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Oxalate

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Niob

Part of the book series: Nb. Niob. Niobium (System-Nr. 49) ((2021,volume N-b / B / 4))

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Zusammenfassung

Entsteht aus dem Dihydrat (s. unten) durch Entwässerung bei 140°C und zersetzt sich unter CO2-Abspaltung bei 230 bis 260°C, wobei ein Rückstand der Zusammensetzung Na3NbO3C2O · 2 CO erhalten wird, der unter CO-Abspaltung bei etwa 500°C in Na3NbO4 übergeht. An feuchter Luft bildet sich aus Na3NbO(C2O4)3 das Dihydrat, L. G. Vlasov, A. V. Lapitskii, M. A. Salimov, B. V. Strizhkov (Zh. Neorgan. Khim. 7 [1962] 2534/6; Russ. J. Inorg. Chem. 7 [1962] 1314/5), L. G. Vlasov, A. V. Lapitskii, B. V. Strizhkov (Vestn. Mosk. Univ. Ser. II Khim. 16 Nr. 1 [1961] 57/8; C.A. 56 [1962] 12 525).

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Authors
  1. Herbert Lehl
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Herbert Lehl

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Lehl, H. (1972). Oxalate. In: Lehl, H. (eds) Niob. Nb. Niob. Niobium (System-Nr. 49), vol N-b / B / 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-11109-3_24

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  • DOI: https://doi.org/10.1007/978-3-662-11109-3_24

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