low energy limit of reflection and sticking coefficients in atom-surface scattering II: Long range forces. Z. Phys. B 48, 43 (1982). Erratum: Z. Phys. B 49, 362 (1983)
Berry, M.V., Mount, K.E.: Semiclassical approximations in wave mechanics. Rep. Prog. Phys. 35, 315 (1972)
Brenig, W.: Low-energy limit of reflection and sticking coefficients in atom surface scattering: 1. Short-range forces. Z. Phys. B 36, 227 (1980)
Bodo, E., Zhang, P., Dalgarno, A.: Ultra-cold ion–atom collisions: near resonant charge exchange. New J. Phys. 10, 033024 (2008)
Chin, C., Grimm, R., Julienne, P., Tiesinga, E.: Feshbach resonances in ultracold gase. Rev. Mod. Phys. 82, 1225 (2010)
Côté, R., Heller, E.J., Dalgarno, A.: Quantum suppression of cold atomic collisions. Phys. Rev. A 53, 234 (1996)
Carbonell, J., Lasauskas, R., Delande, D., Hilico, L., Kiliç, S.: A new vibrational level of the \(\mathrm{H}_{2}^{ +}\) molecular ion. Europhys. Lett. 64, 316 (2003)
Crubellier, A., Luc-Koenig, E.: Threshold effects in the photoassociation of cold atoms: R-6 model in the Milne formalism. J. Phys. B 39, 1417 (2006)
Clougherty, D.P., Kohn, W.: Quantum theory of sticking. Phys. Rev. B 46, 4921 (1992)
Casimir, H.B.G., Polder, D.: The influence of retardation on the London–van der Waals forces. Phys. Rev. 73, 360 (1948)
Côté, R., Segev, B.: Quantum reflection engineering: the bichromatic evanescent-wave mirror. Phys. Rev. A 67, 041604(R) (2003)
Druzhinina, V., DeKieviet, M.: Experimental observation of quantum reflection far from threshold. Phys. Rev. Lett. 91, 193202 (2003)
Del Giudice, E., Galzenati, E.: On singular potential scattering I. Nuovo Cimento 38, 435 (1965)
Dalfovo, F., Giorgini, S., Guilleumas, M., Pitaevskii, L., Stringari, S.: Collective and single-particle excitations of a trapped Bose gas. Phys. Rev. A 56, 3840 (1997)
Dickinson, A.S.: Quantum reflection model for ionization rate coefficients in cold metastable helium collisions. J. Phys. B 40, F237 (2007)
Davis, K.B., Mewes, M.-O., Andrews, M.R., van Druten, N.J., Durfee, D.S., Kurn, D.M., Ketterle, W.: Bose–Einstein condensation in a gas of sodium atoms. Phys. Rev. Lett. 75, 3969 (1995)
Dashevskaya, E.I., Maergoiz, A.I., Troe, J., Litvin, I., Nikitin, E.E.: Low-temperature behavior of capture rate constants for inverse power potentials. J. Chem. Phys. 118, 7313 (2003)
Damburg, R.J., Propin, R.K.: On asymptotic expansions of electronic terms of the molecular ion \(\mathrm{H}_{2}^{+}\). J. Phys. B 1, 681 (1968)
Docenko, O., Tamanis, M., Zaharova, J., Ferber, R., Pashov, A., Knöckel, H., Tiemann, E.: The coupling of the \(\mathrm{X}^{1}\varSigma^{+}\) and \(\mathrm{a}^{3}\varSigma^{+}\) states of the atom pair Na + Cs and modelling cold collisions. J. Phys. B 39, S929 (2006)
Eltschka, C., Friedrich, H., Moritz, M.J.: Comment on “Breakdown of Bohr’s correspondence principle”. Phys. Rev. Lett. 86, 2693 (2001)
Fink, M., Eiglsperger, J., Madroñero, J., Friedrich, H.: Influence of retardation in the scattering of ultracold atoms by conducting nanowires. Phys. Rev. A 85, 040702(R) (2012); Fink, M.: Scattering and Absorption of Ultracold Atoms by Nanotubes. Doctoral thesis, Technical University Munich (2013): http://mediatum.ub.tum.de/doc/1141600/1141600.pdf
Flambaum, V.V., Gribakin, G., Harabati, C.: Analytical calculation of cold-atom scattering. Phys. Rev. A 59, 1998 (1999)
Friedrich, H., Jurisch, A.: Quantum reflection times for attractive potential tails. Phys. Rev. Lett. 92, 103202 (2004)
Friedrich, H., Jacoby, G., Meister, C.G.: Quantum reflection by Casimir van der Waals potential tails. Phys. Rev. A 65, 032902 (2002)
Friedrich, H.: Theoretical Atomic Physics, 2nd edn. Springer, Berlin (1998). 3rd. Ed. 2006
Friedrich, H., Trost, J.: Working with WKB waves far from the semiclassical limit. Phys. Rep. 397, 359 (2004)
Gribakin, G.F., Flambaum, V.V.: Calculation of the scattering length in atomic collisions using the semiclassical approximation. Phys. Rev. A 48, 546 (1993)
Gao, B.: Quantum-defect theory of atomic collisions and molecular vibration spectra. Phys. Rev. A 58, 4222 (1998)
Gao, B.: Breakdown of Bohr’s correspondence principle. Phys. Rev. Lett. 83, 4225 (1999)
Gao, B.: General form of the quantum-defect theory for \(-1/r^{ \alpha}\) type of potentials with \(\alpha>2\). Phys. Rev. A 78, 012702 (2008)
Gao, B.: Universal properties in ultracold ion–atom interactions. Phys. Rev. Lett. 104, 231201 (2010)
Greene, C., Fano, U., Strinati, G.: General form of quantum defect theory. Phys. Rev. A 19, 1485 (1979)
Giusti, A.: A multichannel quantum defect approach to dissociative recombination. J. Phys. B 13, 3867 (1980)
Greene, C.H., Rau, A.R.P.: General form of the quantum-defect theory. II. Phys. Rev. A 26, 2441 (1982)
Gao, B., Tiesinga, E., Williams, C.J., Julienne, P.S.: Multichannel quantum-defect theory for slow atomic collisions. Phys. Rev. A 72, 042719 (2005)
Hilico, L., Billy, N., Grémaud, B., Delande, D.: Ab initio calculation of the \(J=0\) and \(J=1\) states of the \(\mathrm{H}_{2}^{+}\), \(\mathrm{D}_{2}^{+}\) and \(\mathrm{HD}^{+}\) molecular ions. Eur. Phys. J. D 12, 449 (2000)
Huang, K., Yang, C.N.: Quantum-mechanical many-body problem with hard-sphere interaction. Phys. Rev. A 105, 767 (1957)
Johnson, S.: Life of Abraham Cowley. In: Lonsdale, R. (ed.) The Lives of the Most Eminent English Poets. Oxford University Press, Oxford (2006). (First published 1781)
Khuri, N.N., Martin, A., Richard, J.-M., Wu, T.T.: Low-energy potential scattering in two and three dimensions. J. Math. Phys. 50, 072105 (2009)
Kaiser, A., Müller, T.-O., Friedrich, H.: Influence of higher-order dispersion coefficients on near-threshold bound and continuum states: application to 88Sr2. J. Chem. Phys. 135, 214302 (2011)
Kaiser, A., Müller, T.-O., Friedrich, H.: Quantisation rule for highly excited vibrational states of \(\mathrm{H}_{2}^{+}\). Mol. Phys. 111, 878 (2013)
Lapidus, I.R.: Quantum-mechanical scattering in two dimensions. Am. J. Phys. 50, 45 (1982)
LeRoy, R.J., Bernstein, R.B.: Dissociation energy and long-range potential of diatomic molecules from vibrational spacings of higher levels. J. Chem. Phys. 52, 3869 (1970)
Lemeshko, M., Friedrich, B.: Rotational and rotationless states of weakly bound molecules. Phys. Rev. A 79, 050501 (2009)
Lemeshko, M., Friedrich, B.: Rotational structure of weakly bound molecular ions. J. At. Mol. Sci. 1, 39 (2010)
Landau, L.D., Lifschitz, E.M.: Quantenmechanik. Theoretische Physik, vol. 3, p. 81. Akademie-Verlag, Berlin (1965)
Laue, T., Tiesinga, E., Samuelis, C., Knöckel, H., Tiemann, E.: Magnetic-field imaging of weakly bound levels of the ground-state Na2 dimer. Phys. Rev. A 65, 023412 (2002)
Marinescu, M., Dalgarno, A., Babb, J.F.: Retarded long-range potentials for the alkali-metal atoms and a perfectly conducting wall. Phys. Rev. A 55, 1530 (1997)
Moritz, M.J., Eltschka, C., Friedrich, H.: Threshold properties of attractive and repulsive inverse-square potentials. Phys. Rev. A 63, 042101 (2001)
Moritz, M.J., Eltschka, C., Friedrich, H.: Near-threshold quantization and level densities for potential wells with weak inverse-square tail. Phys. Rev. A 64, 022101 (2001)
Madroñero, J., Friedrich, H.: Influence of realistic atom wall potentials in quantum reflection traps. Phys. Rev. A 75, 022902 (2007)
Mody, A., Haggerty, M., Doyle, J.M., Heller, E.J.: No-sticking effect and quantum reflection in ultracold collisions. Phys. Rev. B 64, 085418 (2001)
Müller, T.-O., Friedrich, H.: Near-threshold quantization for potentials with inverse-cube tails. Phys. Rev. 83, 022701 (2011)
Mies, F.: A multichannel quantum defect analysis of diatomic predissociation and inelastic atomic scattering. J. Chem. Phys. 80, 2514 (1984)
Mies, F., Julienne, P.S.: A multichannel quantum defect analysis of two-state couplings in diatomic molecules. J. Chem. Phys. 80, 2526 (1984)
Müller, T.-O., Kaiser, A., Friedrich, H.: \(s\)-Wave scattering for deep potentials with attractive tails falling off faster than \(-1/r^{ 2}\). Phys. Rev. 84, 032701 (2011)
Müller, T.-O., Kaiser, A., Friedrich, H.: Addendum to “\(s\)-Wave scattering for deep potentials with attractive tails falling off faster than \(-1/r^{ 2}\)”. Phys. Rev. 84, 054702 (2011)
Müller, T.-O.: Threshold law far attractive inverse-cube interactions. Phys. Rev. Lett. 110, 260401 (2013)
Moerdijk, A.J., Verhaar, B.J., Axelsson, A.: Resonances in ultracold collisions of 6Li, 7Li, and 23Na. Phys. Rev. A 51, 4852 (1995)
Madison, K.W., Wang, Y., Rey, A.M., Bongs, K. (eds.): Annual Review of Cold Atoms and Molecules, vol. 1. World Scientific, Singapore (2013)
Oberst, H., Kouznetsov, D., Shimizu, K., Fujita, J., Shimizu, F.: Fresnel diffraction mirror for an atomic wave. Phys. Rev. Lett. 94, 013203 (2005)
Peek, J.M.: Eigenparameters for the \(1s\sigma g\) and \(2p\sigma u\) orbitals of \(\mathrm{H}_{2}^{ +}\). J. Chem. Phys. 43, 3004 (1965)
Paulsson, R., Karlsson, F., LeRoy, R.J.: Reliability of high-order phase integral eigenvalues for single and double minimum potentials. J. Chem. Phys. 79, 4346 (1983)
Phys. Rev. Focus: Apply quantum principle with caution, http://prlo.aps.org/story/v4/st26 (1999)
Pasquini, T., Shin, Y., Sanner, C., Saba, M., Schirotzek, A., Pritchard, D.E., Ketterle, W.: Quantum reflection from a solid surface at normal incidence. Phys. Rev. Lett. 93, 223201 (2004)
Quémener, G., Julienne, P.S.: Ultracold molecules under control. Chem. Rev. 112, 4949 (2012)
Raab, P., Friedrich, H.: Quantization function for deep potentials with attractive tails. Phys. Rev. A 78, 022707 (2008)
Raab, P., Friedrich, H.: Quantization function for potentials with \(-1/r^{4}\) tails. Phys. Rev. A 80, 052705 (2009)
Shimizu, F.: Specular reflection of very slow metastable neon atoms from a solid surface. Phys. Rev. Lett. 86, 987 (2001)
Stein, A., Knöckel, H., Tiemann, E.: Fourier-transform spectroscopy of Sr2 and revised ground-state potential. Phys. Rev. A 78, 042508 (2008)
Steinke, M., Knöckel, H., Tiemann, E.: (X)1 \({}^{1}\varSigma^{+}\) state of LiNa studied by Fourier-transform spectroscopy. Phys. Rev. A 85, 042720 (2012)
Schwarz, F., Müller, T.-O., Friedrich, H.: Near-threshold Feshbach resonances in interatomic collisions and spectra. Phys. Rev. A 85, 052703 (2012)
Schuster, T., Scelle, R., Trautmann, A., Knoop, S., Oberthaler, M.K., Haverhals, M.M., Goosen, M.R., Kokkelmans, S.J.J.M.F., Tiemann, E.: Feshbach spectroscopy and scattering properties of ultracold Li + Na mixtures. Phys. Rev. A 85, 042721 (2012)
Samuelis, C., Tiesinga, E., Laue, T., Elbs, M., Knöckel, H., Tiemann, E.: Cold atomic collisions studied by molecular spectroscopy. Phys. Rev. A 63, 012710 (2000)
Stwalley, W.: The dissociation energy of the hydrogen molecule using long-range forces. Chem. Phys. Lett. 6, 241 (1970)
Trost, J., Eltschka, C., Friedrich, H.: Quantisation in molecular potentials. J. Phys. B 31, 361 (1998)
Ticknor, C.: Two-dimensional dipolar scattering. Phys. Rev. A 80, 052702 (2009)
Verhaar, B.J., van den Eijnde, P.H.W., Voermans, M.A., Schaffrath, M.M.J.: Scattering length and effective range in two dimensions: application to adsorbed hydrogen atoms. J. Phys. A 17, 595 (1984)
Voronin, A.Y., Froelich, P.: Quantum reflection of ultracold antihydrogen from a solid surface. J. Phys. B 38, L301 (2005)
Voronin, A.Y., Froelich, P., Zygelman, B.: Interaction of ultracold antihydrogen with a conducting wall. Phys. Rev. A 72, 062903 (2005)
Yu, I.A., Doyle, J.M., Sandberg, J.C., Cesar, C.L., Kleppner, D., Greytak, T.J.: Evidence for universal quantum reflection of hydrogen from liquid 4He. Phys. Rev. Lett. 71, 1589 (1993)
Zhao, B.S., Meijer, G., Schöllkopf, W.: Quantum reflection of He2 several nanometers above a grating surface. Science 331, 892 (2011)
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Friedrich, H. (2016). Special Topics. In: Scattering Theory. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-48526-2_4
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