Compounds with Ligands Bonded by Two or Three Carbon Atoms (Beryllocarbaboranes)

  • Hubert Schmidbaur
Part of the Gmelin Handbook of Inorganic Chemistry book series (GMELIN, volume B-e / 1 / 1)


To 1,2-C2B9H13 in C6H6 is added an equimolar amount of Be(C2H5)2∙3.30(C2H5)2. C2H6 is evolved, and a white precipitate is formed in a small yield. The precipitate is separated by filtration, washed with C6H6, and dried at 50°C.


interpLanar angLe Bridge Linkage Unresolved Resonance Icosahedral Geometry Carborane Carbon 
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    Popp, G., Hawthorne, M. F. (J. Am. Chem. Soc. 90 [1968] 6553/4).CrossRefGoogle Scholar
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    Popp, G., Hawthorne, M F. (Inorg. Chem. 10 [1971] 391/3).Google Scholar
  3. [3]
    Schmid, G., Boltsch, O., Boese, R. (Organometallics 6 [1987] 435/9).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1987

Authors and Affiliations

  • Hubert Schmidbaur
    • 1
  1. 1.Anorganisch-Chemisches Institut der T.U. MünchenGermany

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