Advertisement

Spectral data of porphyrin derivative C50H29F5N4O

  • M. P. Dobhal
Part of the Molecules and Radicals book series (volume 32B2)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of porphyrin derivative C50H29F5N4O.

2. Spectral Studies

Spectral Data of Porphyrin Isomers and Expanded Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks γ [cm−1]

Solvent

Peaks λ [nm]/ (ε [M−1cm−1]/ log ε)

  

CDCl3

1 H NMR

−2.80 (s, 2H, 2xNH),

7.33 (d, 2H, J = 8.6 Hz, 3′, 5′-H),

7.73–7.78 (m, 9H, 3xm, 3xp-ϕ-H),

8.17 (d, 2H, J = 8.6 Hz, 2′, 6′-H),

8.20–8.23 (m, 6H, 3xo-ϕ-H),

8.82–8.87 (m, 8H, β-pyrrole-H)

 

CHCl3

420 (5.71), 516 (4.30), 551 (3.92), 591 (3.76), 646 (3.63)

 

[05Tom]

CDCl3

13 C NMR

113.7, 118.6, 120.25, 120.3, 126.7, 127.7, 131.2, 134.6, 135.7, 138.0, 142.1, 157.0

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [05Tom]
    Tome, J.P.C., Neves, M.G.P.M.S., Tome, A.C., Cavaleiro, J.A.S., Mendonca, A.F., Pegado, I.N., Duarte, R., Valdeira, M.L.: Bioorg. Med. Chem. 13, 3878 (2005)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  • M. P. Dobhal
    • 1
  1. 1.Department of ChemistryUniversity of RajasthanJaipurIndia

Personalised recommendations