The methods for the preparation of tetraorgano-substituted germanes, known before 1936, include the reactions of germanium tetrahalides with dialkyl-, diaralkyl-, or diaryl-zinc, c with organomagneslum halides, or with aryl halides and sodium. Now these compounds are conveniently prepared by reacting germanium tetrahalides with organolithium compounds in the presence or absence of solvents.


Sulfide Iodide Germanium Semicarbazone Trisulfide 

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© Springer-Verlag Berlin Heidelberg 1961

Authors and Affiliations

  • Michael Dub
    • 1
  1. 1.Research and Engineering DivisionMonsanto Chemical CompanyUK

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