Abstract
So far we have ignored the fact that the nuclei are surrounded by electrons with which they can interact. In this chapter we shall consider the magnetic interactions, postponing until later the consideration of the strong electrostatic effects that may be found when a nucleus possesses an electrical quadrupole moment. The magnetic coupling of the electrons to the nucleus arises from magnetic fields originating either from the motion of the electrical charges or from the magnetic moment associated with the electron spin. The former gives rise to the so-called chemical shifts; the latter, to the Knight shifts in metals and to a coupling between nuclear spins.
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© 1990 Springer-Verlag Berlin Heidelberg
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Slichter, C.P. (1990). Magnetic Interactions of Nuclei with Electrons. In: Principles of Magnetic Resonance. Springer Series in Solid-State Sciences, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-09441-9_4
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DOI: https://doi.org/10.1007/978-3-662-09441-9_4
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