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Kobalt(I)-Verbindungen / Cobalt(I) Compounds

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Kobalt

Part of the book series: Gmelins Handbuch der Anorganischen Chemie ((1956,volume C-o / B / 1-2 / 1))

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Zusammenfassung

Bldg. bei Bed. der wss. Lsg. von [Co dpy3]Cl3 (s. S. 378) oder [Co dpy3] Cl2 (s. S. 87) an der Hg-Tropfelektrode oder durch Na[BH4]-Lsg. in Ggw. von Dipyridyl-(2.2′) und NaNO3. Halbwellenpot. der Red. CoIII/CoII: −0.14 V, der Red. CoII/CoI: −1.32 V. Die Lsg. ist tiefblau und selbst in sauerstoffreier N2-Atm. instabil, B.Martin, G. M. Waind (Pr. ehem. Soc. 1958 169), G. M. Waind, B. Martin (J. inorg. nuclear Chem. 8 [1958] 551/6, 555).

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Allgemeine Literatur

  • L. Malatesta, Isocyanide complexes of metals, Progr. inorg. Chem. 1 [1959] 283/379, 340, 353.

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Authors

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Herbert Lehl Karl-Christian Buschbeck Rostislaw Gagarin

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© 1963 Springer-Verlag Berlin Heidelberg

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Lehl, H., Buschbeck, KC., Gagarin, R. (1963). Kobalt(I)-Verbindungen / Cobalt(I) Compounds. In: Lehl, H., Buschbeck, KC., Gagarin, R. (eds) Kobalt. Gmelins Handbuch der Anorganischen Chemie, vol C-o / B / 1-2 / 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-12164-1_2

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  • DOI: https://doi.org/10.1007/978-3-662-12164-1_2

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-12165-8

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