Abstract
This chapter mainly focuses on recent research progress in photofunctional rare earth materials based on ionic liquids, with an emphasis on the photofunctional rare earth hybrid materials using ionic liquid compounds as both double functional linkers and matrices. It covers photofunctional rare earth compounds with ionic liquids, photofunctional rare earth compounds dispersed in ionic liquids, and photofunctional rare earth hybrid materials based on ionic liquid with special groups (organically modified siloxanes, carboxyl groups, and thiol groups). Herein we focus on the work of our group in the recent years.
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References
Binnemans K (2005) Ionic liquid crystals. Chem Rev 105:4148–4204
Greaves TL, Drummond CJ (2008) Ionic liquids as amphiphile self-assembly media. Chem Soc Rev 37:1709–1726
Plechkova NV, Seddon KR (2008) Applications of ionic liquids in the chemical industry. Chem Soc Rev 37:123–150
Parvulescu VI, Hardacre C (2007) Catalysis in ionic liquids. Chem Rev 107:2615–2665
Binnemans K (2007) Lanthanides and actinides in ionic liquids. Chem Rev 107:2592–2614
Hallett JP, Welton T (2011) Room-temperature ionic liquids: solvents for synthesis and catalysis. 2. Chem Rev 111:3508–3576
Nunez NO, Ocana M (2007) An ionic liquid based synthesis method for uniform luminescent lanthanide fluoride nanoparticles. Nanotechnology 18:455606
Jacob DS, Bitton L, Grinblat JC et al (2006) Are ionic liquids really a boon for the synthesis of inorganic materials? A general method for the fabrication of nanosized metal fluorides. Chem Mater 18:3162–3168
Liu XM, Zhao JW, Sun YJ et al (2009) Ionothermal synthesis of hexagonal-phase NaYF4:Yb3+, Er3+/Tm3+ upconversion nanophosphors. Chem Commun 6628–6630
Zhang C, Chen J, Zhou YC et al (2008) Ionic liquid-based “all-in-one” synthesis and photoluminescence properties of lanthanide fluorides. J Phys Chem C 112:10083–10088
Li CX, Lin J (2010) Rare earth fluoride nano-/microcrystals: synthesis, surface modification and application. J Mater Chem 20:6831–6847
Eliseeva SV, Bunzli JCG (2010) Lanthanide luminescence for functional materials and biosciences. Chem Soc Rev 39:189–227
Le Bideau J, Viau L, Vioux A (2011) Ionogels, ionic liquid based hybrid materials. Chem Soc Rev 40:907–925
Li M, Pham PJ, Pittman CU et al (2009) SBA-15-supported ionic liquid compounds containing silver salts: novel mesoporous pi-complexing sorbents for separating polyunsaturated fatty acid methyl esters. Microporous Mesoporous Mater 117:436–442
Nakashima T, Nonoguchi Y, Kawai T (2008) Ionic liquid-based luminescent composite materials. Polym Adv Technol 19:1401–1405
Feng J, Zhang HJ (2013) Hybrid materials based on lanthanide organic complexes: a review. Chem Soc Rev 42:387–410
Hines CC, Cocalia VA, Rogers RD (2008) Using ionic liquids to trap unique coordination environments: polymorphic solvates of ErCl3(OH2)4⋅2([C2mim]Cl). Chem Commun 226–228
Maggini L, Traboulsi H, Yoosaf K et al (2011) Electrostatically-driven assembly of MWCNTs with a europium complex. Chem Commun 47:1626–1628
Mudring AV, Tang S (2010) Ionic liquids for lanthanide and actinide chemistry. Eur J Inorg Chem 2569–2581
Jensen MP, Neuefeind J, Beitz JV (2003) Mechanisms of metal Ion transfer into room-temperature ionic liquids: the role of anion exchange. J Am Chem Soc 125:15466–15473
Guillet E, Imbert D, Scopelliti R et al (2004) Tuning the emission color of europium-containing ionic liquid-crystalline phases. Chem Mater 16:4063–4070
Nockemann P, Breuer E, Driesen K et al (2004) Photostability of a highly luminescent europium β-diketonate complex in imidazolium ionic liquids. Chem Commun 4354–4356
Babai A, Mudring AV (2005) Anhydrous praseodymium salts in the ionic liquid [bmpyr][Tf2N]: structural and optical properties of [bmpyr]4[PrI6][Tf2N] and[bmyr]2[Pr(Tf2N)5]. Chem Mater 17:6230–6238
Arenz S, Babai A, Binnemans K et al (2005) Intense near-infrared luminescence of anhydrous lanthanide(III) iodides in an imidazolium ionic liquid. Chem Phys Lett 402:75–79
Mudring AV, Babai A, Arenz S (2006) Strong luminescence of rare earth compounds in ionic liquids: luminescent properties of lanthanide(III) iodides in the ionic liquid 1-dodecyl-3-methylimidazoliumbis(trifluoromethanesulfonyl)imide. J Alloys Compd 418:204–208
Samikkanu S, Mellem K, Berry M et al (2007) Luminescence properties and water coordination of Eu3+ in the binary solvent mixture water/1-butyl-3-methylimidazolium chloride. Inorg Chem 46:7121–7128
Tang S, Babai A, Mudring AV (2008) Europium-based ionic liquids as luminescent soft materials. Angew Chem Int Ed 47:7631–7634
Mallick B, Balke B, Felser C et al (2008) Dysprosium room-temperature ionic liquids with strong luminescence and response to magnetic fields. Angew Chem Int Ed 47:7635–7638
Getsis A, Balke B, Felser C et al (2009) Dysprosium-based ionic liquid crystals: thermal, structural, photo- and magnetophysical properties. Cryst Growth Des 9:4429–4436
Tang S, Cybinska J, Mudring AV et al (2009) Luminescent soft material: two new europium-based ionic liquids. Helv Chim Acta 92:2375–2386
Tang S, Mudring AV (2009) Terbium β-diketonate based highly luminescent soft materials. Eur J Inorg Chem 2769–2775
Getsis A, Tang S, Mudring AV et al (2010) A luminescent ionic liquid crystal: [C12mim]4[EuBr6]Br. Eur J Inorg Chem 2172–2177
Getsis A, Mudring AV (2011) Switchable green and white luminescence in terbium-based ionic liquid crystals. Eur J Inorg Chem 3207–3213
Lunstroot K, Nockemann P, Hecke KV et al (2009) Visible and near-infrared emission by samarium(III)-containing ionic liquid mixtures. Inorg Chem 3018–3026
Pandey S, Baker GA, Sze L et al (2013) Ionic liquids containing fluorinated β-diketonate anions: synthesis, characterization and potential applications. New J Chem 37:909–919
Wang D, Wang H, Li H (2013) Novel luminescent soft materials of terpyridine-containing ionic liquids and europium(III). ACS Appl Mater Interfaces 5:6268–6275
Driesen K, Nockemann P, Binnemans K (2004) Ionic liquids as solvents for near-infrared emitting lanthanide complexes. Chem Phys Lett 395:306–310
Brandner A, Kitahara T, Beare N et al (2011) Luminescence properties and quenching mechanisms of Ln(Tf2N)3 complexes in the ionic liquid bmpyr Tf2N. Inorg Chem 50:6509–6520
Hopkins T, Goldey M (2009) Tb3+ and Eu3+ luminescence in imidazolium ionic liquids. J Alloys Compd 488:615–618
Getsis A, Mudring AV (2010) Lanthanide containing ionic liquid crystals: EuBr2, SmBr3, TbBr3 andDyBr3 in C12mimBr. Z Anorg Allg Chem 636:1726–1734
Devi SV, Maji S et al (2011) Novel room temperature ionic liquid for fluorescence enhancement of Eu3+ and Tb3+. J Lumin 131:739–748
Puntus LN, Pekareva IS, Lyssenko KA et al (2010) Influence of ionic liquid anion nature on the properties of Eu-containing luminescent materials. Opt Mater 32:707–710
Nockemann P, Thijs B, Lunstroot K et al (2009) Speciation of rare-earth metal complexes in ionic liquids: a multiple-technique approach. Chem Eur J 15:1449–1461
Li H, Shao H, Wang Y et al (2008) Soft material with intense photoluminescence obtained by dissolving Eu2O3 and organic ligand into a task-specific ionic liquid. Chem Commun 18:5209–5211
Lunstroot K, Baeten L, Nockemann P et al (2009) Luminescence of LaF3: Ln3+ nanocrystal dispersions in ionic liquids. J Phys Chem C 113:13532–13538
Yan Z, Yan B (2013) Luminescent hybrid ionogels functionalized with rare earth fluoride up-conversion nanocrystals dispersing in ionic liquid. Photochem Photobiol 89:1262–1268
Yan Z, Yan B, Jia L (2014) Hydrogels immobilized by doped rare earth fluoride nanocrystals: ionic liquid dispersion and down/up-conversion luminescence. Spectro chim Acta A 121:732–736
Lunstroot K, Driesen K, Nockemann P et al (2006) Luminescent Ionogels based on europium-doped ionic liquids confined within silica-derived networks. Chem Mater 18:5711–5715
Bruno SM, Ferreira RAS, Almeida Paz FA et al (2009) Structural and photoluminescence studies of a europium(III) tetrakis(β-diketonate) complex with tetrabutylammonium, imidazolium, pyridinium and silica-supported imidazolium counterions. Inorg Chem 48:4882–4895
Feng Y, Li H, Gan Q et al (2010) A transparent and luminescent ionogel based on organosilica and ionic liquid coordinating to Eu3+ ions. J Mater Chem 20:972–975
Lunstroot K, Driesen K, Nockemann P et al (2010) Ionic liquid as plasticizer for europium(III)-doped luminescent poly(methyl methacrylate) films. Phys Chem Chem Phys 12:1879–1885
Li Q, Yan B (2012) Luminescent hybrid materials of lanthanide β-diketonate and mesoporous host through the covalent and ion bonding with anion metathesis. Dalton Trans 41:8567–8573
Li Q, Yan B (2012) Luminescent GaN semiconductor based on surface modification with lanthanide complexes through an ionic liquid bridge. RSC Adv 2:10840–10843
Li Q, Yan B (2013) Novel luminescent hybrids by incorporating rare earth β-diketonates into polymers through ion pairing with an imidazolium counter ion. Photochem Photobiol Sci 12:1628–1635
Li Q, Yan B (2014) Photophysical properties of lanthanide (Eu3+, Tb3+) hybrid soft gels of double functional linker of ionic liquid modified silane. Photochem Photobiol 90:22–28
Li Q, Yan B (2014) Luminescent hybrid nanoparticles prepared by encapsulated lanthanide chelates to the silica microsphere. Colloid Polym Sci 292:1385–1393
Cuan J, Yan B (2013) Multi-component assembly and photophysical property of europium polyoxometalates and polymer functionalized (mesoporous) silica through double functional ionic liquid linker. Dalton Trans 42:14230–14239
Cuan J, Yan B (2013) Cool-white light emitting hybrid materials of resin-mesoporous silica composite matrix encapsulating europium polyoxometalates through ionic liquid linker. RSC Adv 3:20077–20084
Cuan J, Yan B (2014) Photofunctional hybrid materials with polyoxometalates and benzoate modified mesoporous silica through double functional imidazolium ionic liquid linkage. Microporous Mesoporous Mater 183:9–16
Yan Z, Yan B (2014) Luminescent lanthanide-polyoxometalates assembling zirconia/alumina/titania hybrid xerogels through task-specified ionic liquid linkage. RSC Adv 4:1735–1743
Yan Z, Yan B (2014) Novel photoactive lanthanide complex functionalized hybrid soft xerogels through ionic liquid linkage. New J Chem 38:2604–2610
Mei Y, Lu Y, Yan B (2013) Multi-component hybrid soft gels containing Eu3+ complexes and MS (M = Zn, Cd) nanoparticles assembled with mercapto- ion liquid linkage: adjustable color and white luminescence. New J Chem 37:2619–2623
Mei Y, Yan B (2014) White hybrid soft materials of lanthanide (Eu3+, Sm3+) beta-diketonates and Ag/Ag2S nanoparticles based with thiol-functionalized ionic liquid bridge. Inorg Chem Commun 40:39–42
Mei Y, Lu Y, Yan B (2014) Soft materials composed with lanthanide (Eu3+, Tb3+) beta-diketonates and ZnO nanoparticles through thiol-functionalized ionic liquid bridge to integrate white luminescence. J Photochem Photobiol A Chem 280:1–4
Mei Y, Yan B (2014) Photoactive hybrid materials of lanthanide (Eu3+, Tb3+, Sm3+) beta-diketonates and polymer resin through ionic liquid bridge. Photochem Photobiol 90:1462–1466
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Yan, B. (2016). Photofunctional Rare Earth Materials Based on Ionic Liquids. In: Chen, J. (eds) Application of Ionic Liquids on Rare Earth Green Separation and Utilization. Green Chemistry and Sustainable Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-47510-2_8
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DOI: https://doi.org/10.1007/978-3-662-47510-2_8
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