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Electrochemical Behaviour

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Rh Rhodium

Part of the book series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition ((1047,volume R-h / R-h / A / 1))

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Abstract

The oxidation potentials of the most commonly encountered compounds are given by [1]. A more complete List is given in [2, 3]. The most important oxidation state is Rh3+ RhO2 and RhO3 have been prepared in alkaline solution, but are not stable in acid ones. Rh2O3 is soluble in HCl to form complex chlorides and this oxide is also probably soluble in HClO4.

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References

  1. Latimer, W.M. (The Oxidation States and Their Potentials in Aqueous Solutions, 2nd Ed., Prentice-Hall, Englewood Cliffs, N.J., 1961 ).

    Google Scholar 

  2. van Muylder, J.; Pourbaix, M. (Centre Belge Etude Corros. Rappt. Tech. No. 59 [1958] 1/11).

    Google Scholar 

  3. Llopis, J.F.; Tordesillas, I.M. (Encyl. Electrochem. Elem. 6 [1976] 299/329).

    Google Scholar 

  4. Peukert, M. (J. Electroanal. Chem. Interfacial Electrochem. 185 [1985] 379/91).

    Google Scholar 

  5. Petukhova, R.P.; Podlovchenko, B.I.; Gas’kov, A.M. (Elektrokhimiya 21 [1985] 1414/8; Soviet Electrochem. 21 [1985] 1339/43).

    Google Scholar 

  6. Rand, D.A.J. (Proc. Roy. Australian Chem. Inst. 41 [1974] 8/12).

    Google Scholar 

  7. Llopis, J.; Tordesillas, I.M.; Muniz, M. (Electrochim. Acta 10 [1965] 1045/55).

    Google Scholar 

  8. Llopis, J.; Vazquez, M. (Electrochim. Acta 9 [1964] 1655/63).

    Google Scholar 

  9. Hickling, A.; Salt, F.W. (Trans. Faraday Soc. 36 [1940] 1226/35).

    Google Scholar 

  10. Damjanovic, A.; Dey, A.; Bockris, J.O’M. (J. Electrochem. Soc. 113 [1966] 739/46).

    Google Scholar 

  11. Victori, L.; Marcotegui, J.; Monge, J. (Rev. Iberoam. Corros. Prot. 15 No. 4 [1984] 63/4).

    Google Scholar 

  12. Grube, G.; Autenrieth, H. (Z. Elektrochem. Angew. Physik. Chem. 44 [1938] 296/9).

    Google Scholar 

  13. Khrushcheva, E.I.; Shumilova, N.A.; Tarasevich, M.R. (Elektrokhimiya 2 [1966] 277/82; Soviet Electrochem. 2 [1966] 258/62).

    Google Scholar 

  14. Genshaw, M.A.; Damjanovic, A.; Bockris, J.O’M. (J. Phys. Chem. 71 [1967] 3723/31).

    Google Scholar 

  15. Pentland, N.; Bockris, J.O’M.; Sheldon, E. (J. Electrochem. Soc. 104 [1957] 182/94).

    Google Scholar 

  16. Böld, W.; Breiter, M. (Electrochim. Acta 5 [1961] 169/79).

    Google Scholar 

  17. Shibata, S. (Bull. Chem. Soc. Japan 38 [1965] 1330/7).

    Google Scholar 

  18. Hoare, J.P. (J. Electrochem. Soc. 111 [1964] 232/6).

    Google Scholar 

  19. Hoare, J.P. (Electrochim. Acta 13 [1968] 417/28).

    Google Scholar 

  20. Okamura, T. (Denki Kagaku 37 [1969] 831/5).

    Google Scholar 

  21. Peukert, M. (Surf. Sci. 141 [1984] 500/14).

    Google Scholar 

  22. Raub, E.; Buss, G. (Z. Elektrochem. Angew. Physik. Chem. 46 [1940] 195/202).

    Google Scholar 

  23. Savitskii, E.; Polyakova, V.N.; Gorina, N.; Roshan, N. (Physical Metallurgy of Platinum Metals, MIR Publ., Moscow 1978 ).

    Google Scholar 

  24. Vasin, B.D.; Ivanov, V.A.; Raspopin, S.P. (Soviet Non-Ferrous Metals Res. 13 [1985] 393/6).

    Google Scholar 

  25. Buck, W.R.; Leidheiser, H. (Nature 181 [1958] 1681/2).

    Google Scholar 

  26. Buck, W.R.; Leidheiser, H. (Z. Elektrochem. 62 [1958] 690/5).

    Google Scholar 

  27. Buck, W.R.; Leidheiser, H. (Nature 204 [1964] 177/8).

    Google Scholar 

  28. Hoar, T.P. (Platinum Metals Rev. 5 [1961] 141/3).

    Google Scholar 

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© 1991 Springer-Verlag Berlin Heidelberg

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Watts, G.R. (1991). Electrochemical Behaviour. In: Swars, K. (eds) Rh Rhodium. Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition, vol R-h / R-h / A / 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06411-5_6

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  • DOI: https://doi.org/10.1007/978-3-662-06411-5_6

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-06413-9

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