Abstract
We treat non-radiative electronic capture rates induced by the non-adiabatic perturbation operator with corresponding transition probabilities. Therefore a dynamical electronic wave-function is evaluated. By coupling the electron to “dressed phonon” modes, which connect the “local” optical mode to the acoustic phonons, exact energy balance in the transition probabilities is possible. The Franck-Condon-Integrals arising there are thermal averaged analytically. The method is applicable to transitions between two discrete electronic levels as well as band to discrete level transitions. Numerical results are given.
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© 1974 Springer-Verlag Berlin Heidelberg
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Fraser, S. (1974). Non-Radiative Electronic Capture Rates by a Halide Vacancy in Alkali Halides. In: Busch, G., Strässler, S. (eds) Physics of Condensed Matter. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-39595-0_7
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DOI: https://doi.org/10.1007/978-3-662-39595-0_7
Publisher Name: Springer, Berlin, Heidelberg
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