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Atom Tunneling Reactions in Quantum Solid Hydrogen

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Book cover Atom Tunneling Phenomena in Physics, Chemistry and Biology

Part of the book series: Springer Series on Atomic, Optical, and Plasma Physics ((SSAOPP,volume 36))

Abstract

According to the generally accepted model, a chemical reaction takes place when reactants with excess energies pass over an activated state and change into products, shown by the dotted line in Fig. 4.1. This type of reaction is here called a classical reaction. A chemical reaction is an exchange of atoms or molecules. Since hydrogen is the lightest atom, the wave property of hydrogen plays an important role in a hydrogen-atom (molecule) exchange reaction. A new type of chemical reaction takes place by passing through the potential energy barrier for the reaction by a quantum-mechanical tunneling effect due to the wave character of the hydrogen atom or molecule, as shown by the dashed line in Fig. 4.1.

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  1. T. Miyazaki
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Editors and Affiliations

  1. Department of Applied Chemistry, Furo-cho, Nagoya University, Graduate School of Engineering, 464-8603, Chikusa-ku, Nagoya, Japan

    Tetsuo Miyazaki

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Miyazaki, T. (2004). Atom Tunneling Reactions in Quantum Solid Hydrogen. In: Miyazaki, T. (eds) Atom Tunneling Phenomena in Physics, Chemistry and Biology. Springer Series on Atomic, Optical, and Plasma Physics, vol 36. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-05900-5_4

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  • DOI: https://doi.org/10.1007/978-3-662-05900-5_4

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-05684-0

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