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Abstract

The different boron compounds have widely differing toxicities, which arise in a variety of ways. These include the ability of Lewis acids to form adducts, the liberation of borenium ions (chelate formation), the chemical and physiological activity of the ligands that are bound to boron, or simply the general physicochemical behavior of the molecule including hydrogen bond formation, solubility in lipids, hydrophobic interactions, ionic activity, etc. Boron, metal borid es, and boron carbide are relatively inert. On the other hand, the boranes, many of the polyboranes, and halogenoboranes are highly toxic and, because of extensive use, are especially dangerous in industry. Boric acid and its salts, esters, and complexes are considerably less toxic but are often employed in medicines and cosmetics and are widely used in agriculture, industry, and the home. As a result of this wide distribution, their toxicity has been studied more thoroughly. The organoborons, including the carboranes, which are used mainly in the laboratory, range from slightly toxic to very toxic. The toxic mechanism is more or less known for several groups of boron compounds. The following chapters give the experimental toxicities, chiefly for vertebrates, and cases of human poisoning. Therapy and prophylaxis are also presented.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1980

Authors and Affiliations

  • Wolfgang Kliegel
    • 1
  1. 1.Institut für Pharmazeutische ChemieTechnische Universität BraunschweigBraunschweigDeutschland

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