Abstract
S34/S32 measurements and trace element analyses were performed on sediment from selected cores from the Red Sea geothermal deposit, the overlying brine and interstitial water.
The data show that δS34 falls into four general ranges: (1) >25 per mill, (2) +23 to +15 per mill, (3) +12 to +2 per mill, (4) <−25 per mill. Sulfate in the brine appears to have been derived from marine evaporites, whereas sulfide originates from two sources. In the Atlantis II Deep, it is derived from a hydrothermal process and introduced with the brine. In the other areas, biological sulfate reduction produces sulfide which precipitates metals from the brine originating in the Atlantis II Deep.
Contribution No. 680, Institute of Geophysics and Planetary Physics.
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References
Ault, W. V. and J. L. Kulp: Isotopic geochemistry of sulphur. Geochim. et Cosmochim. Acta. 16, 201 (1959).
Ault, W. V. and J. L. Kulp: Sulfur isotopes and ore deposits. Econ. Geol. 55, 73 (1960).
Barton, P. B., Jr.: Possible role of organic matter in the precipitation of the Mississippi Valley ores. Econ. Geol. 3, 371 (1967).
Bischoff, J. L.: Red Sea geothermal deposits: their mineralogy, chemistry and genesis. In: Hot brines and recent heavy metal deposits in the Red Sea, E. T. Degens and D. A. Ross (eds.). Springer-Verlag New York Inc., 368-401 (1969).
Bischoff, J. L. and F. T. Manheim: Economic potential of the Red Sea heavy mineral deposits. In: Hot brines and recent heavy metal deposits in the Red Sea, E. T. Degens and D. A. Ross (eds.). Springer-Verlag New York Inc., 535-541 (1969).
Brewer, P. G., J. P. Riley, and F. Culkin: The chemical composition of the hot salty water from the bottom of the Red Sea. Deep Sea Res. 12, 497 (1965).
Brooks, R. R., I. R. Kaplan, and M. N. A. Peterson: Trace element composition of the Red Sea geothermal brine and interstitial water. In: Hot brines and recent heavy metal deposits in the Red Sea, E. T. Degens and D. A. Ross (eds.). Springer-Verlag New York Inc., 180-203 (1969).
Burnham, C. W.: Lattice constant refinement. Carnegie Inst. Wash. Yearbook. 61, 132 (1962).
Chester, R.: Elemental geochemistry of marine sediments. In: Chemical Oceanography, J. P. Riley and G. Skirrow (eds.). 2, 23 (1965).
Craig, H.: Isotopic composition and origin of the Red Sea and Salton Sea geothermal brines. Science. 154, 1544 (1966).
Davidson, C. F.: On the cobalt-nickel ratio in ore deposits. Mining Mag., 106, 78 (1962a).
Davidson, C. F.: The origin of some strata-bound sulfide ore deposits. Econ. Geol., 57, 265 (1962b).
Davidson, C. F.: A possible mode of origin of strata-bound copper ores. Econ. Geol. 60, 942 (1965).
Degens, E. T. and D. A. Ross: Hot brines and heavy metals in the Red Sea. Oceanus. 13, 24 (1967).
Drake, C. L. and R. W. Girdler: A geophysical study of the Red Sea. Geophys. J. Roy. Ast. Soc. 8, 473 (1964).
Dunham, K. C.: Neptunist concepts in ore genesis. Econ. Geol. 59, 1 (1964).
Fleischer, M.: Minor elements in some sulfide minerals. Econ. Geol., 50th anniv. vol., 970 (1955).
Gavelin, S., A. Parwel, and R. Ryhage: Sulfur isotope fractionation in sulfide mineralization. Econ. Geol. 55, 510 (1960).
Germanov, A. I.: Geochemical significance of organic matter in the hydrothermal process. Geochemistry International. 2, 643 (1965).
Gross, W. H. and H. G. Thode: Ore and the source of acid intrusives using sulfur isotopes. Econ. Geol. 60, 576 (1965).
Hardie, L. A.: The gypsum-anhydrite equilibrium at one atmosphere pressure. Am. Min. 52, 171 (1967).
Harrison, A. G. and H. G. Thode: The kinetic isotope effect in the chemical reduction of sulphate. Trans. Farad. Soc. 53, 1648 (1957).
Hartmann, M. and H. Nielsen: Sulfur isotopes in the hot brine and sediment of Atlantis II Deep (Red Sea). Marine Geol. 4, 305 (1966).
Heybroek, F.: The Red Sea Miocene Evaporite Basin. In: Salt Basins Around Africa, Inst. Petroleum, London, 17 (1965).
Holser, W. T. and I. R. Kaplan: Isotope geochemistry of sedimentary sulfates. Chem. Geol. 1, 93 (1966).
Hulston, J. R. and W. J. McCabe: Mass spectrometer measurements in the thermal areas of New Zealand. Part 2: Carbon isotopic ratios. Geochim. et Cosmochim. Acta. 26, 399 (1962).
Hunt, J. M., E. E. Hays, E. T. Degens, and D. A. Ross: Red Sea: detailed survey of hot brine area. Science. 156, 512 (1967).
Kaplan, I. R., K. O. Emery, and S. C. Rittenberg: The distribution and isotopic abundance of sulphur in recent marine sediments off Southern California. Geochim. et Cosmochim. Acta. 27, 297 (1963).
Kaplan, I. R. and S. C. Rittenberg: Microbial fractionation of sulphur isotopes. J. Gen. Microbiol. 34, 195 (1964).
Lebedev, L. M.: Modern growth of sphalerite. Doklady Akad. Nauk USSR (English trans.), 175, 196 (1967a).
Lebedev, L. M.: Metacolloids in Endogenetic Deposits. Plenum Press, New York, 1 (1967b).
Lloyd, R. M.: Oxygen-18 composition of oceanic sulfate. Science. 156, 1228 (1967).
Loftus-Hills, G. and M. Solomon: Cobalt, nickel and selenium in sulphides as indicators of ore genesis. Min. Deposita. 2, 228 (1967).
Longinelli, A. and H. Craig: Oxygen-18 variations in sulfate ions in sea water and saline lakes. Science. 156, 56 (1967).
Miller, A. R., C. D. Densmore, E. T. Degens, J. C. Hathaway, F. T. Manheim, P. F. McFarlin, R. Pocklington, and A. Jokela: Hot brines and recent iron deposits in deeps of the Red Sea. Geochim. et Cosmochim. Acta. 30, 341 (1966).
Nakai, N. and M. L. Jensen: Sulfur isotope fractionation by bacterial oxidation and reduction of sulfur. Geochim. et Cosmochim. Acta. 28, 1893 (1964).
Onishi, H. and E. B. Sandell: Geochemistry of arsenic. Geochim. et Cosmochim. Acta. 7, 1 (1955).
Presley, B. J., R. R. Books, and H. M. Kappel: A simple squeezer for removal of interstitial water from ocean sediments. J. Marine Res., 25, 355 (1967).
Riley, J. P.: The hot saline waters of the Red Sea bottom and their related sediments. In: Oceanogr. Mar. Biol.Ann. Rev., H. Barnes (ed.). 5, 141 (1967).
Sakai, H.: Fractionation of sulfur isotopes in nature. Geochim. et Cosmochim. Acta. 12, 150 (1957).
Skinner, B. J., P. B. Barton, and G. Kullerud: Effect of FeS on the unit cell edge of sphalerite. A revision. Econ. Geol. 54, 1040 (1959).
Skinner, B. J., D. E. White, H. J. Rose, and R. E. Mays. Sulfides associated with the Salton Sea geothermal brine. Econ. Geol., 62, 316 (1967).
Stanton, R. L.: The application of sulphur isotope studies in ore genesis theory — a suggested model. N.ZJ. Geol. Geophys. 3, 375 (1960).
Steiner, A. and T. A. Rafter: Sulfur isotopes in pyrite, pyrrhotite, alunite and anhydrite from steam wells in the Taupo volcanic zone, New Zealand. Econ. Geol. 61, 1115 (1966).
Tatsumi, T.: Sulfur isotopic fractionation between coexisting sulfide minerals from Japanese ore deposits. Econ. Geol. 60, 1645 (1965).
Toland, W. G.: Oxidation of organic compounds with aqueous sulfate. J. Am. Chem. Soc. 82, 1911 (1960).
Triiper, H. G.: Bacterial sulfate reduction in the Red Sea hot brines. In: Hot brines and recent heavy metal deposits in the Red Sea, E. T. Degens and D. A. Ross (eds.). Springer-Verlag New York Inc., 263-271 (1969).
Trudge, A. P. and H. G. Thode: Thermodynamic properties of isotopic compounds of sulphur. Canad. J. Res., 28B, 567 (1950).
Turekian, K. K. and K. H. Wedepohl: Distribution of the elements in some major units of the earth’s crust. Bull. Geol. Soc. Amer. 72, 175 (1961).
Vlasov, K. A.: Geochemistry of rare elements. Translated by Israel Program for Scientific Translations, Jerusalem. 1, 552 (1966).
Watson, S. W. and J. B. Waterbury: The sterile hot brines of the Red Sea. In: Hot brines and recent heavy metal deposits in the Red Sea, E. T. Degens and D. A. Ross (eds.). Springer-Verlag New York Inc., 272-281 (1969).
White, D. E.: Ore forming fluids of diverse origins. Econ. Geol. 63, 301 (1968).
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Kaplan, I.R., Sweeney, R.E., Nissenbaum, A. (1969). Sulfur Isotope Studies on Red Sea Geothermal Brines and Sediments. In: Degens, E.T., Ross, D.A. (eds) Hot Brines and Recent Heavy Metal Deposits in the Red Sea. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-28603-6_43
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DOI: https://doi.org/10.1007/978-3-662-28603-6_43
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