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Niob pp 88-133 | Cite as

System Niob—Natrium—Sauerstoff

  • Herbert Lehl
Part of the Nb. Niob. Niobium (System-Nr. 49) book series (GMELIN, volume N-b / B / 4)

Zusammenfassung

Bei 400°C reagiert flüssiges Na mit Nb2O5 unter Bildung von Na2Nb2O5, dagegen bei 600°C unter Bildung von Na3NbO4, metallischem Nb und einer Phase X unbekannter Zusammensetzung. Diese entsteht ebenfalls bei der thermischen Zersetzung von Na2Nb2O5 bei 700°C neben Nb und Na3NbO4 sowie bei der Reaktion von Na2O und NbO2 bei 800°C neben Na3NbO4, Addison u. a. [1]. Dagegen wird Bildung von Na2Nb2O5 aus Na und Nb2O5 bei 600°C neben nicht identifizierten Verbindungen angegeben von Tyzack [2] nach Hickam [3].

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© Springer-Verlag Berlin Heidelberg 1972

Authors and Affiliations

  • Herbert Lehl

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