Methylated metal(loid) species in biological waste treatment

  • R. A. Diaz-Bone
  • B. Menzel
  • A. Barrenstein
  • A. V. Hirner


Biomethylation of metal(loid)s by microorganisms is a process, that fundamentally changes the physico-chemical properties of elements by the addition of methyl groups. In particular, the toxicity, mobility and bioavailability are often increased. Due to bioaccumulation even small environmental concentrations can have harmful effects on the upper levels of the food chain.


Anaerobic Digestion Organic Waste Green Waste Compost Pile Compost Facility 
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  1. ANS — Arbeitskreis zur Nutzbarmachung von Siedlungsabfällen e.V. ANS (2002) Kompostatlas Online. Internet address:
  2. Barth J (2001) Biological waste treatment in Europe — technical and market developments. Internet address: Google Scholar
  3. Craig PJ (ed) (1986) Organometallic compounds in the environment. Longman, Harlow.Google Scholar
  4. Craig PJ, Jenkins RO, Dewick R, Miller DP (1999) Trimethylantimony generation by Scopulariopsis brevicaulis during aerobic growth. Sci Tot Environ 229: 83–88CrossRefGoogle Scholar
  5. Diaz LF, Savage GM, Eggerth LL, Golueke CG (1993) Composting and recycling — Mu-nicipal solid waste. Lewis Publ., Boca RatonGoogle Scholar
  6. Diaz-Bone RA, Felix J, Hirner AV (2003) Multi-element organometal(loid) analysis by pH-gradient hydride generation. Book of Abstracts of the European Winter Plasma Conference on Plasma Spectrochemistry 2003: 296Google Scholar
  7. Feldmann J (1997) Summary of a calibration method for the determination of volatile metal(oid) compounds in environmental gas samples by using gaschromatographyinductively coupled plasma mass spectroscopy. J. Anal. At Spectrom 12: 1069–1076CrossRefGoogle Scholar
  8. Feldmann J, Grumping R, Hirner AV (1994) Determination of volatile metal and metalloid compounds in gases from domestic waste deposits with GC/ICP-MS. Fresenius J Anal Chem 350: 228–234CrossRefGoogle Scholar
  9. Jenkins RO, Forster SN, Craig PJ (2002) Formation of methylantimony species by an aerobic prockaryote: Flavobacterium sp.. Arch Microbiol 178: 274–278CrossRefGoogle Scholar
  10. Griner UM, Kresimon J, Hirner AV (2000) A new HG/LT-GC/ICP-MS multi-element speciation technique for real samples in different matrices. Fresenius J Anal Chem 368: 67–72CrossRefGoogle Scholar
  11. Grüter UM, Hitzke M, Kresimon J, Hirner AV (2001) Derivatisation of organometal(loid) species by sodium borohydride — Problems and solutions. J Chromatogr A 938: 225–236.CrossRefGoogle Scholar
  12. Hirner AV, Rehage H, Sulkowski M (2000) Umweltgeochemie. Steinkopff, Darmstadt CrossRefGoogle Scholar
  13. Hirner AV, Feldmann J, Krupp E, Grumping R, Goguel R, Cullen WR (1998) Metal(loid)organic compounds in geothermal gases and waters. Org Geochem 29: 1765–1778CrossRefGoogle Scholar
  14. Kern M, Fund K, Mayer M (1998): Stand der biologischen Abfallbehandlung in Deutschland. Müll and Abfall 11Google Scholar
  15. Koch I, Feldmann J, Lintschinger J, Serves SV, Cullen WR (1998) Demethylation of trimethylantimony species in aqueous solution during analysis by hydride generation/gas chromatography with AAS and ICP-detection. Appl Organomet Chem, 12: 129–136CrossRefGoogle Scholar
  16. Krupp E (1999) Analytik umweltrelevanter Metall(oid)spezies mittels gaschromatographischer Trennmethoden. Dissertation, Universität-GH EssenGoogle Scholar
  17. Maillefer S, Lehr CR, Cullen WR (2003) The analysis of volatile trace compounds in landfill gases, compost heaps and forest air. Apll Organomet Chem 17: 154–160CrossRefGoogle Scholar
  18. Michalke K, Wickenheiser EB, Mehring M, Hirner AV, Hensel R (2000) Production of volatile derivates of metal(loid)s by microflora involved in anaerobic digestion of sewage sludge. Appl Environ Microbiol 66: 2791–2796CrossRefGoogle Scholar
  19. Wickenheiser EB, Michalke KT, Hensel R, Drescher C, Hirner AV, Brutishauer B, Bachofen R (1998) Volatile compounds in gases emitted from the wetland bogs near Lake 112 Cadagno. In: Peduzzi R, Bachofen R, Tonella M (ed). Lake Cadagno: A Meromictic Lake. Documenta del Ínstituto Italiano di Idrobiologia, No 63Google Scholar

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© Springer-Verlag Berlin Heidelberg 2004

Authors and Affiliations

  • R. A. Diaz-Bone
  • B. Menzel
  • A. Barrenstein
  • A. V. Hirner

There are no affiliations available

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