Abstract
Little has been published on the rhodium-iron phase diagram. Thermal analysis investigations have established the liquidus, solidus and γ/δ phase transformation temperatures for alloys containing up to 21 at% rhodium and this work showed that the system was of the expanded y-field type, in which the temperature of the A4 transformation was raised by the addition of rhodium [1]. Earlier work carried out by magnetic measurements had shown that the γ-phase underwent an austenitic → martensitic transformation at lower temperatures. Changes in the magnetic susceptibility and the Curie temperature suggested other changes at compositions of 20 and 50 at% rhodium [2]. The former was later shown to be associated with a crystallographic change of the bcc α-phase to an ordered CsCl-type structure. A tater investigation showed an unexpected and sudden rise in the magnetization curve of alloys containing ~ 50 at% rhodium at a temperature of ~100 °C [3]. In an X-ray investigation which followed, the phenomenon was wrongly associated with a crystalline phase change between an ordered CsCI and a fcc phase [4]. Subsequent X-ray work showed that the ordered CsCI structure was stable above and below the magnetic transformation temperature, and that it remained stable up to temperatures of ~1300 °C; a small change in lattice parameter was found associated with the magnetic transformation. Above ~1300 °C, the CsCI structure changed into the fcc γ-phase [5]. This conclusion was supported by Mössbauer work on FeRh [6]. Neutron diffraction studies showed evidence of an antiferromagnetic ordering of the type found in Heusler alloys, Fm3m [7]. A considerable volume of research on alloys near the FeRh composition has followed; this will be considered separately.
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Watts, G.R. (1991). Alloys with Iron. In: Swars, K. (eds) Rh Rhodium. Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition, vol R-h / R-h / A / 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06411-5_42
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