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Evaluating the Environmental Friendliness, Economics and Energy Efficiency of Chemical Processes: Heat Integration

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Technological Choices for Sustainability

Abstract

The design and improvement of chemical processes can be very challenging. The earlier energy conservation, process economics and environmental aspects are incorporated into the process development, the easier and less expensive it is to alter the process design. In this work different process design alternatives with increasing levels of energy integration are considered in combination with evaluations of the process economics and potential environmental impacts. The example studied is the hydrodealkylation (HDA) of toluene to produce benzene. This study examines the possible fugitive and open emissions from the HDA process, evaluates the potential environmental impacts and the process economics considering different process design alternatives. Results of this work show that there are tradeoffs in the evaluation of potential environmental impacts. As the level of energy integration increases process fugitive emissions increase while energy generation impacts decrease. Similar tradeoffs occur for economic evaluations, where the capital and operating costs associated with heat integration could be optimised. From the example designs considered here, an intermediate amount of energy integration produces the most economically beneficial and environmentally friendly process.

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References

  • Cabezas, H, Bare JC, Mallick SK (1999) Pollution Prevention with chemical process simulators: the generalized waste reduction ( WAR) algorithm — full version. Comput Chem Eng 23: 623–634

    Google Scholar 

  • Chemical Engineering, mid-August (2000):410

    Google Scholar 

  • Chemical Market Reporter, (2002) October 7, 262(12)

    Google Scholar 

  • Douglas JM (1988) Conceptual Design of Chemical Processes. McGraw-Hill, New York, pp. 267–280

    Google Scholar 

  • Hilaly AK, Sikdar SK (1994) Pollution balance: a new method for minimizing waste production in manufacturing processes. J Air Waste Manag Assoc 44: 1303–1308

    CAS  Google Scholar 

  • Holman JP (1987) Heat Transfer. McGraw-Hill, New York, p. 527

    Google Scholar 

  • Krajnc M, Glavic P (1995) The Influence of Different Temperature Contributions on Heat Integrated Process Structure. Trans IchemE Part A 73: 880–888

    CAS  Google Scholar 

  • Linnhoff B, Flower JR (1978) Synthesis of Heat Exchanger Networks. AIChE J 24 (4): 633–54

    Article  CAS  Google Scholar 

  • Linnhoff B, Hindmarsh E (1983) The Pinch Design Method for Heat Exchanger Networks. Chem Eng Sci 38 (5): 745–763

    Article  CAS  Google Scholar 

  • Luyben WL (2000) Effect of Kinetic, Design, and Operating Parameters on Reactor Gain. Ind Eng Chem Res 39: 2384–2391

    Article  CAS  Google Scholar 

  • Peters MS, Timmerhaus KD (1991) Plant Design and Economics for Chemical Engineers, 4th ed. McGraw-Hill International Editions, Chemical and Petroleum Engineering Series

    Google Scholar 

  • Seider DW, Seader JD, Lewin DR (1998) Process Design Principles. Synthesis, Analysis and Evaluation. John Wiley & Sons, New York

    Google Scholar 

  • Smith JM, Van Ness HC (1987) Introduction to Chemical Engineering Thermodynamics, 4th ed. McGraw-Hill International Editions, pp 574–597

    Google Scholar 

  • Smith RL, Mata TM, Young DM, Cabezas H, Costa CAV (2001) Designing Efficient, Economic and Environmentally Friendly Chemical Processes. In Computer-Aided Chemical Engineering 9, edited by Jorgensen S and Gani R. Elsevier Science B. V., Proceedings of the 11`h European Symposium on Computer Aided Process Engineering, Kolding, Denmark, 27–30 May, 1165–1170

    Google Scholar 

  • Smith RL (2002) Evaluating the Economics and Environmental Friendliness of New and Retrofitted Chemical Processes. Clean Techn Environ Policy, 3: 383–391

    Article  Google Scholar 

  • Terril DL, Douglas JM (1987) Heat- Exchanger Network Analysis. 1. Optimization. Ind Eng Chem Res 26: 685–691

    Google Scholar 

  • Terril DL, Douglas JM (1987) Heat- Exchanger Network Analysis. 2. Steady-State Operability Evaluation. Ind Eng Chem Res 26: 691–696

    Google Scholar 

  • U. S. EPA (1995) Protocol for Equipment Leak Emission Estimates. EPA-453/R-95–017. U.S. EPA, Office of Air and Radiation, Office of Air Quality Planning and Standards, Res. Triang. Park

    Google Scholar 

  • Young DM, Cabezas H (1999) Designing Sustainable Processes with Simulation: The Waste Reduction ( WAR) Algorithm. Comput Chem Eng 23: 1477–1491

    Google Scholar 

  • Young DM, Scharp R, Cabezas H (2000) The waste reduction (WAR) algorithm: environmental impacts, energy consumption and engineering economics. Waste Manage 20: 605–615

    Article  CAS  Google Scholar 

  • Young DM (2002) Personal communication

    Google Scholar 

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Mata, T.M., Smith, R.L., Young, D.M., Costa, C.A.V. (2004). Evaluating the Environmental Friendliness, Economics and Energy Efficiency of Chemical Processes: Heat Integration. In: Sikdar, S.K., Glavič, P., Jain, R. (eds) Technological Choices for Sustainability. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-10270-1_22

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  • DOI: https://doi.org/10.1007/978-3-662-10270-1_22

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-05934-6

  • Online ISBN: 978-3-662-10270-1

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