CO2 Coordination to Metal Centres: Modes of Bonding and Reactivity



The modes of coordination of carbon dioxide (CO2) to metal centres are presented in this chapter. The coordination at both room temperature and low temperature in gas matrices is discussed with the reactivity of the coordinated cumulene. X-ray diffraction structural data are presented and discussed together with spectroscopic properties of the complexes.


Metal Centre Coordination Mode Nuclear Magnetic Resonance Spectroscopy Metal Organic Framework Early Transition Metal 
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© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  1. 1.Chemical and Biomolecular Engineering DepartmentNUSSingaporeSingapore
  2. 2.CIRCCPisaItaly
  3. 3.Department of Chemistry and CIRCCUniversity of BariBariItaly

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