Complexes with Hydrazides

  • Karl Koeber
  • Helga Köttelwesch
  • Dietrich Schneider
  • Helga Demmer
  • Edith Schleitzer-Rust
Part of the Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition book series (GMELIN, volume M-n / D / 5)

Abstract

Complexes of composition MnLnX2 with hydrazides of monocarboxylic acids, RC(O)NHNH2 (= L) are prepared in alcoholic and aqueous alcoholic solution. The IR and Raman spectra of the compounds were interpreted mostly in terms of bidentate ligation of the, hydrazide ligands to Mn through the carbonyl oxygen atom and the nitrogen atom of the terminal NH2 group, forming a five-membered metallocycle. This was confirmed by X-ray studies, as reported for the isothiocyanato complexes with aceto- (pp. 169/70) and benzohydrazide (pp. 175/6), and for the chloro complex with 2-pyridinecarbohydrazide (pp. 186/7). The magnetic moments of the MnLnX2 compounds are indicative of high-spin octahedral manganese(II) complexes, which are often polymeric.

Keywords

Acetone Benzene Histidine Chloro CCl4 

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References

  1. [1]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Metreveli, D. P., Pirtskhalava, N. I. (Koord. Khim. 3 [1977] 897/901; Soviet J. Coord. Chem. 3 [ 1977 ] 696 /700, 698 ).Google Scholar
  2. [2]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Metreveli, D. P., Pirtskhalava, N. I. (Koord. Khim. 3 [1977] 1069/74; Soviet J. Coord. Chem. 3 [ 1977 ] 829 /33, 831 ).Google Scholar
  3. [3]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Metreveli, D. P. (Koord. Khim. 2 [1976] 131/2; Soviet J. Coord. Chem. 2 [ 1976 ] 107 ).Google Scholar
  4. [4]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Pirtskhalava, N. I., Metreveli, D. P. (Zh. Neorgan. Khim. 22 [1977] 2768/73; Russ. J. Inorg. Chem. 22 [1977] 1502 /6, 1505 ).Google Scholar
  5. [5]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Metreveli, D. P., Pirtskhalava, N. I. (Koord. Khim. 3 [1977] 1534/40; Soviet J. Coord. Chem. 3 [ 1977 ] 1196 /202, 1198 ).Google Scholar
  6. [6]
    Biswas, P. K., Dasgupta, M. K., Mitra, S., Ray Chaudhuri, N. (J. Coord. Chem. 11 [ 1982 ] 225 /30, 227 ).Google Scholar
  7. [7]
    Kharitonov, Yu. Ya., Metreveli, D. P., Machkhoshvili, R. I., Pirtskhalava, N. I. (Koord. Khim. 3 [1977] 1386/93; Soviet J. Coord. Chem. 3 [1977] 1082/9, 1083, 1087/8).Google Scholar
  8. [1] Kharitonov, Yu. Ya., Machkhoshvili, R. I. (Zh. Neorgan. Khim. 16 [1971]
    /30; Russ. J. Inorg. Chem. 16 [ 1971 ] 492 /5, 493 ).Google Scholar
  9. [2]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I. (Zh. Neorgan. Khim. 14 [1969] 3181; Russ. J. Inorg. Chem. 14 [1969] 1697/80).Google Scholar
  10. [3]
    Ahmed, A. D., Ray Chaudhuri, N. (J..Inorg. Nucl. Chem. 33 [1971] 189/201, 192/4).Google Scholar
  11. [4]
    Ahmed, A. D., Mandel, P. K., Ray Chaudhuri, N. (J. Inorg. Nucl. Chem. 28 [1966] 2951 /9, 2952 ).Google Scholar
  12. [5]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I. (Zh. Neorgan. Khim. 16 [1971] 2697/704; Russ. J. Inorg. Chem. 16 [1971] 1438 /42, 1440 ).Google Scholar
  13. [6]
    Tsintsadze, G. V., Gogorishvili, P. V., Nagornaya, L. K., Tsivtsivadze, T. N., Machkhoshivili, R. I. (Issled. Obl. Khim. Kompleksn. Prostykh Soedin. Nek. Perekhodnykh Redk. Metal. No. 2 [1974] 194/6; C.A. 82 [1975] No. 25295).Google Scholar
  14. [7]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Generalova, N. B., Shchelokov, R. N. (Zh. Neorgan. Khim. 19 [1974] 1124/5; Russ. J. Inorg. Chem. 19 [1974] 613/4).Google Scholar
  15. [8]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Generalova, N. B., Shchelokov, R. N. (Zh. Neorgan. Khim. 20 [1975] 965/71; Russ. J. lnorg. Chem. 20 [ 1975 ] 540 /4, 542 ).Google Scholar
  16. [9]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Tsintsadze, G. V., Gogorishvili, P. V., Nagornaya, L. K. (Zh. Neorgan. Khim. 19 [1974] 2769/73; Russ. J. lnorg. Chem. 19 [1974] 1512/5).Google Scholar
  17. [10]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Generalova, N. B. (Zh. Neorgan. Khim. 22 [1977] 3294/8; Russ. J. Inorg. Chem. 22 [1977] 1796/8).Google Scholar
  18. [11]
    Tsintsadze, G. V., Tsivtsivadze, T. I., Turiashvili, T. N., Kvitashvili, A. I., Shkurpelo, A. I., Nagornaya, L. K. (Soobshch. Akad. Nauk Gruz.SSR 115 [1984] 537/40; C.A. 102 [ 1985 ] No. 123 483 ).Google Scholar
  19. [1]
    Ahmed, A. D., Mandat, P. K., Ray Chaudhuri, N. (J. Inorg. Nucl. Chem. 28 [1966] 2951 /9, 2952 ).Google Scholar
  20. [2]
    Ahmed, A. D., Ray Chaudhuri, N. (J. Indian Chem. Soc. 48 [1971] 747/52, 748, 751 ).Google Scholar
  21. [3]
    Moussa, M. N. H., Taha, F. I. M., Mostafa, M. M. (Egypt. J. Chem. 16 [1973] 115/23, 116, 119/21; C.A. 80 [1974] No. 77730).Google Scholar
  22. [4]
    Mostafa, M. M., Hassan, S. M., El-Asmy, A. F. A. (J. Indian Chem. Soc. 55 [1978] 529/31).Google Scholar
  23. [5]
    Machkhoshvili, R. I., Metreveli, D. P., Mitaishvili, G. Sh., Shchelokov, R. N. (Zh. Neorgan. Khim. 29 [1984] 1020/6; Russ. J. Inorg. Chem. 29 [1984] 586/90).Google Scholar
  24. [1]
    Mostafa, M. M., Nicholls, D. (Inorg. Chim. Acta 51 [1981] 35/8).Google Scholar
  25. [2]
    Machkhoshvili, R. I. Mitaishvili, G. Sh., Pirtskhalava, N. 1. (Zh. Neorgan. Khim. 27 [1982] 972/4; Russ. J. Inorg. Chem. 27 [1982] 545/7).Google Scholar
  26. [3]
    Tolmachev, V. N., Lomako, L. A., Miroshnik, L. V. (Vysokomol. Soedin. B 10 [1968] 905/7; C. A. 70 [1969] No. 47973).Google Scholar
  27. [4] Lomako, L. A., Tolmachev, V. N. (Ukr. Khim. Zh. 37 [1971]
    /5; Soviet Progr. Chem. 37 No. 11 [ 1975 ] 55 /8, 57 ).Google Scholar
  28. [5]
    Lomako, L. A., Ishchenko, I. K., Tolmachov, V. M. (Vestn. Kharkov. Univ. No. 84 [1972] 79/82; C.A. 78 [1973] No. 148416).Google Scholar
  29. [1]
    Aggarwal, R. C., Narang, K. K. (Indian J. Chem. A 14 [1976] 64/7).Google Scholar
  30. [2]
    Gogorishvili, P. V., Karkarashvili, M. V., Kalandarishvili, D. Z. (Zh. Neorgan. Khim. 14 [1969] 1516/20; Russ. J. Inorg. Chem. 14 [1969] 794/6).Google Scholar
  31. [3] Kharitonov, Yu. Ya., Machkhoshvili, R. I., Gogorishivili, P. V., Karkarashvili, M. V. (Zh. Neorgan. Khim. 17 [1972]
    /66; Russ. J. Inorg. Chem. 17 [1972] 550 /3, 552 ).Google Scholar
  32. [4]
    Dutta Ahmed, A., Ray Chaudhuri, N. (J. Inorg. Nucl. Chem. 33 [1974] 189/201, 192/4).Google Scholar
  33. [5]
    Dutta Ahmed, A., Mandal, P. K., Ray Chaudhuri, N. (J. Inorg. Nucl. Chem. 28 [1966] 2951 /9, 2952 ).Google Scholar
  34. [6]
    Issa, R. M., El-Shazly, M. F., Iskander, M. F. (Z. Anorg. Allgem. Chem. 354 [1967] 90/7, 92, 95 ).Google Scholar
  35. [7]
    Machkhoshvili, R. I., Pirtskhalava, N. I. Kharitonov, Yu. Ya., Kvernadze, M. S. (Zh. Neorgan. Khim. 23 [1978] 1018/23, 547/8; Russ. J. Inorg. Chem. 23 [1978] 563/6, 565, 304/5).Google Scholar
  36. [8]
    Tsintsadze, G. V., Gogorishvili, P. V., Nagormaya, L. K., Tsivtsivadze, T. I. (Nauchn. Tr. Gruz. Politekhn. Inst. im. V. I. Lenina No. 153, Pt. 5 [1972] 34/9, 35/7; C.A. 80 [1974] No. 66253).Google Scholar
  37. [9]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Tsintsadze, G. V., Gogorishvili, P. V., Nagornaya, L. K. (Zh. Neorgan. Khim. 20 [1975] 1281/5; Russ. J. Inorg. Chem. 20 [1975] 720/2).Google Scholar
  38. [10]
    Karkarashvili, M. V., Gogorishvili, P. V., Nagebashvili, Dzh. S. (Soobshch. Akad. Nauk Gruz.SSR 51 [1968] 101/6, 105; C.A. 69 [1968] No. 100085).Google Scholar
  39. [11] Kharitonov, Yu. Ya., Machkhoshvili, R. I., Tsintsadze, G. V., Gogorishvili, P. V., Nagornaya, L. K. (Zh. Neorgan. Khim. 19 [1974]
    /44; Russ. J. Inorg. Chem. 19 [ 1974 ] 727 /32, 731 ).Google Scholar
  40. [12]
    Aggarwal, R. C., Singh, N. K. (Def. Sci. J. 26 No. 4 [1976] 169/74, 170/1; C.A. 87 [1977] No. 15264).Google Scholar
  41. [13]
    Karkarashvili, M. V., Beshkenadze, I. A. (Issled. Obl. Khim. Kompleksn. Prostykh. Soedin. Nek. Perekhodnykh Redk. Metal. No.3 [1978] 44/51, 45/8; C.A. 90 [1979] No. 214471).Google Scholar
  42. [14]
    Tsintsadze, G. V., Tsivtsivadze, T. I., Turiashvili, T. N., Kvitashvili, A. I., Shkurpelo, A. I., Nagornaya, L. K. (Soobshch. Akad. Nauk Gruz.SSR 111 [1983] 65/8; C.A. 99 [ 1983 ] No. 222 804 ).Google Scholar
  43. [15] Tsintsadze, G. V., Tsivtsivadze, T. I., Turiashvili, T. N., Kvitashvili, A. I., Shkurpelo, A. I., Nagonaya, L. K. (Soobshch. Akad. Nauk Gruz. SSR 115 [1984]
    /40; C. A. 102 [ 1985 ] No. 123 483 ).Google Scholar
  44. [1]
    Gogorishvili, P. V., Karkarashvili, M. V., Shamilishvili, O. Kh. (Soobshch. Akad. Nauk Gruz.SSR 62 [1971] 61/4; C.A. 75 [1971] No. 54107).Google Scholar
  45. [2] Kharitonov, Yu. Ya., Machkhoshvili, R. I., Gogorishvili, P. V., Shamilishvili, O. Kh. (Zh. Neorgan. Khim. 17 [1972]
    /7; Russ. J. Inorg. Chem. 17 [ 1972 ] 843 /7, 845 ).Google Scholar
  46. [1]
    Grewal, S., Sekhon, B. S., Pannu, B. S., Chopra, S. L. (Indian J. Chem. 13 [1975] 623/4).Google Scholar
  47. [2]
    Kachhawaha, M. S., Bhattacharya, A. K. (J. Inorg. Nucl. Chem. 25 [1963] 361/3).Google Scholar
  48. [3]
    Gopal, R., Misra, V. N., Narang, K. K. (Indian J. Chem. A 14 [1976] 364/6).Google Scholar
  49. [4]
    Mach, J. (Acta Univ. Palacki Olomuc. Fac. Rerum Nat. No. 41 [1973] 27/36, 29/32; C.A. 81 [ 1974 ] No. 44787).Google Scholar
  50. [5]
    Issa, R. M., El-Shazly, M. F., Iskander, M. F. (Z. Anorg. Allgem. Chem. 354 [1967] 90/7, 91/2, 95/6).Google Scholar
  51. [6]
    Aggarwal, R. C., Singh, N. K. (Def. Sci. J. 26 No. 4 [1976] 169/74; C.A. 87 [1977] No. 15264).Google Scholar
  52. Beshkenadze, I. A., Karkarashvili, M. V., Gogorishvili, P. V. (Izv. Akad. Nauk Gruz.SSR Ser. Khim. 5 No. 2 [1979] 103/10, 104/8; C.A. 91 [1979] No. 221662).Google Scholar
  53. Karkarishvili, M. V., Beshkanadze, I. A. (Issled. Obl. Khim. Kompleksn. Prostykh. Soedin. Nek. Perekhodnykh Redk. Metal. No. 3 [1978] 32/43, 33, 35/40; C.A. 90 [1979] No. 214470).Google Scholar
  54. Kharitonov, Yu. Ya., Machkhoshvili, R. I., Generalova, N. B., Shchelokov, R. N. (Zh. Neorgan. Khim. 20 [1975] 965/71, 19 [1974] 1124/5; Russ. J. Inorg. Chem. 20 [1975] 540/4, 542, 19 [1974] 613/4).Google Scholar
  55. [1]
    Shamilishvili, O. Kh., Machkhoshvili, R. I., Kharitonov, Yu. Ya., Dzhibladze, T. G. (Zh. Neorgan. Khim. 20 [1975] 3003/6; Russ. J. Inorg. Chem. 20 [1975] 1661/3).Google Scholar
  56. [2]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Generalova, N. B., Shchelokov, R. N. (Zh. Neorgan. Khim. 20 [1975] 693/700,19 [1974] 1124/5; Russ. J. Inorg. Chem. 20 [1975] 387/92, 391, 19 [1974] 613/4).Google Scholar
  57. Mostafa, M. M., Hassan, S. M., El-Asmy, A. A. (Egypt. J. Chem. 22 [1979/80] 383/8, 384/6; J. Indian Chem. Soc. 57 [1980] 127/9).Google Scholar
  58. [1]
    Rao, T. R., Sahay, M., Aggarwal, R. C. (Syn. React. Inorg. Metal-Org. Chem. 15 [1982] 209/22, 212/3, 217).Google Scholar
  59. [2]
    Rao, T. R., Sahay, M., Aggarwal, R. C. (Indian J. Chem. A 23 [1984] 214/8).Google Scholar
  60. [1] Tsivadze, A. Yu., Tsintsadze, G. V., Petriashvili, Zh. D., Kharitonov, Yu. Ya. (Koord. Khim. 3 [1977]
    /9; Soviet J. Coord. Chem. 3 [ 1977 ] 815 /21, 816 ).Google Scholar
  61. [2]
    Tsintsadze, G. V., Tsivtsivadze, T. I., Dzhavakhishvili, Z. O., Ilinskii, A. I., Orbeladze, F. V. (Koord. Khim. 5 [1979] 909/11; Soviet J. Coord. Chem. 5 [1979] 718/20).Google Scholar
  62. [3]
    Aggarwal, R. C., Rao, T. R. (J. Inorg. Nucl. Chem. 40 [1978] 1177/8).Google Scholar
  63. [1]
    Tsintsadze, G. V., Manvelidze, G. V., Mdivani, M. A., Petriashvili, Zh. D., Chigogidze, N. Sh., Kiguradze, R. A., Dzhavakhishvili, Z. O. (Tr. Gruz. Politekhn. Inst. 1975 No. 4, pp. 5/18, 11/2; C. A. 86 [1977] No. 47263 ).Google Scholar
  64. [2]
    Aggarwal, R. C., Rao, T. R. (Transition Metal Chem. [Weinheim] 2 [1977] 201/4).Google Scholar
  65. [3] Tsivadze, A. Yu., Tsintsadze, G. V., Petriashvili, Zh. D., Kharitonov, Yu. Ya. (Koord. Khim. 1 [1975]
    /7; Soviet J. Coord. Chem. 1 [ 1975 ] 1223 /7, 1224 ).Google Scholar
  66. [4]
    Tsivadze, A. Yu., Tsintsadze, G. V., Petriashvili, Zh. D., Kharitonov, Yu. Ya. (Koord. Khim. 3 [1977] 1052/9; Soviet J. Coord. Chem. 3 [1977] 815/21, 816, 821 ).Google Scholar
  67. [5]
    Pilicec, S., Vasiliev, R., Maurer, A., Mracec, M., Havlik, J., Costi§or, O., Jitaru, M., Topciu, V., Csaki, N. (Timisoara Med. 26 No. 3 [1981] 29/34, 30; C.A. 97 [1982] No. 66073).Google Scholar
  68. [6]
    Abou Sekkina, M. M., Abou El-Azm, M. G. (Thermochim. Acta 77 [ 1984 ] 211 /8, 215 ).Google Scholar
  69. [1]
    Nagano, K., Kinoshita, H., Tamura, Z. (Chem. Pharm. Bull. [Tokyo] 11 [1963] 999 /1013, 1006, 1013 ).Google Scholar
  70. [2]
    Ishidate, M. (Anal. Chem. Proc. Intern. Symp., Birmingham, Engl., 1962 [1963], pp$1178/82, 180; C.A. 59 [ 1963 ] 10967 ).Google Scholar
  71. [1]
    Narimanidze, A. P., Tsivadze, A. Yu., Dzhavakhishvili, Z. O., Il’inskii, A. L., Tsivtsivadze, T. I., Kharitonov, Yu. Ya. (Koord. Khim. 4 [1978] 233/8; Soviet J. Coord. Chem. 4 [1978] 175/9).Google Scholar
  72. [2]
    Sanke Gowda, H., Janardhan, R. (Proc. Indian Acad. Sci. Chem. Sci. 91 [1982] 339/41; C. A. 98 [1983] No. 10673).Google Scholar
  73. [3]
    Allan, J. R., Baillie, G. M., Baird, N. D. (J. Coord. Chem. 13 [ 1984 ] 83 /8, 84 ).Google Scholar
  74. [4]
    Khakimov, Kh. Kh., Azizov, M. A., Khamraev, A. D. (Mater. Yubileinoi Resp. Nauchn. Konf. Farm. Posvyashch. 50-Letiyu Obrazov. SSSR, Tashkent 1972, pp. 151/2; C.A. 82 [1975] No. 164327).Google Scholar
  75. [5]
    Tsintsadze, G. V., Dzhavakhishvili, Z. O., Aleksandrov, G. G., Struchkov, Yu. T., Narimanidze, A. P. (Koord. Khim. 6 [1980] 785/92; C.A. 93 [1980] No. 35435).Google Scholar
  76. [6]
    Narimanidze, A. P., Dzhashiashvili, T. K., Kharitonov, Yu. Ya. (Tr. Gruz. Politekhn. Inst. 1972 No. 2, pp. 9/15, 9/11, 14; C.A. 92 [1980] No. 68844).Google Scholar
  77. [7]
    Abou Sekkina, M. M., Abou EI-Azm, M. G. (Thermochim. Acta 79 [ 1984 ] 47 /53, 49 ).Google Scholar
  78. [8]
    Neuzil, E., Segonne, J. (Bull. Soc. Pharm. Bordeaux 93 [1955] 49/66, 58; C.A. 1956 9200 ).Google Scholar
  79. [9] Petriashvili, Zh. D., Narimanidze, A. P., Mamulashvili, A. M. (Sakartvelos Politeknikuri Institutis Shromebi [Tr. Gruz. Politekhn. Inst.] 3 No. 167 [1974]
    /4; C.A. 83 [ 1975 ] No. 141 223 ).Google Scholar
  80. [10] Tsivadze, A. Yu., Kharitonov, Yu. Ya., Tsintsadze, G. V., Petriashvili, Zh. D. (Koord. Khim. 1 [1975]
    /30; Soviet J. Coord. Chem. 1 [ 1975 ] 425 /30, 427 ).Google Scholar
  81. [11] Hlevca, M. (Acad. Rep. Populare Romine Studii Cercetari Chim. 9 [1961]
    /56, 550; C. A. 57 [ 1962 ] 12090 ).Google Scholar
  82. [12] Narimanidze, A. P., Tsivadze, A. Yu., Kharitonov, Yu. Ya., Dzhashiashvili, T. K. (Koord. Khim. 1 [1975]
    /41; Soviet J. Coord. Chem. 1 [ 1975 ] 793 /8, 794 ).Google Scholar
  83. [13]
    Grecu, I. (Omagiu Raluca Ripan 1966 236/7; C.A. 67 [1967] No. 49969).Google Scholar
  84. [14]
    Grecu, I., Curea, E., Pills, M. (Acad. Rep. Populare Romine Filiala Cluj Studii Cercetari Chim. 13 [1962] 213/8, 216; C.A. 61 [ 1964 ] 10027 ).Google Scholar
  85. [15]
    Doadrio, A., Crâciunescu, D., Suarez, M., Shohet, J., Castro, F. (Acta Pharm. Fennica 85 [1976] 19/27, 22/3; C.A. 85 [1976] No. 117301).Google Scholar
  86. [16]
    Grecu, I., Piti Neamtu, M. (Farmacia [Bucharest] 11 [1963] 655/61, 659; C.A. 60 [ 1964 ] 14108 ).Google Scholar
  87. [17]
    Narimanidze, A. P., Dzhashiashvili, T. K., Kharitonov, Yu. Ya. (Nauchn. Tr. Gruz. Politekhn. Inst. Khim. Koord. Soedin. No. 12 [1982] 14/8; C.A. 100 [1984] No.44421).Google Scholar
  88. [1] Kharitonov, Yu.Ya., Machkhoshvili, R. I., Goeva, L. V. (Koord. Khim. 5 [1979]
    /5; Soviet J. Coord. Chem. 5 [ 1979 ] 904 /8, 907 ).Google Scholar
  89. [2] Kharitonov, Yu.Ya., Machkhoshvili, R. I., Goeva, L. V. (Koord. Khim. 1 [1975]
    /57; Soviet J. Coord. Chem. 1 [ 1975 ] 1205 /11, 1206 ).Google Scholar
  90. [1] Kharitonov, Yu. Ya., Machkhoshvili, R. I., Goeva, L. V. (Koord. Khim. 5 [1979]
    /8; Soviet J. Coord. Chem. 5 [ 1979 ] 1055 /60, 1058 ).Google Scholar
  91. [2]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Goeva, L. V. (Koord. Khim. 2 [1976] 1481/9; Soviet J. Coord. Chem. 2 [ 1976 ] 1137 /43, 1142 ).Google Scholar
  92. [1]
    Gopal, R., Misra, V. N., Narang, K. K. (Indian J. Chem. 13 [1975] 186/8).Google Scholar
  93. [2]
    Gopal, R., Misra, V. N., Narang, K. K. (Indian J. Chem. A 14 [1976] 364/6).Google Scholar
  94. [1]
    Aggarwal, R. C., Singh, N. K., Prasad, L. (Indian J. Chem. A 14 [1976] 325/7).Google Scholar
  95. [2]
    Aggarwal, R. C., Singh, N. K., Prasad, L. (Indian J. Chem. A 14 [1976] 181/3).Google Scholar
  96. [1]
    Aggarwal, R. C., Singh, B. (Z. Anorg. Allgem. Chem. 445 [ 1978 ] 227 /32, 229 ).Google Scholar
  97. [2]
    Gogorishvili, P. V., Karkarashvili, M. V., Shamilishvili, O. Kh. (Soobshch. Akad. Nauk Gruz.SSR 60 No. 1 [1970] 89/92; C.A. 74 [1971] No. 60333).Google Scholar
  98. [3]
    Kharitonov, Yu. Ya., Machkhoshvili, R. I., Gogorishvili, P. V., Shamilishvili, O. Kh. (Zh. Neorgan. Khim. 17 [1972] 2992/5; Russ. J. Inorg. Chem. 17 [1972] 1574/6).Google Scholar
  99. [1]
    Shvelashvili, A. E., Zhorzholiani, N. B., Svanidze, O. P., Zedelashvili, E. N. (Soobshch. Akad. Nauk Gruz.SSR 119 No. 1 [1985] 105/8; C.A. 104 [1986] No. 25039).Google Scholar
  100. [2]
    Gobedzhishvili, K. M., Nagebashvili, S. Sh., Dolidze, Ts. G. (Nauchn. Tr. Gruz. Politekhn. Inst. im. V. I. Lenina No. 11 [1980] 12/6, 14; C.A. 96 [1982] No. 134784).Google Scholar
  101. [3] Aggarwal, R. C., Singh, B. (Current Sci. [India] 47 [1978]
    /80; C.A. 89 [ 1978 ] No. 208 305 ).Google Scholar
  102. [4]
    Dutta Ahmed, A., Mandal, P. K., Ray Chaudhuri, N. (J. Inorg. Nucl. Chem. 28 [1966] 2951/9, 2952/6).Google Scholar
  103. [5]
    Dutta Ahmed, A., Ray Chaudhuri, N. (J. Inorg. Nucl. Chem. 31 [1969] 2545 /56, 2550 ).Google Scholar
  104. [6]
    Vardosanidze, T. O., Sokol, V. I., Sobolev, A. N., Shvelasvili, A. E., Porai-Koshits, M. A. (Zh. Neorgan. Khim. 30 [1985] 1745/51; Russ. J. lnorg. Chem. 30 [1985] 992/5).Google Scholar
  105. [7]
    Vardosanidze, T. O., Shvelashvili, A. E., Sobolev, A. N., Porai-Koshits, M. A. (Zh. Neorgan. Khim. 30 [1985] 364/7; Russ. J. lnorg. Chem. 30 [1985] 203/6).Google Scholar
  106. [8]
    Gogorishvili, P. V., Machkhoshvil.i, R. I., Tsitsishvili, L. D., Kharitonov, Yu. Ya., Shvelash-vili, A. E. Tsutsunava, T. I. (Zh. Neorgan. Khim. 22 [1977] 3275/9; Russ. J. Inorg. Chem. 22 [1977] 1784/7).Google Scholar
  107. [9]
    Dutta Ahmed, A., Ray Chaudhuri, N., Saha, U. (Indian J. Chem. 11 [1973] 1036/7).Google Scholar
  108. [10]
    Vardosanidze, T. O., Sobolev, A. N., Shvelashvili, A. E. Charelishvili, L. Sh. (Soobshch. Akad. Nauk Gruz.SSR 119 [1985] 305/8; C.A. 104 [1986] No. 140948).Google Scholar
  109. [11] Machkhoshvili, R. I., Vekua, N. N., Gogorishvili, P. V., et al. (Koord. Khim. 3 [1977]
    /41; Soviet J. Coord. Chem. 3 [ 1977 ] 244 /52, 246 ).Google Scholar
  110. [1]
    Shvelashvili, A. E., Zhorzholiani, N. B., Svanidze, O. P., Zedelashvili, E. N. (Soobshch. Akad. Nauk Gruz.SSR 119 No. 1 [1985] 105/8; C.A. 104 [1986] No. 25039).Google Scholar
  111. [2]
    Ahmed, A. D., Ray Chaudhuri, N. (J. Inorg. Nucl. Chem. 31 [1969] 2545 /56, 2548, 2551 ).Google Scholar
  112. [3]
    Tsitsishvili, L. D., Gogorishvili, P. V., Tsutsunava, T. I. (Issled. Obl. Khim. Kompleksn. Prostykh. Soedin. Nek. Perekhodnykh Metal. 2 [1974] 145/51, 148; C.A. 82 [1975] No. 38076).Google Scholar
  113. [4] Kharitonov, Yu. Ya., Tsitsishvili, L. D., Tsutsunava, T. l., Chumakova, T. M., Stoppe, M. G. (Koord. Khim. 8 [1982]
    /73; Soviet J. Coord. Chem. 8 [1982] 357/63, 358, 362 ).Google Scholar
  114. [5]
    Gogorishvili, P. V., Machkhoshvili, R. I., Tsitsishvili, L. D. Kharitonov, Yu. Ya., Shvelashvili, A. E., Tsutsunava, T. I. (Zh. Neorgan. Khim. 22 [1977] 3275/9; Russ. J. Inorg. Chem. 22 [1977] 1784/7).Google Scholar
  115. [1]
    Shvelashvili, A. E., Zhorzholiani, N. B., Svanidze, O. P., Zedelashvili, E. N. (Soobshch. Akad. Nauk Gruz.SSR 119 No. 1 [1985] 105/8; C.A. 104 [1986] No. 25039).Google Scholar
  116. [2]
    Gogorishvili, P. V., Tsitsishvili, L. D., Chrelashvili, M. V. (Issled. Obl. Khim. Kompleksn. Soedin. Nek. Perekhodnykh Redk. Metal No. 1 [1970] 5/13, 6/7, 10; C.A. 74 [1971] No. 82616).Google Scholar
  117. [3] Machkhoshvili, R. I., Kharitonov, Yu. Ya., Gogorishvili, P. V., Tsitsishvili, L. D. (Koord. Khim. 3 [1977]
    /7; Soviet J. Coord. Chem. 3 [ 1977 ] 307 /11, 310 ).Google Scholar
  118. [4]
    Gogorishvili, P. V., Tsitsishvili, L. D., Chrelashvili, M. V. (Issled. Obl. Khim. Kompleksn. Prostykh. Soedin. Nek. Perekhodnykh Redk. Metal No. 1 [1970] 27/36, 28, 32, 35; C.A. 74 [1971] No. 60339).Google Scholar
  119. [5] Tsutsunava, T. I., Kharitonov, Yu. Ya., Tsitsishvili, L. D., Stoppe, M. G., Chumakova, T. M. (Koord. Khim. 8 [1982]
    /93; Soviet J. Coord. Chem. 8 [ 1982 ] 420 /6, 424 ).Google Scholar
  120. [6]
    Kharitonov, Yu. Ya., Tsitsishvili, L. D., Tsutsunava, T. I., Chumakova, T. M., Stoppe, M. G. (Koord. Khim. 8 [1982] 666/73; Soviet J. Coord. Chem. 8 [1982] 357/63).Google Scholar
  121. [7]
    Gogorishvili, P. V., Machkhoshvili, R. I., Tsitsishvili, L. D., Kharitonov, Yu. Ya., Shvelashvili, A. E., Tsutsunava, T. I. (Zh. Neorgan. Khim. 22 [1977] 3275/9; Russ. J. Inorg. Chem. 22 [1977] 1784/7).Google Scholar
  122. [1]
    Nikoiaev, A. V., Savel’eva, Z. A., Larionov, S. V., Leonova, T. G., Shklyarev, A. A. (Koord. Khim. 2 [1976] 1234/7; Soviet J. Coord. Chem. 2 [1976] 944/6).Google Scholar
  123. [2]
    Murzubraimov, B., Shtrempler, G. I., Rysmendeev, K. (Zh. Neorgan. Khim. 23 [1978] 779/83; Russ. J. lnorg. Chem. 23 [1978] 430/2).Google Scholar
  124. [3]
    Shtrempler, G. I., Murzubraimov, B. (Zh. Neorgan. Khim 26 [1981] 3297/9; Russ. J. Inorg. Chem. 26 [1981] 1768/70).Google Scholar
  125. [4]
    Murzubraimov, B., Shtrempler, G. I. (Zh. Neorgan. Khim. 27 [1982] 1473/5; Russ. J. Inorg. Chem. 27 [1982] 829/30).Google Scholar
  126. [5]
    Agrawal, Y. K., Patel, D. R. (J. Pharm. Sci. 75 [1986] 190/2).Google Scholar
  127. [6]
    Murzubraimov, B., Toktomatov, A. (Koord. Khim. 10 [1984] 1531/5; C.A. 102 [1985] No. 35645).Google Scholar
  128. [1]
    Ivanov, M. G., Kalinichenko, I. 1. (Zh. Neorgan. Khim. 26 [1981] 2134/7; Russ. J. Inorg. Chem. 26 [1981] 1150/1).Google Scholar
  129. [2]
    Dutta, R. L., Sarkar, A. K. (J. Inorg. Nucl. Chem. 43 [1981] 2557/9).Google Scholar
  130. [3]
    Ivanov, M. G., Kalinichenko, I. I. (Zh. Neorgan. Khim. 26 [1981] 2159/62; Russ. J. Inorg. Chem. 26 [1981] 1162/4).Google Scholar
  131. [4]
    Ivanov, M. G., Kalinichenko, I. I., Savitskii, A. M. (Koord. Khim. 11 [1985] 45/8; C.A. 102 [1985] No. 196726).Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1987

Authors and Affiliations

  • Karl Koeber
    • 1
  • Helga Köttelwesch
    • 1
  • Dietrich Schneider
    • 1
  • Helga Demmer
    • 1
  • Edith Schleitzer-Rust
    • 1
  1. 1.Gmelin-InstitutFrankfurt am MainGermany

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