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Molybdate Hydrates with Alkaline Earth Metals

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Mo Molybdenum

Part of the book series: Gmelin Handbook of Inorganic Chemistry ((1039,volume M-o / A-B / B / 4))

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Abstract

This system has been investigated at 25°C, see Fig. 66, p. 178. The following solid compounds have been found to exist in stable equilibria with the solution: Mg(OH)2, 8MgO · MoO3.48 H2O, 4 MgO · MoO3 ·12 H2O, MgMoO4 · 5 H2O, MgO · 3 MoO3 · 10 H2O, MoO3. The “trimolybdate” 10-hydrate is the only polymolybdate in this sequence [1]. The paramolybdate 3MgO · 7MoO3 · 20H2O was found to exist only in a metastable equilibrium [2]. Because of the slow equilibration when starting from MgO, MoO3, and H2O, the initial materials in this investigation were the compounds MgMoO4 · 5 H2O, MgO · 3 MoO3 · 10 H2O, and Mg3[Mo7O24] · 20 H2O. Selected points on the phase diagram are [1]:

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Authors and Affiliations

  1. Universität Göttingen, Germany

    Karl-Heinz Tytko

  2. Gmelin-Institut, Frankfurt am Main, Germany

    Wolf-Dietrich Fleischmann, Dieter Gras & Eberhard Warkentin

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  1. Karl-Heinz Tytko
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  2. Wolf-Dietrich Fleischmann
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  3. Dieter Gras
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  4. Eberhard Warkentin
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  5. Hartmut Katscher
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  6. Friedrich Schröder
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Hartmut Katscher Friedrich Schröder

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Tytko, KH., Fleischmann, WD., Gras, D., Warkentin, E., Katscher, H., Schröder, F. (1985). Molybdate Hydrates with Alkaline Earth Metals. In: Katscher, H., Schröder, F. (eds) Mo Molybdenum. Gmelin Handbook of Inorganic Chemistry, vol M-o / A-B / B / 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-07836-5_3

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  • DOI: https://doi.org/10.1007/978-3-662-07836-5_3

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