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Simple Coordination Complexes of Cucurbit[n]urils with Metal Ions

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Supramolecular Assemblies of Cucurbit[n]urils with Metal Ions

Part of the book series: SpringerBriefs in Molecular Science ((BRIEFSMOLECULAR))

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Abstract

Generally, the noncovalent interaction of Q[n]s with various guest molecules has led to the development of Q[n]-based host–guest chemistry, which has become the mainstream in Q[n] chemistry. In fact, the establishment of Q[n] chemistry started with Q[n]-based coordination chemistry because the structural characteristics of the first characterized member of the Q[n] family, Q[6], was based on the determination of the complex of Q[6] molecules with Ca2+ cations. From a structural viewpoint, the two preorganized (identical) carbonyl fringed portals in Q[n]s are ideal for acting as a rigid platform for developing a variety of Q[n]-metal derived coordination structures. In this chapter, a number of Q[n]-based metallo-supramolecular coordination fashions and examples are reviewed in detail. Overall, molecular bowls, molecular capsules, sandwich pairs, and heterometallic complexes are the general structures in the solid state. We therefore describe them in this chapter as simple coordination complexes of Q[n]s with metal ions.

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Authors and Affiliations

  1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang, China

    Xin-Long Ni, Xin Xiao, Hang Cong & Zhu Tao

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  1. Xin-Long Ni
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  2. Xin Xiao
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  3. Hang Cong
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Correspondence to Xin-Long Ni .

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Ni, XL., Xiao, X., Cong, H., Tao, Z. (2015). Simple Coordination Complexes of Cucurbit[n]urils with Metal Ions. In: Supramolecular Assemblies of Cucurbit[n]urils with Metal Ions. SpringerBriefs in Molecular Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-46629-2_2

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