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Pentanuclear Compound

  • Ulf Thewalt
  • Reinhard Hemmer
Part of the Ti. Titan. Titanium (System-Nr. 41) book series (GMELIN, volume T-i / 1-5 / 5)

Abstract

(π-C5H5)5Ti5S6 (Formula I). This cluster compound can be prepared in 73% yield by the reaction between (π-C5H5)2Ti(CO)2 and gaseous H2S (6.4:7.7) in toluene at 80°C for 72 h. It is dark green-brown, moderately air-sensitive and very soluble in toluene. Large crystals are obtained when the toluene solution is layered with hexane [1, 2].

Keywords

Bond Distance Unpaired Electron Large Crystal Weak Absorption Toluene Solution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. [1]
    F. Bottomley, G. O. Egharevba, P. S. White (J. Am. Chem. Soc. 107 [1985] 4353/4).CrossRefGoogle Scholar
  2. [2]
    F. Bottomley, D. F. Drummond, G. O. Egharevba, P. S. White (Organometallics 5 [1986] 1620/5).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1989

Authors and Affiliations

  • Ulf Thewalt
    • 1
  • Reinhard Hemmer
    • 1
  1. 1.Universität UlmGermany

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