Abstract
As already presented in Sect. 1.2, some of the atoms or molecules tied to a solid or liquid, can, at a fixed temperature, leave the condensed phase. In a closed system a certain vapor pressure p is established, which depends, according to Eq. (1.1b), on the temperature. Equation (1.1b) is only valid when the enthalpy of vaporization dHV is independent of the temperature. This is not always true.
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© 2004 Springer-Verlag Berlin Heidelberg
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Predel, B., Hoch, M., Pool, M. (2004). Phase Equilibria Including a Vapor Phase. In: Phase Diagrams and Heterogeneous Equilibria. Engineering Materials and Processes. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-09276-7_5
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DOI: https://doi.org/10.1007/978-3-662-09276-7_5
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