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Spectral data of iridium complex of porphyrin derivative C51H45ClIrN+5

  • M. P. Dobhal
Part of the Molecules and Radicals book series (volume 32B2)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of iridium complex of porphyrin derivative C51H45ClIrN+5.

2. Spectral Studies

Spectral Data of Porphyrin Isomers and Expanded Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks γ [cm−1]

Solvent

Peaks λ [nm]/ (ε [M−1cm−1]/ log ε)

  

CDCl3

1 H NMR

2.74 (s, 12H, 4xCH3),

7.56 (t, 8H, J = 6.0 Hz),

8.02 (d, 4H, 7.2 Hz),

8.15 (d, 4H, J = 7.2 Hz),

8.71 (s, 8H)

 

CH2Cl2

412 (5.34), 522 (4.21), 555 (3.47)

 

[12And]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [12And]
    Anding, B.J., Ellern, A., Woo, L.K.: Organometallics 31, 3628 (2012)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  • M. P. Dobhal
    • 1
  1. 1.Department of ChemistryUniversity of RajasthanJaipurIndia

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