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Carboxylates Adsorbed on TiO2 (110)

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Chemistry of Nanomolecular Systems

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 70))

Summary

Experimental results on carboxylate (RCOO−) molecules chemisorbed on an atomically flat TiO2 (110) surface are summarized as a prototype of well-defined organo-oxide interfaces. Recent research has led to remarkable advances in preparing carboxylate monolayers and in characterizing those interfaces by thermal desorption spectroscopy, photoelectron spectroscopy, X-ray absorption spectroscopy, vibrational spectroscopy, electron stimulated desorption, and probe microscopy. The principles of carboxylate adsorption, i.e. dissociation at the surface, a bridge structure of the adsorbate, and spontaneous formation of a (2 ×1)-ordered monolayer at room temperature, are valid for all alkyl-substituted carboxylates (R = H, CH3, C2H5, C(CH3)3, C≡CH, C6H5, and CF3) ever examined. Selected topographic images of carboxylate monolayers determined by scanning tunneling microscopy and noncontact atomic force microscopy are presented. Different carboxylates (RCOO− and R′COO−) can be identified molecule-by-molecule by the microscopes when they are coadsorbed.

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Authors
  1. Hiroshi Onishi
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Editors and Affiliations

  1. Research Institute for Electronic Science, Hokkaido University, N12W6, Kita-ku, 060-0812, Sapporo, Japan

    Takayoshi Nakamura

  2. The Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, 567-0047, Osaka, Japan

    Takuya Matsumoto

  3. Institute for Molecular Science, Myodaiji, 444-8585, Okazaki, Japan

    Hirokazu Tada

  4. Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachi-Oji, 192-0397, Tokyo, Japan

    Ken-ichi Sugiura

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Onishi, H. (2003). Carboxylates Adsorbed on TiO2 (110). In: Nakamura, T., Matsumoto, T., Tada, H., Sugiura, Ki. (eds) Chemistry of Nanomolecular Systems. Springer Series in Chemical Physics, vol 70. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-05250-1_5

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  • DOI: https://doi.org/10.1007/978-3-662-05250-1_5

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