The System Boron-Chlorine

  • Anton Meller
Part of the Gmelin Handbook of Inorganic Chemistry book series (GMELIN, volume B / 1-20 / 1-4 / 3 / 4)

Abstract

Thermodynamic data obtained from a combination of tungsten transport measurements and theoretical considerations are: ΔH298=151 kJ/mol; S298 = 213 J·mol-1·K-1; Cp.298 = 32 J·mol·K [1]. The bond order-dependent enthalpy term E(BCl) is obtained from the relationship E(BCl) = A[n(BF)]m to be 531.8kJ/mol (bond order n = 3), and the standard heat of formation ΔH f (g) =149.5 kJ/mol (in good agreement with the value given above) [2].

Keywords

Enthalpy Zeolite Photolysis Quinoline Halogen 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • Anton Meller
    • 1
  1. 1.Anorganisch-Chemisches InstitutUniversität GöttingenGöttingenFederal Republic of Germany

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