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Zeolites in Sustainable Chemistry pp 37–76Cite as

Ionothermal Synthesis of Molecular Sieves

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Part of the book series: Green Chemistry and Sustainable Technology ((GCST))

Abstract

The synthesis of molecular sieves in ionic liquid or deep eutectic solvent is termed ionothermal synthesis. It involves an ionic reaction environment with extremely low volatility, and thus, can avoid the safety risks of hydro/solvothermal reactions, and bring great convenience and flexibility to both the synthesis of molecular sieves and the study on their formation mechanisms. In this chapter, first introduced are the special physicochemical properties of ionic liquids and deep eutectic solvents, and the distinctive opportunities brought by them to synthesize molecular sieves. A detailed methodological illustration of ionothermal synthesis technique is provided subsequently. The molecular sieves ionothermally synthesized are summarized by their features such as composition, structure, porosity and morphology. Then follows a review on the fascinating structure-directing effect of various guest species in ionothermal synthesis. Finally, a prospect is given on the future development of ionothermal synthesis.

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Acknowledgement

The authors gratefully acknowledge National Natural Science Foundation of China for its funding support (Grant No. 21373214).

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Authors and Affiliations

  1. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

    Zhi-Jian Tian & Hao Liu

  2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

    Zhi-Jian Tian

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  2. Hao Liu
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Correspondence to Zhi-Jian Tian .

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  1. Department of Chemistry, Zhejiang University, Hangzhou, China

    Feng-Shou Xiao

  2. Department of Chemistry, Zhejiang University, Hangzhou, China

    Xiangju Meng

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Tian, ZJ., Liu, H. (2016). Ionothermal Synthesis of Molecular Sieves. In: Xiao, FS., Meng, X. (eds) Zeolites in Sustainable Chemistry. Green Chemistry and Sustainable Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-47395-5_2

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