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The System Boron-Iodine

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B Boron Compounds

Part of the book series: Gmelin Handbook of Inorganic Chemistry ((955,volume B / 1-20 / 1-4 / 3 / 4))

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Abstract

When BI3 vapor mixed with argon or helium is passed through a microwave discharge, four new bands (at 349.8, 350.8, 3651.2, and 352.5 nm) degrading to the red have been observed and assigned to BI. It is assumed that the formation of B2I4 in this process occurs via the donation of the lone pair of BI into the empty 2p orbital of BI3 [1].

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Author information

Authors and Affiliations

  1. Institut für Anorganische Chemie, Universität Göttingen, Göttingen, Federal Republic of Germany

    Anton Meller

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  1. Anton Meller
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Editor information

Editors and Affiliations

  1. Gmelin-Institut, Frankfurt/Main, Germany

    Karl-Christian Buschbeck

  2. Department of Chemistry, University of Kentucky, Lexington, Kentucky, USA

    Kurt Niedenzu

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© 1988 Springer-Verlag Berlin Heidelberg

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Meller, A. (1988). The System Boron-Iodine. In: Buschbeck, KC., Niedenzu, K. (eds) B Boron Compounds. Gmelin Handbook of Inorganic Chemistry, vol B / 1-20 / 1-4 / 3 / 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06138-1_3

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  • DOI: https://doi.org/10.1007/978-3-662-06138-1_3

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-06140-4

  • Online ISBN: 978-3-662-06138-1

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