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Spectral data of phosphorus complex of porphyrin derivative C56H54N4O2P

  • M. P. Dobhal
Chapter
Part of the Molecules and Radicals book series (volume 32B2)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of phosphorus complex of porphyrin derivative C56H54N4O2P.

2. Spectral Studies

Spectral Data of Porphyrin Isomers and Expanded Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks γ [cm−1]

Solvent

Peaks λ [nm]/ (ε [M−1cm−1]/ log ε)

  

CDCl3

1 H NMR

2.47 (dt, 4H, J = 12.4, 6.5 Hz),

1.52–1.59 (m, 4H),

0.86–0.93 (m, 4H),

0.09 (quintet, 4H, J = 7.5 Hz),

0.30 (t, 6H, J = 7.5 Hz),

0.38 (sextet, 4H, J = 7.5 Hz),

7.76–7.84 (m, 12H),

7.95–7.97 (m, 8H),

9.08 (d, 8H, J = 2.8 Hz)

 

CH3OH

429 (34.2 × 104),

560 (1.41 × 104),

601 (0.43 × 104)

 

[11Mat]

CDCl3

13 C NMR

13.35, 21.45, 23.62, 27.07 (d, J = 16.1 Hz),

30.05, 61.45 (d, J = 16.3 Hz),

116.14 (d, J = 1.5 Hz), 128.46,

129.45, 133.05 (d, J = 5.1 Hz),

133.33, 139.13

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [11Mat]
    Matsumoto, J., Shinbara, T., Tanimura, S.-I., Matsumotyo, T., Shiragami, T., Yokoi, H., Nosaka, Y., Okazaki, S., Hirakawa, K., Yasuda, M.: J. Photochem. Photobiol. A.: Chem. 218, 178 (2011)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  • M. P. Dobhal
    • 1
  1. 1.Department of ChemistryUniversity of RajasthanJaipurIndia

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