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Baylis-Hillman reaction

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Abstract

Also known as Morita—Baylis—Hillman reaction, and occasionally known as Rauhut—Currier reaction. It is a carbon-carbon bond-forming transformation of an electron-poor alkene with a carbon nucleophile. Electron-poor alkenes include acrylic esters, acrylonitriles, vinyl ketones, vinyl sulfones, and acroleins. On the other hand, carbon nucleophiles may be aldehydes, α-alkoxycarbonyl ketones, aldimines, and Michael acceptors.

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© 2003 Springer-Verlag Berlin Heidelberg

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Li, J.J. (2003). Baylis-Hillman reaction. In: Name Reactions. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-05336-2_21

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  • DOI: https://doi.org/10.1007/978-3-662-05336-2_21

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-05338-6

  • Online ISBN: 978-3-662-05336-2

  • eBook Packages: Springer Book Archive

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