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Springer Handbook of Electrochemical Energy pp 331–363Cite as

Electrochemical Energy Generation and Storage as Seen by In-Situ NMR

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Abstract

This chapter will provide a concise review/snap-shots of the development of in situ electrochemical nuclear magnetic resonance spectroscopy (including magnetic resonance imaging), in both solution and solid state, and its current state of applications to understanding chemical processes for electrochemical energy generation and storage. This will include pedagogical descriptions of involved principles and techniques and discussions of representative case studies that showcase the technical prowess of the methodologies, particularly in investigating nanomaterials used in electrocatalysis for fuel cells and energy storage devices (batteries) and associated water distribution in the former and Li metal deposits in the latter.

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Abbreviations

BMS:

bulk magnetic susceptibility

COHP:

crystal orbital hamiltonian population

CSI:

chemical shift imaging

DFT:

density functional theory

DNP:

dynamic nuclear polarization

EC:

electrochemical

EOS:

electronic-orbital-specific

FAOR:

formic acid oxidation reaction

FC:

fuel cell

FWHM:

full width at half maximum

GDL:

gas diffusion layer

LDOS:

local density of state

MAS:

magic angle spinning

MEA:

membrane–electrode assembly

MO:

molecular orbital

MOR:

methanol oxidation reaction

MRI:

magnetic resonance imaging

NMR:

nuclear magnetic resonance

NP:

nanoparticle

OCV:

open circuit voltage

ORR:

oxygen reduction reaction

PD:

packing density

PEMFC:

proton-exchange membrane fuel cell

PEM:

proton-exchange membrane

QSE:

quantum size effect

RF:

radio frequency

RH:

relative humidity

ROI:

regions of interest

SD:

smoothly deposited

SEI:

solid electrolyte interphase

SEM:

scanning electron microscopy

TEM:

transmission electron microscopy

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Authors and Affiliations

  1. Dept. Chemistry, Georgetown University, 37th & O Streets, NW, DC 20057, Washington, USA

    YuYe J. Tong

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  1. Dept. Mechanical Engineering, TU Dresden, Helmholtzstr. 14, 01062, Dresden, Germany

    Cornelia Breitkopf

  2. Chemistry Division, US Naval Research Laboratory, 4555 Overlook Ave., DC 20375, Washington, USA

    Karen Swider-Lyons

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Tong, Y.J. (2017). Electrochemical Energy Generation and Storage as Seen by In-Situ NMR. In: Breitkopf, C., Swider-Lyons, K. (eds) Springer Handbook of Electrochemical Energy. Springer Handbooks. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-46657-5_12

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