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Photochemistry, a Powerful Science

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Photochemistry

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Abstract

Photochemical reactions often take an unexpected course, or at least one that is not predicted on the basis of thermal chemistry. This is not surprising when the high energy of excited states, comparable with that of covalent bonds, is considered and thus the formation of high-energy intermediates is taken into account. The course of photochemical reactions can be traced by typical methods, flash photolysis and matrix isolation, that are highly informative. The study by these methods is of wide interest in chemistry both for supporting the reaction mechanism by supplying evidence about high-energy intermediates and for application to new syntheses, e.g., of strained molecules.

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  1. Organic Chemistry, University of Pavia, Pavia, Italy

    Angelo Albini

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Albini, A. (2016). Photochemistry, a Powerful Science. In: Photochemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-47977-3_6

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