Abstract
The amorphous state is a borderline state of matter between micelles, which are, thermodynamic equilibrium systems in which concentrations of single molecules are in equilibrium with a molecular aggregate, and solid crystal structures. These amorphous systems have a high surface entropy owing to the disordered molecular arrays in their structure. This disorder can be produced by simple shear grinding of water-insoluble crystals, spray-drying under vacuum of solutions of the crystalline form or coprecipitation in water of associations consisting of large polar and non-polar oppositedly charged surfactants, such as alkyl sulfates and alkyl substituted amines.
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Reference
Collected works of J. Willard Gibbs (1878), Lon;gmans, Green and Company, London, Edition 1928, p. 329.
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© 1967 Springer-Verlag Wien
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Schulman, J.H., Rosoff, M., Erbring, H. (1967). Surface Properties of Molecular Aggregates of Micellar Size in Relation to Membrane Permeability and Adhesion. In: Bolis, L., Capraro, V., Porter, K.R., Robertson, J.D. (eds) Symposium on Biophysics and Physiology of Biological Transport. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-25134-8_37
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DOI: https://doi.org/10.1007/978-3-662-25134-8_37
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